• Title/Summary/Keyword: 반응 모델

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A Molecular Neural Network Based on Synaptic Transmission (시냅스 전위활동에 기반한 분자 신경망)

  • 정호진;조동연;장병탁
    • Proceedings of the Korean Information Science Society Conference
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    • 2003.04c
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    • pp.416-418
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    • 2003
  • 해마 뉴런의 시냅스에서 발생하는 전류는 후시냅스의 생화학적 반응을 통해 다음 뉴런으로 전달된다. 즉, 시냅스는 정보를 전달하는 매개로서 전시냅스에서 입력된 정보에 의거하여 후시냅스로 보내는 전류량을 조절하게 된다. 본 논문에서 제안하는 시냅스 기전 신경망 모델은 기존의 신경망과는 달리 시냅스에서 일어나는 반응-확산(reaction-diffusion) 모델에 의하여 입력과 출력의 관계를 결정한다. 제안된 신경망을 분류 문제에 적용한 결과 은닉 뉴런층 없이도 좋은 성능을 보였으며, 이 신경망은 앞으로 뇌에서의 생화학적 뉴런 학습 양상을 연구하는 모델로 사용될 수 있다.

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The Computer-Aided Simulation Study on the Gasification Characteristics of the Roto Coal in the Partitioned Fluidized-Bed Gasifier (상용모사기를 이용한 로토석탄의 분할유동층 가스화기 가스화 특성 모사)

  • Park, Young Cheol;Moon, Jong-Ho;Lee, Seung-Yong;Lee, Dong-Ho;Jin, Gyoung Tae
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.511-515
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    • 2012
  • In this study, we used a commercial simulator to investigate the gasification characteristics of Roto coal in the partitioned fluidized-bed gasifier, which consists of 4 parts such as coal pyrolysis, char gasification, tar/oil gasification and char combustion. The heating medium was exchanged between the combustion part and the gasification part in order to supply the energy needed for pyrolysis and gasification. The correlation model from experimental data in relation to the reaction temperatures, the reaction gases and the coal feed rates was derived for the coal pyrolysis. The equilibrium model was used for the gasification and the combustion model for the char combustion. In order to compare the reaction behavior of the partitioned fluidized-bed gasifier, the single-bed gasifier was also simulated. The cold gas efficiency of both partitioned fluidized-bed gasifier and single-bed gasifier was almost the same. The $H_2$ and $CH_4$ contents of the syngas in the partitioned fluidized-bed gasifier slightly increased and the CO and $CO_2$ contents slightly decreased, compared with the singlebed gasifier. In order to verify the model, ten cases of the single-bed gasification experiment have been simulated. The contents of CO, $CO_2$, $CH_4$ in the syngas from the simulation corresponded with the experimental data while those of $H_2$ was slightly higher than experimental data, but the tendency of $H_2$ content in the syngas was similar to the experiments. In the coal conversion, the simulation results were higher than the experiments since equilibrium model was used for the gasification so that the residence time and contact time in the model is different from the experiments.

A Study on Development of Reaction Rate Equation for Reactive Flow Simulation in Energetic Materials (고에너지 물질의 연소반응 해석을 위한 반응속도식 개발 및 정의에 관한 연구)

  • Kim, Bo-Hoon;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.5
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    • pp.47-57
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    • 2012
  • A modified ignition and growth(I&G) model which is necessary to simulate the combustion phenomena of energetic materials and an analytical model determining the unknown parameters of the reaction rate equation are proposed. The modified I&G model sustains important physical implications with overcoming some problems of previous rate equations. This rate model consists of ignition term which represents the formation of the hotspot due to void collapse and growth term which means the shock to detonation transition phenomena. Also, the theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, $b,\;G,\;x,\;I$. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

A study on development of reaction rate equation for reactive flow simulation in energetic materials (고에너지 물질의 연소반응 해석을 위한 반응속도식 개발 및 정의에 관한 연구)

  • Kim, Bo-Hoon;Yoh, Jai-Ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.331-341
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    • 2012
  • A modified Ignition and Growth(I&G) model which is necessary to simulate the combustion phenomena of energetic materials and an analytical model determining the unknown parameters of the reaction rate equation are proposed. The modified I&G model sustains important physical implications with overcoming some problems of previous rate equations. This rate model consist of Ignition term which represent the formation of the hotspot due to void collapse and Growth term which means the shock to detonation transition phenomena. Also, the theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, b, G, x, I. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

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Changes in the Concept of Disability and its Implications for Social Work Practice (장애개념의 변화와 사회복지실천 현장 함의)

  • Kim, Yong-Deug
    • Korean Journal of Social Welfare
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    • v.51
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    • pp.157-182
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    • 2002
  • This study attempts to identify the changes in social reactions to disabilities in general, and to research the contextual implication of these changes in social work practice in Korea. In the early years after the Industrial Revolution, disability was conceived as social unfitness and it was assumed that the cause and responsibility could be attributed to people with disabilities. But, in the midst and late 20th century, social responsibility for people with disabilities was argued and generally accepted. As the results of these changes, conceptual models explaining disabilities have changed gradually; there has been a transition, so called, from individual model to social model. In a similar vein, WHO has refined the definition and classification of disability. Related to these changes, social welfare service paradigm for people with disabilities has shifted. This paradigm shift can be explained with the perspective of strength approach, empowerment approach, case management and independent living model. In Korea, 1998 Act on welfare for people with disabilities meant that social service for the disabled were categorized with, namely, residential service, community rehabilitation service and vocational rehabilitation service. Recently, the extent of these services has been rapidly broadened. In these situation, this study researched to identify the implications on social work practice in the context of changes in social response, conceptual model, definition and also service paradigm. Such as the followings are enumerated for the implications: disabled person's participation in assessment process, development of assessment tools focusing on social and environmental perspectives, reinforcement of information service helping self-determination, supporting on formal and informal helping network, expanding self-help programs and, finally, a shift from displacement model to support model.

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Dynamic Extinction of Solid Propellants by Depressurization of Combustion Chamber (연소실 압력 강하에 의한 고체 추진제의 동적 소화)

  • Jeong, Ho-Geol;Lee, Chang-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.2
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    • pp.91-97
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    • 2002
  • Dynamic extinction of solid propellants subjected to rapid pressure drop was studied with the aid of energy equation of condensed phase and flame model in gas phase. It is found that the total residence time($\tau_\gamma$) which measures the residing time of fuel in the reaction zone may play a crucial role in determining the dynamic response of the combustuion to extinction. Residence time was modeled by various combinations of diffusion and chemocal kinetic time scale. Effect of pressure history coupled with chamber volume on the extinction response was also performed and was found that dynamic extinction is more susceptible in a confined chamber than in open geometry. And, dynamic extinction was revealed to be affected profoundly by diffysion time scale rather than chemical kinetic time scale.

An Investigation on the Effect of Fuel Stratification of DME/n-Butane mixture on Reduction of Pressure Rise-Rate in HCCI Combustion (DME/n-Butane 혼합 연료의 농도 성층화에 의한 HCCI엔진연소의 압력 상승률 저감에 관한 연구)

  • Lim, Ock-Taeck;Park, Kyu-Yeol
    • Journal of the Korean Institute of Gas
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    • v.15 no.3
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    • pp.39-46
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    • 2011
  • This study investigates the effects of the DME and n-Butane mixture and of the stratification on combustion characteristics of HCCI engine by chemical reaction calculation. First, the existing DME reaction scheme and n-Butane is combined to make new chemical reaction model, then validating the effectiveness of new scheme. Furthermore, this study verify the HCCI combustion characteristics according to the changes of DME and n-Butane mixture ratio, which shows different auto ignition characteristics. Finally, it confirms the effects of stratification of mixture fuel on the reduction of pressure rise rate.

Development of a Computer Code for Analyzing Time-dependent Nuclides Concentrations in the Multi-stage Continuous HLW Processing System (I) - Equilibrium Steady State - (다단계 연속후처리를 포함하는 핵주기공정의 핵종농도 동적분포 해석코드 계발(I) -정상 평형상태 해석모델-)

  • Oh, Se-Kee
    • Proceedings of the KIEE Conference
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    • 2000.11a
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    • pp.262-264
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    • 2000
  • 원자로 내에서 연소 중인 핵연료나 저장 또는 재처리 중인 사용후핵연료의 성분으로서 시설의 공정설계, 안전성분석 및 차폐설계에 중요한 입력자료가 되는 핵분열생성물질, 방사화생성물 및 악티나이드의 핵종 농도와 이에 대응하는 방사능 강도의 기기 별 시간변 화율을 해석할 수 있는 코드 개발할 목적으로 MULTISAMS 정상 평형상태 모델을 구현하였다. MULTISAMS 코드의 반응공정 모델은 서로 연결되어 있으며 내부에 방사성물질의 혼합유체가 순환하는 세 종류의 반응기(원자로, 열교환기 및 화학반응기) 계통에서 자연적 또는 설계에 의해 일어나는 현상으로서; 반응기 간의 물질 흐름; 각 반응기 내에서 방사성 붕괴, 변환, 이동과 중성자 흡수 및 핵분열; 외부로부터 특정 핵종의 유입혹은 유출을 고려한 시간종속 핵종농도보존방정식 이론에 근거한다. 코드의 유용성 및 신뢰성을 검증하기 위해 현재 개념설계가 진행 중인 AMBIDEXTER원자력 에너지시스템을 대상으로 ORIGEN2 계산과 비교하였다. 두 코드 간의 입력조건과 배경이론차이점 때문에 절대적 비교가 불가능하므로 단순이론의 중간매개코드로서 SAMS를 이용한 2단계 비교방법을 따랐다. 결론은 MULTISAMS는 ORIGEN2 계산의 수렴치와 근사하게 일치하면서 ORIGEN2 가 다룰 수 없는 핵주기 연속후처리공정의 정상가동 시 핵종 평형농도를 기기 별로 계산할 수 있다는 장점을 확인하였다.

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Dynamic Optimization of a Reactive Distillation Column Producing Methyl Acetate (메틸 아세테이트 생산을 위한 반응증류 공정의 동적 최적화)

  • Kim, Jiyong;Kim, Junghwan;Moon, Il
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.739-746
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    • 2008
  • The aim of this study is finding the optimal design parameters and the optimal operation variables of a reactive distillation column. Different from steady state optimization, dynamic optimization makes it possible considering operation ability as well as design problems at process design step. For performing dynamic optimization, dynamic simulation should be done first. If dynamic simulation is already finished, dynamic optimization can be performed with less effort than that of dynamic simulation.Reactive distillation systems involving reaction and separation in a single unit have the potential to reduce capital and operating costs, particularly when reaction have conversion constraint or when azeotropes exist making conventional separation difficult and expensive. This study here present work on the continuous distillation process, the homogeneous catalyzed esterification of methanol and acetic acid, the synthesis of methyl acetate. Based on an equilibrium stage model of a reactive distillation column a dynamic optimization problem was formulated and solved. And the results were verified by performing dynamic simulation and showing the variation of conversion and purity as the variation of the operation variables. As the results of dynamic optimization, this study found optimal feed ratio, reflux ratio and reboiler duty of this system. And as this study applied it to dynamic simulations the dynamic characteristics of a reactive distillation column are showed under optimal operating condition.

Modeling of Liquid Hold-up in Fixed-bed Reactor for Fischer-Tropsch Synthesis (고정층 Fischer-Tropsch 반응기의 액상 왁스 정체 현상 모델링)

  • Park, Chansaem;Jung, Ikhwan;Park, Seongho;Na, Jonggeol;Kshetrimayum, Krishnadash;Han, Chonghun;Lee, Jong Yeol;Jung, Jongtae
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.63-67
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    • 2014
  • Fischer-Tropsch synthesis mainly produces a wax which is a viscous liquid for long carbon chain. When a catalytic fixed-bed reactor is used for Fischer-Tropsch synthesis, the wax generated on a catalyst surface can keep adsorbing on the catalyst surface. This liquid hold-up causes significant pressure drop and clogging problems through the reactor. Thus, the model for liquid hold-up is required to design the size of reactor and catalyst particles. In this study, the liquid hold-up model considering structural and operational conditions was proposed based on empirical equations for convective mass transfer between the syngas flow and the wax-adsorbed catalyst. The developed model was validated by comparing with the experimental data from Knochen's work (2010). The influence of reactor length and coross section on the wax hold-up in reactor were analyzed and the optimal reactor size were proposed.