• Title/Summary/Keyword: 반응 동특성

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Characteristics of $\beta$-Glucosidase Immobilized on the Modified Chitin in Bioresctors (수식 Chitin에 고정된 $\beta$-Glucosidase의 동특성)

  • 이경희;김종덕김병우송승구
    • KSBB Journal
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    • v.5 no.3
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    • pp.279-291
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    • 1990
  • Partial hydrolysed and deacetylated chitin, CHITA and CHITB as supports of immobilized enzyme were obtained by treatment of acid and base respectively. Glutaraldehyde, bifunctional reagent, was employed for crosslinking between $\beta$-glucosidase and support. Immobilized enzyme activities of CHITA-Gase and CHITB-Gase were determined with the reaction of p-nitrophenol-$\beta$-D-glucopyranoside(PNG) in batch reactor, CSTR and PFR. Their optimum temperature, pH and enzymatic characteristics including Km and Vmax values were observed with variation of the flow rates. Mass transfer coefficient(h), effectiveness factor(η), deactivation rate(kd ) of two immobilized enzymes were also examined to compare efficiency of reactors.

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고속노계의 노물리적 연구 (고속림계실험장치를 중심으로)

  • Cho, Man;Kim, Jung-Do
    • Nuclear Engineering and Technology
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    • v.7 no.3
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    • pp.243-256
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    • 1975
  • 1. 기초실험 1) 안전성의 검토 대형고속로의 안전성확보를 위한 Doppler효과, Na void 효과 등의 검토 2) 노심의 제특성 측정 청계질양, 비균질효과, 중성자내분포, 중성자 energy 분포, 제물광의 반응도채치, 증식비, Doppler계수, Na의 void 계수 3) 중성자 energy 측정법의 확립 대형노심에 었어서의 중성자 spectrum을 정도높게 정하는 것은 고속노물리자험의 전제조건이 되는 동요한 역천이다, 현재로서는 측정기, 긴정법자체가 업분치 못하기 때문에 많은 연구가 필요하다. 4) 고원여심의 군정수 정비 고동로심의 군정수가 정비 확립 안된것이 계산신업가 낮은 원인이 되고 있기 때문에 제채험의 결과와 대조하여 신뢰성있는 군정수를 정비하여 고속노설계에 양지를 시공한다. 5) 동특성 및 Pulse 체험원자로 내전운전과 핵연료의 효율적인 연소관리를 위한 동특실험과 Pulse 실험을 행하여 동특성해석을 한다. 2. 핵적 Mock-up 실험 관발 건조하고져하는 책험노, 원형노, 책용노의 대심을 모남하여 제물리적인 Parameter를 측정, 최적화를 수행한다.

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Preparation and Characterization of Copper Oxychloride from Acidic Copper Chloride Etchant (PCB 산업에서 배출되는 산성 염화동 폐액으로부터 Copper Oxychloride의 제조 및 특성분석)

  • 김영희;김수룡;정상진;이윤주;어영선
    • Resources Recycling
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    • v.12 no.2
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    • pp.3-10
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    • 2003
  • Copper oxychloride used as an agricultural fungicide has been recovered from copper-containing waste etchant by the neutralization with alkali hydroxides. Large amount of copper-containing waste etchant is generated from Printed Circuit Board industry. In an environmental and economic point of view, retrieve of the valuable natural resource from the waste is important. Recycling process of copper oxychloride from the waste etchant is discovered through the our study. In the range of reaction temp. 2$0^{\circ}C$-4$0^{\circ}C$, pH 5-7, pure copper oxychloride was able to prepare and the yield of copper oxychloride was higher than 95%. Physical properties of the sample have been characterized using SEM, XRD, TGA, ICP and Atomic absorption spectroscopy.

A study of the dynamic characteristic of airship through the flight test (비행선의 비행 시험을 통한 동특성에 관한 연구)

  • Woo, Gui-Aee;Kim, Jong-Kwon;Cho, Kyeum-Rae;Lee, Dae-Woo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.5
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    • pp.97-103
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    • 2004
  • Nowadays, many kinds of research for airship are studying with increasing of interests of airship. But these are far from perfect. The data acquisition from the actual flight test has lots of difficulties because of the characteristics from the slow dynamic response and high sensitivity for external environment. In this paper, through the actual flight test, appropriateness of the mathematical dynamic model applied here was verified by comparing the test data with simulation data in same control conditions.

An Analysis of Dynamic Characteristics of RDX Combustion Using Rigorous Modeling (상세 모델링을 통한 RDX 연소 동특성 분석)

  • Kim, Shin-Hyuk;Yeom, Gi-Hwoen;Moon, Il;Chae, Joo-Seung;Kim, Hyeon-Soo;Oh, Min
    • Clean Technology
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    • v.20 no.4
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    • pp.398-405
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    • 2014
  • In the treatment of spent high energetic materials, the issues such as environmental pollution, safety as well as working capacity should be carefully considered and well examined. In this regard, incineration has been recommended as one of the most promising processes for the disposal of such explosives. Due to the fact that high energetic materials encompass various types and their different characteristics, the technology development dealing with various materials is not an easy task. In this study, rigorous modeling and dynamic simulation was carried out to predict dynamic physico-chemical phenomena for research department explosive (RDX). Plug flow reactor was employed to describe the incinerator with 263 elementary reactions and 43 chemical species. Simulation results showed that safe operations can be achieved mainly by controlling the reactor temperature. At 1,200 K, only thermal decomposition (combustion) occurred, whereas increasing temperature to 1,300 K, caused the reaction rates to increase drastically, which led to ignition. The temperature further increased to 3,000 K which was the maximum temperature recorded for the entire process. Case studies for different operating temperatures were also executed and it was concluded that the modeling approach and simulation results will serve as a basis for the effective design and operation of RDX incinerator.

Some Reactor Kinetics Properties of the $250MW_th$ AMBIDEXTER Circulating Fuel Core (용융염 핵연료 원자로 AMBIDEXTER의 동특성 해석)

  • 김태규;윤정선;원성희;임현진;조재국;오세기
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.119-126
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    • 1999
  • 농축우라늄 고체핵연료를 사용하는 기존의 발전용 원자로 개념에서는 냉각기능의 상실 또는 반응도 상실사고와 같은 극심한 열적 불균형에 의해 핵연료의 온도가 급격히 증가하고, 결과적으로 핵연료의 파손 및 용융으로 발전할 수 있다. 본 연구는 이러한 기존 발전로의 고유 안정성 문제를 획기적으로 해결할 수 있는 혁신형으로서 Th/$^{233}$ U 용융염핵연료주기를 사용하며 원자로계통 전체를 원자로용기에 내장하는 일체형 원자로개념의 AMBIDEXTER (Advanced Molten-salt Break-even Inherently-safe Dual-mission Experimental and TEst Reactor) 원자력 에너지시스템의 동특성을 해석하기 위해 수행되고 있다.(중략)

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Simulation of Intelligent Type Instrument For Power Plant Simulator (발전소 시뮬레이터를 위한 지능형계기의 시뮬레이션)

  • Kim, Dong-Wook
    • Proceedings of the KIEE Conference
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    • 1999.07b
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    • pp.686-689
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    • 1999
  • 발전소 운전원 훈련용 시뮬레이터는 중앙제어실(MCR:Main Control Room) 운전원의 운전결과가 실시간 운영체계하에 발전소 프로세스 모델 및 컴퓨터 시스템과 통합되어 실제 발전소와 같은 반응을 운전원에게 제공하여야 한다. 따라서 시뮬레이터에는 프로세스의 동특성 이외에도 제어시스템의 모델링 및 운전원과 인터페이스되는 제어기들이 실제적으로 구성되어야하며, 이들 제어기와 컴퓨터시스템간 다양한 입력간의 통신 및 동기(Synchronization)가 중요하다. 본 논문에서는 원자력 발전소 시뮬레이터에서 쓰이는 지능형 계기(Intelligent Type Instrument)로 분류된 기기를 살펴보고 시뮬레이션을 위해 개발 구현된 방법들을 기술하고자한다.

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A simulation of steady and dynamic states of methanol reforming reaction (메탄올 개질반응의 정상 및 동특성 모사)

  • 김경미;최영순;송형근
    • 제어로봇시스템학회:학술대회논문집
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    • 1989.10a
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    • pp.395-398
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    • 1989
  • A two dimensional pseudo-homogeneous model for the methanol reforming reaction was developed and its steady and dynamic states were studied by a computer simulation. The reactor tube diameter, the catalyst density in the fixed bed, the feed flow rate, the feed temperature and the external temperature were chosen to be adjusted to determine the length of the reactor. The dynamics of the reactor showed that the system was highly nonlinear and sensitive to the feed disturbances.

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Mutagenicity of Reaction Products of Aflatoxin $B_1$ and Ascorbic Acid (아스콜빈산과 Afatoxin $B_1$ 반응생성물의 돌연변이 유발성)

  • 권미향;박건양;최홍식;백형석
    • Microbiology and Biotechnology Letters
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    • v.18 no.5
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    • pp.466-470
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    • 1990
  • Aflatoxin $B_1$ ($AFB_1$) was reacted with ascorbic acid (AA) alone, with AA plue cysteine and with AA plus cupric ion for 5 days (at $37^{\circ}C$ and pH 5), and the mutagenicity of the reaction products was tested with Salmonella typhimurium TA 100. About 10% of AFBl induced mutagenesis was reduced when $AFB_1$ reacted with AA. This decreasing effect was more severe when $AFB_1$ reacted with AA plus cysteine. The mutagenicity of $AFB_1$ when reacted with AA plus cupric ion was almost completely inhibited, however, eupric ion itself was shown to enhance the mutagenicity of $AFB_1$. Therefore, $AFB_1$ may be degraded in the presence of AA under the given reaction condition and the reaction products was observed to have nonmutagenic effects on the bacterial mutagenecity trials.

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Cure Kinetics and Dynamic Mechanical Properties of an Epoxy/Polyoxypropylene Diamine System (에폭시/폴리옥시프로필렌 디아민계의 경화 반응속도 및 동역학 특성 분석)

  • Huang, Guang-Chun;Lee, Jong-Keun
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.196-202
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    • 2011
  • The cure kinetics of a bisphenol A epoxy resin and polyoxypropylene diamine curing agent system are investigated in both dynamic and isothermal conditions by differential scanning calorimetry (DSC). In dynamic experiments, the shift of exothermic peaks obtained at different heating rates is used to obtain activation energy of overall cure reaction based on the methods of Ozawa and Kissinger. Isothermal DSC data at different temperatures are fitted to an autocatalytic Kamal kinetic model. The kinetic model is in a good agreement with the experimental data in the initial stage of cure. A diffusion effect is incorporated to describe the later stage of cure, predicting the cure kinetics over the whole range of curing process. Also, dynamic mechanical analysis is performed to evaluate the storage modulus and average molecular weight between crosslinkages.