• Journal of the Korean GEO-environmental Society
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• v.14 no.10
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• pp.59-64
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• 2013

Effects of weathering intensity on the adsorption of heavy metals such as lead(Pb) and copper(Cu) onto decomposed granite soils were investigated by a series of batch tests. The chemical components such as $SiO_2$, $K_2O$ and $Na_2O$ having relatively high solubility were reduced and the oxidized $Fe_2O_3$ content was increased with the increase of weathering intensity. Weathering of granite soils increased the ignition loss and specific surface area, while it decreased the permeability. The lead and copper adsorptions onto the decomposed granites were enhanced with the increase of weathering intensity, mainly due to the increase of specific surface area and clayed contents. Adsorption of lead and copper onto the weathered granites could be more adequately described by the pseudo-second-order kinetic model than the pseudo-first-order model.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.190-197
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• 2019

The adsorption of methyl green dye using an activated carbon from an aqueous solution was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, initial concentration, contact time and temperature. The Langmuir isotherm model showed a good fit to the equilibrium adsorption data. Based on the estimated Langmuir separation factor, ($R_L=0.02{\sim}0.106$), this process could be employed as the effective treatment (0 < $R_L$ < 1). It was found that the adsorption was a physical process with the adsorption energy (E) value range between 316.869 and 340.049 J/mol obtained using Dubinin-Radushkevich equation. The isothermal saturation capacity obtained from brunauer emmett teller (BET) model increased with increasing the temperature. The kinetics of adsorption followed a pseudo second order model. The free energy and enthalphy values of -5.421~-7.889 and 31.915 kJ/mol, respectively indicated that the adsorption process follows spontaneous endothermic reaction. The isosteric heat of adsorption increased with the increase of equilibrium adsorption amounts, and the total interaction of the adsorbent - adsorbate increased as the surface coverage increased.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1869-1879
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• 2000

A series of experiments were conducted for modeling the fate and effect of the coupled oxidation reduction reaction of ethanol and propionate recognized as important intermediates in anaerobic degradation metabolism. Anaerobic kinetics for conversion of propionate and the interaction with ethanol were investigated using the model of specific substrate priority utilization effect. Seed cultures for the experiment were obtained from an anaerobically enriched steady-state propionate master culture reactor (HPr-MCR), ethanol-propionate master culture reactor (EtPr-MCR) and glucose master culture reactor (Glu-MCR). Experiments were consisted of four phases. Phase I, II and III were conducted by fixing the propionate organic loading as 1.0 g COD/L with increasing ethanol loading of 0, 100, 200, 400 and 1,000 mg/L, to find metabolic interaction of ethanol and propionate degradation by each enriched anaerobic culture. In phase IV, different mixing ratios of Glu-MCR and HPr-MCR cultures with fixed propionate organic loading, 1.0 g COD/L, were applied to observe the propionate degradation metabolic behavior. In the results of this study, different pathways of propionate and ethanol conversion were found using a modified competitive inhibition kinetic model. Increase of $K_{s2}$ value reflected the formation of acetate followed by ethanol degradation. In addition. $K_3$ value was increased slightly as the reactions of acetate formation and degradation were occurred in acetoclastic methanogenesis.

• Applied Chemistry for Engineering
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• v.31 no.2
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• pp.164-171
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• 2020

Adsorption characteristics of reactive red 120 (RR 120) dye by a coal-based granular activated carbon (CGAC) from an aqueous solution were investigated using the amount of activated carbon, pH, initial concentration, contact time and temperature as adsorption variables. Isotherm equilibrium relationship showed that Langmuir's equation fits better than that of Freundlich's equation. The adsorption mechanism was considered to be superior to the adsorption of monolayer with uniform energy distribution. From the evaluated Langmuir separation coefficients (R_L = 0.181~0.644), it was found that this adsorption process belongs to an effective treatment area (R_L = 0~1). The adsorption energy determined by Temkin's equation and Dubinin-Radushkevich's equation was E = 15.31~7.12 J/mol and B = 0.223~0.365 kJ/mol, respectively. The adsorption process showed the physical adsorption (E < 20 J/mol and B < 8 kJ/mol). The adsorption kinetics followed the pseudo first order model. The adsorption reaction of RR 120 dye on CGAC was found to increase spontaneously with increasing the temperature because the free energy change decreased with increasing the temperature. The enthalpy change (12.747 kJ/mol) indicated an endothermic reaction. The isosteric heat of adsorption (△H_x = 9.78~24.21 kJ/mol) for the adsorption reaction of RR 120 by CGAC was revealed to be the physical adsorption (△H_x < 80 kJ/mol).

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.33-41
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• 2018

Large amounts of leaves from street trees fall onto the streets annually and need to be cleaned and treated. Cherry trees are common street trees in Korea. The adsorption characteristics of Pb(II) by cherry leaf (CL) and cherry leaf-derived biochar (CB) were studied through a series of batch experiments. CB was produced through the carbonization of CL at $800^{\circ}C$ for 90 min. Carbonization increased the C content and pH value, while decreased H and O contents. Well developed pore structure was observed at the surface of CB. The pseudo-second order model better described the kinetics of Pb(II) adsorption onto CL and CB, indicating that the rate-limiting step of the heavy metal sorption is chemical sorption. Fast adsorption rates and high adsorption capacities were obtained by the carbonization from CL to CB. Langmuir models better adequately described the Pb(II) adsorption onto CL and CB. Maximum adsorption capacities of Pb(II) expressed by Langmuir constant, $Q^0$ were 37.31 mg/g and 94.34 mg/g, when CL and CB were used as adsorbents, respectively.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.47-50
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• 2005

본 연구의 목적은 차세대 대체에너지로 각광받는 풍력발전 중에서 육상발전보다 여러 가지 이점이 있는 해상에서의 한국형 풍력터빈 블레이드의 최적 형상을 위 한 알고리즘을 구현하는 것이다. 풍력터빈 블레이드에서 깃익형의 공기 역학적 특성은 매우 중요한 사항이다. 이를 위해서 익형 성능예측에 층류에서 난류로의 천이과정을 포함하는 XFOIL을 이용하여 블레이드 익형 단면의 양력과 항력 분포를 해석하였다. 첫 번째 수준의 설계변수는 운용범위내의 바람의 속도와 블레이드 지름, 축 회전수이며, 각 단면에서의 비틀림각과 시위길이는 두 번째 수준의 설계 변수이다. 운용범위 내의 각 설계점에서 익형의 공력 변수들과 최소에 너지손실 조건을 이용하여 시위길이와 피치각 분포를 최적화하였다. 각각의 설계점에서 결과를 바탕으로 풍력발전의 설계 운용범위에서 반응면을 구성하고 구배최적화 기법을 통해 요구동력의 제약함수를 만족하고 효율을 최대로 하는 블레이드 형상을 구현하였다. 최적형상에 대해 탈설계점 해석을 수행하여 그 성능을 구하였다.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.545-550
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• 2012

This work is for the design study of natural gas reformer (40 $m^3/hr$ over). We used experimental kinetic data from literature. After that, we set up theoretical model based on experimental reaction kinetic data. The shape of reactor is 1.7 m long and 200 mm dia. with cylinder geometry. Volume of reactor is 53.4 liter. Average flow velocity of gases in the reactor has been determined 0.272 m/sec and residence time is 9.26 sec. Reaction temperature is $850^{\circ}C$, with pressure 9.3 Bar. Used natural gas volume is about 9.21 $m^3/hr$. Produced hydrogen is 43.7 $m^3/hr$ with no change of pressure. Unreacted natural gas is 0.09 $m^3/hr$ and the amount of steam is 26.9 $m^3/hr$. Steam to $CH_4$ (s/c ratio) is 2.91. Reforming reaction take place from the reactor entrance to 120 cm region of cylinder type reactor. After the entrance of reacting gases to 120 cm region, the reaction reaches equilibrium which is close to products. This study can be applicable to design various reactors. Output data is in good agreements with the data in literatures1).

• Journal of Conservation Science
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• v.28 no.2
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• pp.131-139
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• 2012

The exothermic cure kinetics of epoxy resin was controlled by hardener containing fast and slow curing agents. The epoxy risen comprises hydrogenated bisphenol A-based epoxide (HBA), fast curing agent (FH) and slow curing agent poly(propyleneglycol)bis(2-aminopropylether) (SH). Talc was used as an inorganic additive. In the process of curing, cure kinetics along with temperature was monitored by differential scanning calorimeter (DSC) and thermocouple to show that the temperature increase was well controlled by adjusting the hardener mixture. Additionally, bending and tensile strengths of the epoxy/talc composites were also measured to be lower and higher with the amount of the talc inorganic additive, respectively. It is thus concluded that the increase in the temperature during exothermic curing reaction and mechanical properties of epoxy resins are tuned by optimizing hardener mixture for successful stone conservation.

• Journal of Korean Society for Atmospheric Environment
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• v.5 no.1
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• pp.43-51
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• 1989

개발된 산성비 모델에서는 다종의 대기오염물 제거로 인한 강우내의 화학성분과 산성도의 고도별 및 시간별 변화를 예측하기 위하여, 강우시 구름내와 밑에서 일어나는 대기 오염물의 강우내로의 물질전달 현상과 화학반응 현상을 동시에 고려하였다. 또한, 강우 산성도의 형성에 중요한 영향을 미치는 구름내에서의 복잡한 동력학적 특성을 고려하기 위하여 강우율의 높이별 변화를 단순화하여 해석하였다. 개발모델을 이용하여 1985년과 1987년 가을의 서울시 산성비에 대하여, 산성비 모델을 이용하여 추정한 pH값과 실측 pH값 사이의 상관관계는 0.57을 나타내었고, 효과적이고 정량적인 관리를 위하여 대기중의 이산화황 농도, 구름층의 두께, 지상에서의 강우율 및 황산이온의 형성에 중요한 역활을 하는 산화제들의 강우 산성도에 미치는 영향을 민감도 분석을 통해서 나타내었다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.9.1-9.1
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• 2011

나노입자는 벌크에 비해 월등히 큰 비표면적(surface-to-volume ratio)과 작은 사이즈에서 오는 양자효과로 인해 촉매나 나노 전자 소자 등 여러 분야에서 응용되고 있다. 특히 백금 나노입자는 수소나 메탄올의 산화, 산소환원 반응의 독보적인 촉매로서 연료전지의 산화극과 환원극의 촉매로 널리 활용되고 있다. 본 연구에서는 높은 가격의 백금의 사용량을 줄일 수 있는 합금 나노입자 촉매에 대한 연구의 일환으로 Pd, Au, Cu, Ag 등의 원소를 활용한 합금 나노입자에 대한 구조 및 열역학적 안정성에 대한 연구를 수행하였다. 다양한 합금에 대한 원자간 포텐셜을 개발하였고, 이를 기반으로 몬테카를로 및 분자동력학 시뮬레이션을 수행하여 Pd-Pt, Cu-Pt, Ag-Pt, Au-Pt 이원계 합금 나노입자의 다양한 원자 구조 및 형상에 따른 결합에너지와 열역학적 특성에 대하여 분석하였다.