• Journal of the Computational Structural Engineering Institute of Korea
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• v.14 no.3
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• pp.339-348
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• 2001

More often a commercial package for the structural analysis is necessary in the structural optimum design. In this case the task of combining the package with an optimization program must be required, hut it is not so simple because interchanging some data between them is difficult. Sequential approximate optimization is currently used as a natural way to overcome the hard task. If sequential approximate optimization has wide side constraints that the lower limit of design variables is very small and their upper limit is very large, it is not so easy to obtain approximated functions accurately for the whole design domain. This paper proposes a sequential design domain method, which is very useful to carry out sequential approximate optimization in this case. In this paper, the response surface methodology is used to obtain approximated functions and the orthogonal array is used for design of experiments. The sequential approximate optimization of 3-bar and 10-bar trusses is demonstrated to verify the reliability of the sequential design domain method.

• Journal of the Korean Chemical Society
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• v.20 no.5
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• pp.333-339
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• 1976

The rates of solvolysis for 2-thenoyl chloride have been measured in aqueous acetone and aqueous ethanol at various temperatures ranging from 20 to $40^{circ}C$. The activation parameters and the Grundwald-Winstein's slope are determined by the analysis of solvolysis rates. The results indicated that the reaction rates of solvolysis are considerably slower than those of the reaction for benzoyl chloride due to the electron donating effect of thiophene nucleus. The results also showed that the reaction proceeds with the $S_N1$ mechanism in water-rich solvents whereas the $S_N2$ character increases with the decrease of water content, and overall reaction is subject to entropy control.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.766-771
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• 2012

PC (polycarbonate) is one of the widely used engineering plastics. Polycarbonate (PC) is traditionally produced by the reaction of phosgene and bisphenol-A. This phosgene process has the disadvantage as the high toxicity and corrosiveness of phosgene. The main point of focus to overcome the disadvantage of phosgene based process has been a route through dimethyl carbonate (DMC) to diphenyl carbonate (DPC). In this paper, for the DPC synthesis reaction using PBO as a catalyst, the effect of reaction temperature, reactant ratio, catalyst concentration on the reaction yield was investigated. A kinetic model for the DPC synthesis reaction was proposed and kinetic parameters for the proposed model was determined from batch reactor experiments. The predicted results by the proposed model were in good agreement with the experimental results.

• Korean Journal of Microbiology
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• v.29 no.4
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• pp.258-262
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• 1991

Rate of 11.alpha.-hydroxylation of progesterone with Rhizopus nigricans was accelerated by glucose. Glucose seemed to play an important role in the formation of cofactor because its effects on the reaction were almost same as those of electron acceptors such as NADPH and $NaIO_{4}$. Rate of glucose consumption appeared to increase in proportion as the rate of hydroxylation reaction, which enhanced with increase in the glucose concentration to level off at 0.5 g/l for mycelia and at 20 g/l for spores. However, for mycelia immobilized in polyacrylamide gel, externally added glucose did not affect the reaction rate at all because of the glucose accumulated in the gel during the cultivation period. 5.alpha.-Reduction of 11.alpha.-hydroxyprogesternoe required much higher concentration of glucose than 11.alpha.-hydroxylation of progesternoe so that high yield of 11.alpha.-hydroxyprogesternoe can be obtained by repressing the activity of 5.alpha.-reductase at low concentration of glucose.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.58-67
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• 2013

PBT (polybutylene terephthalate) has excellent mechanical properties such as low absorption, dimensional stability, abrasion resistance. It is used in manufacturing electronic components, the automobile part and the various precise parts. Bis (hydroxybutyl) terephthalate (BHBT) which is a PBT monomer, can be produced by transesterification reaction of DMT (dimethyl terephthalate) with 1,4-butandiol (BD). The kinetics of transesterification reaction of DMT with BD using zinc acetate as a catalyst was studied in a batch reactor. Previous kinetic studies was carried out in a semibatch reactor where generated methanol was removed so that reverse reactions were not considered in the kinetic expressions, resulting in inaccuracy of the kinetic model. Mathematical models of a batch reactor for the transesterification reaction were developed and used to characterize the reaction kinetics and the composition distribution of the reaction products. More accurate models than previous models was obtained and found to have a good agreement between model predictions and experimental data.

• Journal of the Korea Concrete Institute
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• v.21 no.2
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• pp.179-186
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• 2009

The peculiarity pointed out for high strength concrete is the occurrence of spalling during a fire. Recently, there are many efforts such as development of all types of spalling reducing materials and other innovative materials in various fields. Need is now to examine the adequate mixing proportions of these materials. This study intended to derive experimentally and statistically mix proportions that can represent the basic quality requirements as well as the optimal effects on the fire-resistance for 4 types of functional materials that are metakaolin, waste tire chip, polypropylene fiber and steel fiber. Here, the tests were planned through an optimal test method using an orthogonal array table with 4 parameters and 3 levels. The statistical analysis adopted the response surface analysis method. Results verified mutual complementary contribution between the materials when using a combination of the functional materials selected as parameters for the strengthening of the fire-resistance of 80 MPa-class high strength concrete. Besides, the optimal conditions of the fire-resistance strengthening materials derived through response surface analysis were a volumetric replacement of silica fume by 80% of metakaolin, a volumetric replacement of fine aggregates by 3% of tire waste chip, and an addition of 0.2% of the whole volume by polypropylene fiber without mixing of steel fiber. In such cases, the basic characteristics as well as the fire-resistant characteristics of high strength concrete were also satisfied.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1991.04a
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• pp.53-56
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• 1991

산업구조의 급속한 발전과 공업화는 사회구조의 변화 및 대도시로의 인구집 중, 고밀도화, 교통량의 증가를 초래하여 이로부터 기인한 도시지역의 환경 오염 문제는 쾌적한 인간생활을 위협하는 단계에까지 이르렀다. 그중에서 소 음에 관한 문제도 대기 및 수질의 오염과 동시에 도시생활 환경에 많은 영 향을 미치게 되었다. 도시 소음의 주 원인은 주로 도로교통소음이며 이는 기 하급수적으로 늘어가는 자동차의 양에 의해 더욱 심해지고 있다. 따라서 현 재 우리나라에서도 주거지역 및 준주거지역 등의 지역별 소음도 규제 및 신 설되는 공동주택 단지에서의 소음레벨규제등이 있긴 하나 이들은 상당히 소 극적이며 미온적일 뿐 아니라 실제 거주하는 주민들의 반응과는 상당한 차 이를 보이고 있으며 더욱이 주민의 소음에 대한 주관적 반응을 적절히 표현 할 수 있는 지표마저 명확하지 않은 실정이다. 이러한 관점에서 본 고찰에서 는 피험자들의 주관적 반응을 실험할 때 발생하는 변수요인들을 통제 할 수 있는 실험 실시행 청감실험을 실시하기에 앞서 대상지역의 도로교통소음을 여러가지 평가척도에 의해 평가한 후 그 현장에서 이 소음에 노출된 피험자 들의 반응을 파악하여 청취자들이 인지하는 소음레벨을 적절히 평가하는 지 표를 찾고자 한다.

• Korean Journal Plant Pathology
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• v.3 no.3
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• pp.198-202
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• 1987

Toxic metabolites ('Toxins'), produced by Helminthosporium sativum causing leaf blotch in barley and root rot in barley and wheat were partially purified through C-18 column. The partially purified toxins appeared heat unstable and lipophilic. The responses of toxins to wheat and barley root corresponded with those to lettuce growth with the different concentrations. The determination of the concentration of toxins produced was developed using the dilution end-points. The equation [Y = a log X + b) was obtained from the semi-log­graphy with the linear analysis. The values 'a' and 'b' were discussed with the responses of several plants on the toxin produced by H. sativum.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.1
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• pp.84-90
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• 2017

It is observed that chemical characteristics of HTPB(Hydroxyl Terminated Polybutadiene) binder such as OH index, molecular weight and functionality and so on, can be different with synthetic batch, which can affect curing reaction of binder in itself or propellant. Finally this reaction can also affect mechanical properties of propellant. And the results suggest that proper degree of curing reaction is necessary to obtain better mechanical properties of propellant.

• Analytical Science and Technology
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• v.36 no.6
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• pp.332-339
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• 2023

This study aimed to verify the hypothesis that urea denatures hemoglobin in the blood, thereby exposing active sites of enzymes and enhancing the chemiluminescence of the blood-luminol reaction. When blood was pretreated with urea, higher concentrations of pretreatment urea or longer pretreatment times resulted in enhanced chemiluminescence in the blood-luminol reaction, supporting the above hypothesis. However, the chemiluminescence was enhanced when blood was treated with luminol mixed with an 8 M urea solution, although the fact that the time for urea to denature hemoglobin was shorter compared to when blood was pretreated with urea and followed by luminol. In addition, the chemiluminescence was enhanced when a transition metal without hemoglobin was reacted with urea-containing luminol. Based on these results, it is anticipated that urea not only denatures hemoglobin but also plays a role in the luminol-hydrogen peroxide reaction.