• Title/Summary/Keyword: 반응성 상호작용

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하이드록시 아파타이트와 폴리락타이드 복합체에서 특수 상호작용력의 도입과 기계적 물성

  • Lee, Jun-Geun;Lee, Won-Gi
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.529-532
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    • 2008
  • 본 연구에서는 생체 적합성이 뛰어난 HA와 생분해성고분자인 PLLA와의 낮은 혼합성을 개선하기 위하여 HA를 화학적으로 개질하여 PLLA와의 특정 상호 작용력을 부여함으로서 HA/PLLA 복합체의 기계적 물성을 높이는 연구를 수행하였다. TGA분석으로부터 개질된 HA은 6wt% lactic acid 와 7 wt% DLA가 반응하였으며 HA에 비하여 유기용매에 대한 분산안정성이 증가하는 것으로 나타났다. 용매-비용매 방법으로 제조된 HAAD/PLLA 복합체는 DSC측정으로부터 개질된 HA의 DLA 사슬과 PLLA의 LLA사이에 스테레오 콤플렉스를 형성에 의하여 HA가 PLLA사이에 균일하게 분산되었고 상분리 구조의 미개질 HA/PLLA 복합체에 비하여 기계적 물성이 증가하는 것으로 나타났다.

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The Effect of Interaction between Learning Orientation and Environmental Uncertainty on Marketing Capabilities in the IT Firms (IT기업의 학습지향성과 환경불확실성의 상호작용이 마케팅역량에 미치는 영향)

  • Kim, Dong-Gun;Shin, Tack-Hyun
    • Journal of the Korea Society for Simulation
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    • v.25 no.3
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    • pp.125-132
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    • 2016
  • This study intended to exploratively depict the influence of interaction between Environmental Uncertainty and Learning Orientation of Korean IT companies on Marketing Capability which was adopted as one of the organizational performance indicator. Statistical Results based on AMOS and SPSS showed that smaller-sized companies under 500 employees are more inclined to desperately and flexibly meet and adapt to their environmental uncertainty, resulting positive performance, that is, marketing capabilities. On the other hand, larger-sized companies over 500 employees showed no significant interaction effect. This result of the study induces the reasoning that the differences in competitive environment and market leadership accrued by organizational size may also incur differences in environmental adaptive mechanism. However, this reasoning can have some limitation in that the types and traits of IT firms are so different. Therefore, this topic suggests the necessity of follow-up researches using enlarged samples in IT industry and comparative studies in other industries.

The Effects of Reactive Nitrogen (Nr) Compounds on the Acidification in Soil and Water Environment Ecosystems and the Mitigation Strategy (반응성 질소화합물로 인한 토양 및 물 환경 생태계의 산성화 영향 및 대응방안)

  • Cho, Youngil;Kang, Hyesoon;Jeon, Eui-Chan
    • Korean Journal of Ecology and Environment
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    • v.49 no.1
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    • pp.1-10
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    • 2016
  • The increases of industrial and technological development and human activities have disturbed the balance of natural nitrogen (N) circulation. These phenomena have induced that large amounts of N are to be present in excess in air, soil and water environment. We investigated the effects of excess of reactive nitrogen ($N_r$) compounds on soil and water environment ecosystems through literature and case studies, and suggested the strategy of mitigating the acidification in soil and water ecosystems. $N_r$ moves to air, soil and water media, can be converted to different types, and interacts with other chemical compounds. As an efficient N management plan, the evaluation (application of monitoring and safety index) and the chemical restoration (research and development) of the acidification in soil and water environment ecosystems are required to minimize the effects of $N_r$ as well as policies to regulate the various emission sources and amounts of $N_r$.

Interaction Patterns in Dialogic Inquiry of Middle School Students in Small Groups in the Natural History Gallery (자연사관 관람에서 중학생 소집단의 대화적 탐구에서 나타나는 상호작용 유형)

  • Jung, Won-Young;Lee, Joo-Youn;Park, Eun-Ji;Kim, Chan-Jong;Lee, Sun-Kyung
    • Journal of the Korean earth science society
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    • v.30 no.7
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    • pp.909-927
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    • 2009
  • Inquiry became an essential methodology in science education. Recently, argumentation becomes more important in inquiry, but inquiry-based teaching in school science would not provide enough opportunities for students to have voluntary and active interactions during inquiry activities. Informal science learning can be an alternative for authentic inquiry. Accordingly, this study aims to find interaction patterns in dialogic inquiry of junior high school students in small groups in the natural history gallery. Inquiry elements and interaction patterns are analyzed with 42 dialogues of 13 small groups. As a result, seven interaction patterns are identified. First, five major interaction patterns were drawn as follows; Sharing questions, asking questions and simple response, asking questions and simple explanation, asking questions-simple explanation-(collecting data)-data based explanation, and asking questions-collecting data-data based explanation. Second, pattern 2, 'asking questions and simple response', is subdivided into three categories; passive and/or evasive response, inaccurate response, and repeated patterns of asking questions-simple response. The results of the study provide different patterns of dialogic interactions in a small group inquiry in informal contexts from formal contexts, and provide foundations to understand middle school students' interactive dialogues of inquiry occurred in the natural history gallery.

Synthesis and Blood Compatibility of New Biocompatible Copolypeptides : Blood Compatibility of Copolypeptide Having Ethylene Glycol Oligomers Substituted in the Side Chain (새로운 생체적합성 폴리펩티드공중합체의 합성과 혈액적합성에 관한 연구 : 측쇄에 에틸렌글리콜을 함유하는 폴리펩티드 공중합체의 혈액적합성)

  • Inn-Kyu Kang;Sang Dong Park;Chong Su Cho;Yong Kiel Sung
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.947-954
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    • 1992
  • Polyethylene glycol (PEG) grafted poly (γ-benzyl L-glutamate) (PBLG) was synthesized by the substitution reaction of PBLG and PEG having primary amino groups at both ends. PEG-g-PBLG films containing hydroxyl group were also prepared by the substitution reaction of PEG-g-PBLG film and ethanolamine (EA). Adhesion of platelets and activation of plasma proteins on the copolypeptide films were studied. The results showed that platelets are less adhered and activated on the PEG-g-PBLG than on other polypeptides and plasma recalcification time (PRT) on the PEG-g-PBLG was longer than that on other polypeptides. These results were consistent with those of blood clotting time and thrombus formation on the polypeptides. As a results, PEG-g-PBLG surfaces showed better blood compatibility than PBLG or PEG-g-PBLG-EA surfaces.

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Genotype $\times$ Environment Interaction of Rice Yield in Multi-location Trials (벼 재배 품종과 환경의 상호작용)

  • 양창인;양세준;정영평;최해춘;신영범
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.6
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    • pp.453-458
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    • 2001
  • The Rural Development Administration (RDA) of Korea now operates a system called Rice Variety Selection Tests (RVST), which are now being implemented in eight Agricultural Research and Extension Services located in eight province RVST's objective is to provide accurate yield estimates and to select well-adapted varieties to each province. Systematic evaluation of entries included in RVST is a highly important task to select the best-adapted varieties to specific location and to observe the performance of entries across a wide range of test sites within a region. The rice yield data in RVST for ordinary transplanting in Kangwon province during 1997-2000 were analyzed. The experiments were carried out in three replications of a random complete block design with eleven entries across five locations. Additive Main effects and Multiplicative Interaction (AMMI) model was employed to examine the interaction between genotype and environment (G$\times$E) in the biplot form. It was found that genotype variability was as high as 66%, followed by G$\times$E interaction variability, 21%, and variability by environment, 13%. G$\times$E interaction was partitioned into two significant (P<0.05) principal components. Pattern analysis was used for interpretation on G$\times$E interaction and adaptibility. Major determinants among the meteorological factors on G$\times$E matrix were canopy minimum temperature, minimum relative humidity, sunshine hours, precipitation and mean cloud amount. Odaebyeo, Obongbyeo and Jinbubyeo were relatively stable varieties in all the regions. Furthermore, the most adapted varieties in each region, in terms of productivity, were evaluated.

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Electrocatalytic alcohol oxidation on Pt/ATO nanoparticle (ATO nanoparticle에 담지된 백금 촉매의 전기화학적 알콜 산화 반응에 관한 연구)

  • Lee, Kug-Seung;Park, In-Su;Jung, Dae-Sik;Park, Hee-Young;Sung, Yung-Eun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.463-466
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    • 2006
  • 직접 알콜 연료전지는 액체인 알콜을 직접 연료전지에 공급하여 연소시킴으로써 높은 효율을 갖는 휴대용전원으로 주목받는 장치이다. 직접 알콜 연료전지에 담지체로 사용되는 탄소 소재는 넓은 표면적과 우수한 전기전도도를 가지고 있다는 장점 있으나 금속 촉매와의 상호작용이 약하여 촉매 활성에 영향을 주지 못한다. 산화물을 담지체로 사용할 경우 이러한 금속-담지체 간의 상호작용으로 인한 촉매활성 증가 및 입자성장 억제의 효과를 기대할 수 있다. 본 연구에서는, 안티몬 도핑된 주석산화물 (Sb-doped SnO2 : ATO nanoparticle)을 직접 메탄올 연료전지용 담지체어 적용하였으며 합성 과정은 다음과 같다. SnC14 5H2O SbC13, NaOH, HCl 수용액 혼합물을 삼구 플라스크에 넣고 $100^{\circ}C$ 온도에서 환류(reflux) 시킨 후 세척 및 건조하여 Air 분위기에서 열처리하였다. 합성된 산화물 수용액에 폴리올 방법으로 합성된 백금 콜로이드를 담지하였으며, 세척과 건조를 통하여 산화물에 담지된 백금 촉매를 촉매를 합성하였다. 촉매의 구조분석을 위해 XRD, TEM을 사용하였으며, 전극촉매로서의 활성을 평가하기 위해 cyclic voltammetry을 평가하였다. 본 연구에서는 백금의 담지량에 따른 Costripping voltammetry특성과 메탄올 및 에탄올 산화 반응 특성에 대하여, 탄소를 담지체로 사용한 Pt/C 촉매와 비교 평가하였다. 알콜 산화반응 평가결과, 주석산화물에 담지한 촉매가 탄소를 담지체로 사용한 촉매보다 우수한 활성을 나타내었으며 활성증가는 메탄올에 비해 에탄올 산화 반응의 경우 크게 증가하였다. 막과 비교해 보았다. $ZrO_2$ 입자는 전도성이며 동시에 친수성을 나타내기 때문에 상용 막에 비하여 함수율 및 수소이온 전도도가 우수하게 나타났다. 복합막의 이러한 물성은 $100^{\circ}C$이상의 고온에서 전해질 막 내의 물 관리를 용이하게 한다. 단위 전지 운전 온도 $130^{\circ}C$, 상대습도 37%의 운전 조건에서도 상당히 우수한 전지 성능을 보임에 따라 고온/저가습 조건에서 상용 Nafion 112 막보다 우수한 막 특성을 나타냄을 확인하였다.소/배후방사능비는 각각 $2.18{\pm}0.03,\;2.56{\pm}0.11,\;3.08{\pm}0.18,\;3.77{\pm}0.17,\;4.70{\pm}0.45$ 그리고 $5.59{\pm}0.40$이었고, $^{67}Ga$-citrate의 경우 2시간, 24시간, 48시간에 $3.06{\pm}0.84,\;4.12{\pm}0.54\;4.55{\pm}0.74 $이었다. 결론 : Transferrin에 $^{99m}Tc$을 이용한 방사성표지가 성공적으로 이루어졌고, $^{99m}Tc$-transferrin의 표지효율은 8시간까지 95% 이상의 안정된 방사성표지효율을 보였다. $^{99m}Tc$-transferrin을 이용한 감염영상을 성공적으로 얻을 수 있었으며, $^{67}Ga$-citrate 영상과 비교하여 더 빠른 시간 안에 우수한 영상을 얻을 수 있었다. 그러므로 $^{99m}Tc$<

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Effects of Nitrofurantoin on Lipid Peroxidation and Reactive Oxygen Radical Generation in Porcine Lung Microsome (Nitrofurantion이 폐장 미크로솜 지질과산화와 반응성 산소 라디칼 생성에 미치는 영향)

  • Paick, Jae-Seung;Kim, Si-Whang;Kim, Hae-Won;Chung, Myung-Hee;Kim, Myung-Suk
    • The Korean Journal of Pharmacology
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    • v.21 no.1
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    • pp.34-48
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    • 1985
  • In vitro effects of nitrofurantoin, an antimicrobial agent for acute and chronic urinary tract infection, on the lung microsomal lipid peroxidation and the generation of reactive oxygen radicals were investigated to elucidate the biochemical mechanisms of its in vivopulmonary toxicity. The interaction of nitrofurantoin with porcine lung microsome resulted in significant lipid peroxidation. In addition, nitrofurantoin stimulated the generation of reactive oxygen radicals, $O^{-}_{2}{\cdot},\;H_2O_2$ as well as a highly reactive secondary oxygen species, $OH{\cdot}$. The stimulation of lipid peroxidation was inhibited not only by superoxide dismutase and catalase, but also by hydroxyl radical scavengers, mannitol and thiourea. Neither singlet oxygen $({^1}O_{2})$ was detected during the incubation of microsome with nitrofurantoin, nor lipid peroxidation was inhibited by singlet oxygen scavengers. When incubated anaerobically under the nitrogen atmosphere, the ability of nitrofurantoin to stimulatle lipid peroxidation was abolished. It appears that NADPH-dependent metaboliam of nitrofurantoin in pulmonary microsome under aerobic condition is accompanied by the stimulation of lipid peroxidation through the mediation of reactive oxygen radicals, particularly hydroxyl radical. It is strongly suggested from these results that the stimulation of pulmonary microsomal lipid peroxidation by the reactive oxygen radical may be a in vivo mechanism of pulmonary toxicity caused by nitrofurantoin.

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Research on the Interaction of Pressed Flowers as a Servicescape (압화 조형물의 서비스스케이프로서의 상호작용연구)

  • Shin, Jung Ok;Lee, Jin Ho
    • Journal of the Korean Society of Floral Art and Design
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    • no.43
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    • pp.101-122
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    • 2020
  • In this paper, the social paradigm is rapidly changing with the expansion of human consciousness, which has emerged as the development of 20th century science and the influence of cutting-edge media as the search for new forms of flower art sculptures. Is becoming. Accordingly, the purpose of this study is to analyze the interaction relationship of the expression elements of environmentally friendly pressed sculptures in the space as interior materials in the space where customer service is provided. (Research method) After deriving the formative expression characteristics of environmentally friendly pressed flower sculptures, and deriving interactive analysis elements between the servicescape space and humans of the pressed flower sculptures through references, service the flower sculptures for 8 installation cases The expression patterns of the interrelationships in the space of the landscape of the landscape were analyzed. (Results) The characteristics of dynamic formation and continuity were emphasized in the environment-friendly pressed sculpture space, and the interaction that the sympathetic reaction to the natural motif element felt as a new experience in space appeared. In the future, commercial spaces can be actively experienced through natural elements, and users can experience active interactions to create differentiated spaces as spaces where humans and humans coexist.

Research on Emotional Convergence Technology based on Non Contact Sensing and Social Interaction. (비접촉 센싱 기술과 사회적 상호작용에 따른 감성융합기술 연구)

  • Hwang, Sung Teac;Whang, Mincheol
    • Journal of the Korea Convergence Society
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    • v.8 no.6
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    • pp.163-170
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    • 2017
  • In this paper want to recognize competition and cooperation as a non-contact sensing method among the social emotion that are caused by interaction. Experiments were conducted in a pattern matching task divided into competition and cooperation situations. Data collection was performed by extracting the micro-movement data of 15Hz component from the upper body image. We compared and analyzed the amount and the variation and synchronization. As a result, Amount and variation are bigger in competition than cooperation. Synchronization was higher in cooperation than competition. This can be seen as the difference between two people trying to win when they are in competition and trying to breathe each other in cooperation. This study is significant in confirming the possibility of competition and cooperation through non contact sensing method based on physiological response.