• Title/Summary/Keyword: 반응성 분쇄

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Synthesis of zeolite with reaction temperature and alkali concentration from coal bottom ash (화력발전소 바닥재로부터 합성된 제올라이트의 반응온도와 알칼리 농도에 따른 상변화에 대한 연구)

  • Jun So-Youn;Han Gi-Chun;Ahn Ji-Whan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.5
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    • pp.204-210
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    • 2004
  • Though the recycling rate of coal fly ash generated from domestic thermoelectric power plants is gradually increased, at present, the most amount of coal bottom ash is disposed by a landfill instead of recycling. Therefore, to reuse a coal bottom ash as high-value materials the synthesis of zeolite made from a coal bottom ash was investigated in this study. NaPl, hydroxy-sodalite and tobermorite were produced through the alkaline hydrothermal reaction of pulvelized bottom ash at various temperatures; 80, 120, $150^{\circ}C$, and the concentration of NaOH at the range from 1 to 5 M. Especially, NaPl with excellent cation exchange capability had a high crystallinity at ${\leq}2$ M NaOH and ${\leq}120^{\circ}C$.

Protein composition and antigenicity of the tegument from Paragonimus westermani (폐흡충 총체표피의 단백질 조성 및 항원성)

  • 김석일;조승열
    • Parasites, Hosts and Diseases
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    • v.31 no.3
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    • pp.269-276
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    • 1993
  • To ascertain that tegument of Pnragonimus westermoni has specific antigenic proteins, the tegumental fraction was isolated from 10-month-old worms by 0.1% digitonin solution, and subjected to SDS-PAGE and immunoblot. Component proteins of tegumental syncytium comprised of 94, 74 (76-66), 62, 54, 44, 42, 38, 28, 26, 25, 24, 17, 15.5 and 13.5 kDa proteins. Of them, the 94, 44 and 42kDa proteins were more specific to tegument, especially the 94 kDa protein was the most prevailing one. In immunoblot, antigens of the 94, 90, 78, 76, 74, 68, 65, 63, 60, 59 and 54 kDa proteins were commonly detected by 7 sera of 10 human paragonimlasis, but none of them reacted with 5 sera of clonorchiasis. In conclusion, the 94 kDa protein was the major tegumental protein, as well as the specific antigen. The 76 and 66 kDa proteins were the minor components of tegument, which were also specific antigens of R westermcni.

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Immunogenicity and Protective Efficacy of Solubilized Merozoite-enriched Theileria sergenti Immunogens I: Protection against Homologous Stabilate Challenge (Theileriu sergenti merozoite 수용성 항원의 항원성과 면역성)

  • 백병걸;최인혁
    • Parasites, Hosts and Diseases
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    • v.30 no.2
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    • pp.133-140
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    • 1992
  • Theileria sergenti were isolated from infected erythrocytes by hypotonic Iysis, and soluble meroBoite antigens were purified by sonication and differential centrifugation. The preparation contained 29, 34, 35 and 105 kD immuno-dominant polypeptides. The soluble antigens (0.5 mg/ml) were prepared and fortified with Freund's adjuvant. Five month old naive Korean calves were subcutaneously inoculated with the preparation and a booster dose was administered 4 weeks later Nine weeks after the booster dose, vaccinates and controls were challenged with a homologous stabilate (5.6×106 RBC/dose, 40% Parasitemia). All animals were monitored for hematocrit, total erythrocyte count, parasitemia and for the specific antibody by Western immuno- blot (WB) and indirect immuno-auorescent antibody(IFA) test. By 18 weeks after vaccination (6 weeks after the challenge), vaccinated cattle had an average IFA titer of 1 : 10,240 compared with 1 : 1,280 of the controls. The vaccinates showed ne91igib1e change in hematocrit and total RBC count whereas control animals showed significant (P<0.05) hematological chanties and associated anemia. After vaccination and challenge, the antibody responses demonstrated that vaccination had induced significant production of antibody to the 29 and 35 kD polypeptides. The latter polypeptide was much more strongly recognized by the vaccinated animals, and thus it may be a potential candidate for the vaccine.

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Effect of the Fineness of Fly Ash on the Compressive Strength (플라이애시 입도가 압축강도에 미치는 영향)

  • Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Ahn
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.313-319
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    • 2017
  • In general, various factors such as grain size, chemical composition, amorphous amount, amorphous Si and Al content of fly ash affect the reaction with cement. In this study, we investigate the effect of fly ash particle characteristics on compressive strength. The standard sand was pulverized to a particle size similar to that of fly ash and the compressive strength was measured by blending with the cement as in fly. Using the measured compressive strength results, strength enhancement by cement hydration reaction and strength enhancement by particle filling effect were confirmed. Strength increment by pozzolanic reaction of fly ash was calculated by using the compressive strength results of mortar substituted with standard powder. As a result of comparison between compressive strengths and the particle characteristics of fly ash, the blaine showed a weak correlation with the compressive strength and the PI(Pozzolanic Index) showed good correlation with the 10% penetration diameter(D10) and the 50% Respectively. Therefore, it is expected that PI will be a good means to evaluate the fly ash characteristics together with the chemical characteristics of fly ash.

An Innovative Process for High Fructose Corn Syrup Production Coupled with Direct Saccharification of Raw Corn Starch in a Bioattritor (생전분의 고농도 무증자당화법을 도입한 새로운 High Fructose Corn Syrup 제조공정)

  • 박동찬;이용현
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.437-444
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    • 1992
  • An innovative process for high fructose corn syrup (HFCS) production coupled with direct saccharification of raw corn starch in the agitated bead enzyme reactor (bioattitor) was investigated. The required high concentration/purity of glucose solution suitable for isomerization was produced directly in a bioattritor. without condensation of hydrolyzate, 398 g glucose/$\ell$ and 98% glucose content from 400 g/$\ell$ (w/v) of raw corn starch after 24 hours. The unsaccharified residual starch could be separated easily upon centrifugation, and resaccharified. The obtained solution also possessed other desirable requirements as substrate for isomerization, such as. low concentrations of denatured protein and calcium ions, thereby, simplified the purification step. The obtained glucose solution was isomerized in an enzyme reactor paked with immobilized glucose isomerase to evaluate the suitability as a substrate. The proposed new HFCS process seems to have many advantages over the conventional process via liquefaction-saccharification steps. The follow-up investigations of the proposed process need to be conducted to evaluate the feasibility of industrial application.

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Preliminary Study on the Development of Alternative Methods for the Treatment of TRISO Fuels (TRISO 연료 대체 처리방법 개발에 관한 선행연구)

  • Lee Jong-Hyeon;Shim Joon-Bo;Ahn Byung-Gil;Kwon Sang-Woon;Kim Eung-Ho;Yoo Jae-Hyung;Park Seong-Won;Snyder Christine T.;Leibowitz Leonard
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.3
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    • pp.201-211
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    • 2005
  • In this study, conventional head-end processes of spent TRISO fuel have been reviewed to develope more effective treatment methods. The main concerns in the TRISO treatment are to effectively separate the carbon and SiC contained in the TRISO particles. The crush-burn scheme which was considered in the early stages of the development has been replaced by the crush-leach process because of $^{14}C$ problems as a second waste being generated during the process. However, there are still many obstacles to overcome in the reported processes. Hence, innovative thermomechanical concepts and a molten salt electrochemical approach to breach the coating layers of the TRISO particle with a minimized amount of second waste are proposed in this paper and their principles are described in detail.

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Electrochemical Properties of Needle Coke through a Simple Carbon Coating Process for Lithium Ion Battery (침상 코크스의 피치 코팅에 따른 리튬 이차전지 탄소계 음극소재의 전기화학적 특성)

  • Hwang, Jin Ung;Lee, Jong Dae;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.514-519
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    • 2020
  • Graphite materials for lithium ion battery anode materials are the most commercially available due to their structural stability and low price. Recently, research efforts have been conducted on carbon coatings by improving side reactions at the edge site of carbon materials. The carbon coating process has classified into a CVD by chemical reaction, wet coating process with solvent and dry coating by mechanical impact. In this paper, the rapid crush/coating process was used to solve the problem of which only few parts of the carbon precursor (pitch) can be used and also environmental problems caused by solvent removal in the wet coating process. When the ratio of needle coke to pitch was 8 : 2 wt%, and the rapid crush/coating process was carried out, it was confirmed that the fracture surface was coated by pitch. The pitch-coated sample was treated at 2400 ℃ and 41.8% improvement in 10C/0.1C rate characteristic was observed. It is considered that the material simply manufactured through the simple crush/coating process can be used as an anode electrode material for a lithium ion battery.

A study on the ecological lightweight aggregates made of bottom ashes and dredged soils (저회 및 준설토를 이용한 에코인공경량골재의 제조에 관한 연구)

  • Jeon, Hye-Jin;Kim, Yoo-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.133-137
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    • 2007
  • Ecological lightweight aggregates were made in order to recycle the dredged soils from the seaside construction area and the bottom ashes from the power plant. Various physical and chemical analysis were performed on them to identify their possibility for applying lightweight concrete fields. Lightweight aggregates were made of bottom ashes and dredged soils from Yongheung Island which is located 20km west away from Seoul, and all the raw materials were milled before mixing. The physical and chemical properties such as density, absorption rate, stability, alkali latency reaction, heavy metal leaching of the lightweight aggregates were tested and analysed by following the KS standard procedures. From the size analysis, the coarse aggregates showed a suitable fit on standard particle ranges; however, the fine aggregates showed a large deviation from the standard. The absorption rates were increased with decreasing weight of the aggregates. All the aggregates were turned out to be safe by the stability and heavy metal leaching test; however, some of the aggregates were confirmed on the border of harmless and possibly harmful region through the alkali latency reactivity test.

Hydriding and Dehydriding Rates of Magnesium-Nickel Alloy Fabricated by Milling under Hydrogen (수소 분위기에서 밀링에 의해 제조한 마그네슘-니켈 합금의 수소화물 형성 및 분해 속도)

  • Song, Myoung-Youp;Baek, Sung-Hwan;Park, Hye-Ryoung
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.787-793
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    • 2011
  • A 76.5wt%Mg - 23.5wt%Ni (Mg-23.5Ni) sample was prepared by reactive mechanical grinding (RMG) and its hydriding and dehydriding properties were then investigated. Activation of the Mg-23.5Ni sample was completed only after two hydriding (under 12 bar $H_2$) - dehydriding (under 1.0 bar $H_2$) cycles at 593K. The reactive mechanical grinding of Mg with Ni is considered to facilitate nucleation and shorten diffusion distances of hydrogen atoms. After hydriding - dehydriding cycling, the Mg-23.5Ni sample contained Mg2Ni phase.

Reaction Characteristics of the CAC with Various Gypsum Type and Mixing Ratio (석고 종류 및 혼입률에 따른 CAC 반응 특성)

  • Choi, Sun-Mi;Kim, Jin-Man;Koo, Ja-Sul
    • Resources Recycling
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    • v.30 no.1
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    • pp.83-91
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    • 2021
  • Ladle furnace slag is a byproduct of the steel-making process, and it contains the mineral β-C2Sandtherapid-settingmineral (dependingonwhichreducingagenthasbeenused). Ladle furnace slag is often treated through slow cooling, which causes the slag to lose its reactivity. In this study, the properties of air-quenched CAC and pulverized ladle furnace slag containing gypsum were evaluated, and the optimal mixing ratio was determined for broadening their usage. Consequently, the properties of CAC aredemonstrated by the dissolution of gypsum after a period of three hours and the content of gypsum after a period of one day. The optimal mixing ratio of anhydrate and hemihydrate gypsum is found to be within 30% and that of dihydrate gypsum is found to be higher than 35%. Furthermore, based on the results of CAC with dihydrate gypsum, the applicability of the by-product dihydrate gypsum has been verified.