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Studies on Preparation of Resion-Metal Chelates and Its Catalytic Activity for the Oxidation of Hydroxy Compounds and l-Ascorbic Acid (Resin-Metal Chelate의 제조와 Hydroxy화합물 및 l-Ascorbic Acid의 산화 촉매효과에 관한 연구)

  • Whang Kyu-Ja;Lee Young Sun;Kim Young Mi;Lee Yong-Keun
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.113-119
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    • 1989
  • Chelating resins containing hydrazide or triethylenetetramine side chain were prepared using a commercial cation exchage resin, Diaion WK 11, and their nitrogen contents were determined by elemental analysis. The synthesized resin, and commercial chelating resins, (Diaion-CR 10 and-CR 20) were treated with various metal chelates of which metal contents were subsequently determined by chelatometry. Sectioned beads of the resin-metal chelates were also observed using electron microprobs X-ray analyzer. To examine the catalytic activity of the resin-metal chelates, they were applied to the oxidation of various hydroxy compounds and l-ascorbic acid, and found to be effective catalysts.

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Fracture behavior of DGEBA/MDA/SN System (DGEBA/MDA/SN 계의 파괴 거동)

  • Jo, Seong-U;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.3 no.2
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    • pp.140-144
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    • 1993
  • Abstract To modify brittleness among the properties of thermosetting epoxy resin, a reactive additive. succinonitrile(SN) was introduced to Diglycidyl ether of bisphenol A(DGEBA)-4, 4'-methylene dianiline (MDA) system. Fracture behavior was microscopically studied during breaking of composite materials. As a result, post debond friction energy was the most significant for breaking the composite having glass fibres, pull-out energy was the next significant and debonding energy was the last. It was observed that shear stress between glass fibre and epoxy matrix was main factor for fracture behavior. Reactive additive, SN made shear stress deteriorated.

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Numerical Optimization of A Multi-Blades Centrifugal Fan For High-Efficiency Design (원심다익송풍기의 고효율 설계를 위한 수치최적설계)

  • Seo, Seoung-Jin;Kim, Kwang-Yong
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.385-390
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    • 2003
  • Shape of a multi-blades centrifugal fan is optimized by response surface method based on three-dimensional Navier-Stokes analysis. For numerical analysis, Reynolds-averaged Wavier-Stokes equations with standard $k-{\varepsilon}$ turbulence model are transformed into non-orthogonal curvilinear coordinate system, and are discretized with finite volume approximations. Due to the large number of blades in this centrifugal fan, the flow inside of the fan is regarded as steady flow by introducing the impeller force models for economic calculations. Optimizations with and without constraints are carried out. Design variables, location of cur off, radius of cut off, expansion angle of scroll and width of impeller were selected to optimize the shapes of scroll and blades. Data points for response evaluations were selected by D-optimal design, and linear programming method was used for the optimization on the response surface. As a main result of the optimization, the efficiency was successfully improved. The correlation of efficiency with relative size of inactive zone at the exit of impeller is discussed as well as with average momentum fluxes in the scroll.

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Design Optimization of A Multi-Blade Centrifugal Fan With Variable Design Flow Rate (설계유량을 변수로 한 원심다익송풍기의 최적설계)

  • Seo, Seoung-Jin;Kim, Kwang-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.11
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    • pp.1332-1338
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    • 2004
  • This paper presents the response surface optimization method using three-dimensional Navier-Stokes analysis to optimize the shape of a forward-curved blades centrifugal fan. For numerical analysis, Reynolds-averaged Navier-Stokes equations with k-$\varepsilon$ turbulence model are discretized with finite volume approximations. In order to reduce huge computing time due to a large number of blades in forward-curved blades centrifugal fan, the flow inside of the fan is regarded as steady flow by introducing the impeller force models. Three geometric variables, i.e., location of cut off, radius of cut off, and width of impeller, and one operating variable, i.e., flow rate, were selected as design variables. As a main result of the optimization, the efficiency was successfully improved. And, optimum design flow rate was found by using flow rate as one of design variables. It was found that the optimization process provides reliable design of this kind of fans with reasonable computing time.

Characteristics of Biodegradable Blends of PBAST and Chemically Modified Thermoplastic Starch (생분해성 PBAST와 변형 열가소성 전분 블렌드의 특성)

  • Shin, Boo-Young
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.580-585
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    • 2011
  • This article aims to enhance the biodegradability and environment-friendliness of petroleum based biodegradable poly(butylene adipate-co-succinate-co-terephthalate)(PBAST) by blending chemically modified thermoplastic starch(CMPS). CMPS is a kind of bio-based biodegradable resin which is manufactured by reacting starch with maleic anhydride(MA) in the presence of a plasticizer and a free radical initiator. The characteristic properties of PBAST/CMPS blends were investigated by observing their morphology, thermal, mechanical properties, and biodegradability. The good interfacial adhesion between the phases examined by SEM revealed that PBAST/CMPS blends were compatible blends. The tensile strength and elongation decreased with increasing CMPS content, while modulus increased. The biodegradability of the blends was much higher than that of pristine PBAST and increased with increasing CMPS contents.

The change of deflagration to detonation transition by wall cooling effect in ethylene-air mixture (에틸렌-공기 혼합물에서 벽면 온도 감소에 의한 연소폭발천이 현상 변화)

  • Gwak, Min-Cheol;Kim, ki-Hong;Yo, Jai-Ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.457-462
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    • 2011
  • This paper presents a numerical investigation of deflagration to detonation transition (DDT) induced by shock wave and flame interaction in ethylene-air mixtures. Also shows the change of DDT triggering time by wall cooling effect. A model is consisted of the compressible reactive Navier-Stokes equations. And the effect of viscosity, thermal conduction, molecular diffusion, chemical reaction and wall effect are included. Using this model, the generation of hot spot by repeated shock and flame interaction, occurrence of detonation, and wall cooling effect of detonation confining boundaries are studied.

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소상공인을 위한 라이브 커머스 방송은 정말 가능할까?: 쇼호스트 유형 및 관여도에 관한 실험 연구

  • Choe, Eun-Ji;Jang, Mun-Gyeong;Jeon, Seong-Min
    • 한국벤처창업학회:학술대회논문집
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    • 2022.11a
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    • pp.79-81
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    • 2022
  • 최근 정보기술의 발달과 COVID-19으로 인해, 많은 유통의 판도가 바뀌었다. 비대면의 급증으로 배달문화와 온라인 쇼핑과 온라인 회의 등이 성행하며 익숙해지고 이로 인해 디지털 전환이 더욱 빠르게 가속화 되었다. 중국에서 시작되었던 라이브 커머스도 이 시기를 틈타 한국으로 들어왔고 라이브 커머스의 발전이 시작되었다. 이에 따라 라이브 커머스에 관한 연구도 많이 나오고 있는데 연구들이 라이브커머스의 특성만을 다루는 것에 한계점을 느꼈다. 이에 본 연구는 라이브 커머스의 특성에서 나아가 이 특성으로 인하여 진정으로 혜택을 볼 수 있는 소상공인들에 초점을 맞추기로 하였다. 소상공인들이야말로 라이브커머스를 이용하는 80%를 넘는 비중을 차지하고 있는 사용자이자 판매자이다. 하지만 그럼에도 불구하고 아직까지도 많은 판매자들이 라이브커머스를 어렵게 생각하고 전문 방송인을 고용하거나 대행사를 고용하여야만 라이브커머스 방송이 가능하다고 생각하여 시작을 못하고 있다. 본 연구에서는 실험을 설계하여 판매자가 직접 라이브 커머스 방송을 진행하여도 충분히 소비자에게 긍정적인 영향을 줄 수 있고 매출액과 유입수에도 영향을 끼칠 것이란 가설을 설정하였다. 쇼호스트와 관여도라는 변수를 설정하여 2 by 2 실험을 설계하였다. 쇼호스트는 방송전문가인 일반적인 대행사를 섭외하여 방송을 능숙하게 하고 중간에 재미적인 요소를 집어 넣는 쇼호스트와 제품 전문가인 판매자를 직접 방송하게 하여 제품에 대한 전문성을 넣어 소비자의 반응을 살펴 보았다. 관여도는 고관여 제품과 저관여 제품을 식품군으로 비교하는 것으로 설계하는 것으로 연구를 진행하였다.

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Functional Magnetizing Treatment of Natural Quartz and Volcanic Lava Scoria (내추럴 퀄쯔와 화산암재 스코리아의 기능성 마그네타이징 처리)

  • 소대화;소현준;배두안;김정희
    • Journal of the Speleological Society of Korea
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    • no.63
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    • pp.1-8
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    • 2004
  • The non-magnetic materials with non-conductive showing high structure dispersity were developed on the base of natural quartz and lava-scoria which was collected from Je-ju island in Korea, and treated by methane-chemical technology those were obtained novel properties of magnetization through the analyzing. Depending on the processing conditions and subsequent applications the materials produced by strong methane-chemical reaction (MCR) in alcohol solution showed concurrently magnetic, dielectric and electrical properties. The obtained magnetic-electrical powders classified by aggregate complex of their features as segnetomagnetics, containing a dielectric material as a carrying nucleus, particularly the quartz on that surface one or more layers of different compounds were synthesized having thickness up to 10~50 nm and showing magnetic, electrical and other properties. It was confirmed in magnetizing process that powders of quartz and lava-scoria produced by MCR were better oil adsorbent as of oleophilic and floating matter on water surface although their specific gravities are comparably more than 1 in quartz or less than unity, as that of water, in lava-scoira. Therefore, it will be Possible and very useful to remove low density and light gravity oil spillage in difficult recovery from sea and inland water contamination spread on water surface, by marine accident and ship sinking accident occurring frequently in recent years, by way of magnetic adsorbent conveyer system in continuous, if it could be built up the mass Production system of water-floating magnetizable oleophilic adsorbent materials with use of iow cost and good Qualify lava-scoria spread on volcano district in Je-ju island. And, there will also be urgent advent of necessity with strong possibility to develop useful applications of various magnetic functional materials include oleophilic adsorbent for removal of sea oil-contaminants and maritime pollutants, and other kinds of various utilities in industrial applications and practical uses of novel functional materials in the fields of environments and health care applications with in deep expectation.

Effects of shoulder rotation according to stance posture and plane of motion on EMG response of shoulder rotator cuff and Trunk muscles. (스탠스 자세와 운동면의 차이에 따른 위팔어깨관절의 돌림운동이 어깨돌림근군과 몸통근군의 근전도 반응에 미치는 영향)

  • Kim, Ki-Hong;Cho, Sang-Woo;Jeong, Hwan-Jong;Kim, Ki-Hong
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.914-924
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    • 2018
  • The purpose of this study is to provide the basic data for the shoulder strengthening exercise by analyzing the% MVIC of the muscle activity in the shoulder rotator cuff by the difference of the stance posture and the anatomical plane. 8male subjects were randomly assigned to perform the shoulder rotation exercise 10 times on the frontal plane, the horizontal plane, the sagittal plane and the two legs stance posture, the one leg stance posture, the lunge posture. Measured muscle activity of supraspinatus, infraspinatus, teres minor, anterior deltoid, rectus abdominis, erector supinea, pectoralis major, lattisimus dorsi during exercise. A repetitive one-way ANOVA was performed using the SPSS 22.0 statistical program. First, during the external rotation on the frontal plane, the erector spinea was higher in the lunge posture than in the two legs stance posture and the one leg stance posture, And during the internal rotation on the frontal plane, the muscle activity of suprapinatus was higher in one leg stance posture than in the two legs stance posture and more so in the lunge posture. Second, during the external rotation on the horizontal plane, the muscle activity of deltoid anterior was higher in the one legs stance posture and in the lunge posture than in the two legs stance posture, and during the internal rotation on the horizontal plane, the muscle activity of infraspinatus was higher in the lunge posture than in the two legs stance posture and one leg posture, and the muscle activity of pectoralis major was higher in two leg stance posture than in the one legs stance posture and more so in the lunge posture. Third, during the external rotation on the sagittal plane, muscle activity of rectus abdominis was higher one leg stance posture in the lunge posture than in two leg stance posture. During the internal rotation on the sagittal plane, muscle activity of supraspinatus was higher one leg stance posture in the lunge posture than in two leg stance posture. And muscle activity of infraspinatus was higher in the lunge posture than in two leg stance posture, one leg stance. And muscle activity of Rectus abdominis was higher in the lunge posture and one leg stance posture than in the two legs stance posture. And muscle activity of Erector spinea was higher in the two legs stance postur and lunge posture than in the one leg stance posture. In conclusion, the differences in stance and shoulder anatomy have different effects on the muscle activity of the shoulder rotator exercises, and this is expected to be a more positive exercise program when applied to the shoulder strengthening exercise program.

Reviews on the Adaptation Strategy to Climate Change -Application to the Sea Level Rise- (기후변화 적응방안 연구 -해수면 상승을 중심으로-)

  • Cho Kwangwoo;Maeng Jun-Ho;Kim Hae-Dong;Oh Young Min;Kim Dong-Sun;Kim Mu Chan;Yoon Jong Hwui
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.10 no.2 s.21
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    • pp.81-88
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    • 2004
  • We review the adaptation strategies of the 21st climate change in an application to sea level rise. For the development of appropriate adaptation strategies on the coast vulnerable to the sea level rise, we have to consider the issues such as where to adapt, how to adapt, and when to adapt. The coastal target needed adaptation can be found by the evaluation of adaptive capacity of the coastal zone which requires the understanding of impacts and adaptive potential of the natural and socioeconomic systems in the coastal zone. Planned adaptation options to sea level rise can be classified into three generic approaches as managed retreat, accommodation, and protection In practice, the implementation of the options requires the analysis of land use, degree of vulnerability, cost and benefit, etc, and may be combination of the options rather than one approach. In terms of the response timing, the adaptation can be grouped as anticipatory and reactive ones. Generally it is more effective to consider both anticipatory and reactive adaptations at the same time for the impacts of future sea level rise. Due to the scientific uncertainty of climate change issues including sea level rise, the adaptation processes have to be designed to deal with a series of processes such as information md awareness establishment, planning and design implementation, and monitoring and evaluation in continuity and long-term period.

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