• Title/Summary/Keyword: 반응매질

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Development of an Oxide Reduction Process for the Treatment of PWR Spent Fuel (PWR 사용후핵연료 처리를 위한 금속전환공정 개발)

  • Hur, Jin-Mok;Hong, Sun-Seok;Jeong, Sang-Mun;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.77-84
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    • 2010
  • Reduction of oxides has been investigated for the volume reduction and recycling of the spent oxide fuel from commercial nuclear power plants. Various oxide reduction methods were proposed and KAERI (Korea Atomic Energy Research Institute) is currently developing an electrochemical reduction process using a LiCl-$Li_2O$ molten salt as a reaction medium. The electrochemical reduction process, the front end of the pyroprocessing, can connect the PWR (Pressurized Water Reactor) oxide fuel cycle to a metal fuel cycle of the sodium cooled fast reactor. This paper summarizes KAERI efforts on the development, improvement, and scale-up of the oxide reduction process.

Numerical Simulation of Diffusion and Flow in Fabrication of Carbon/Carbon Composite Using Chemical Vapor Infiltration (다단계 화학반응과 밀도화 모델을 이용한 탄소/탄소 복합재 화학기상침투 공정의 확산 및 유동 수치해석)

  • Kim, Hye-gyu;Ji, Wooseok;Jo, Namchun;Park, Jonggyu
    • Composites Research
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    • v.32 no.1
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    • pp.56-64
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    • 2019
  • In this paper, a model is developed to simulate carbon/carbon composite fabrication using chemical vapor infiltration, considering density and porosity change in the preform and multi-step hydrocarbons reactions. The model considers the preform as a porous medium whose diffusion and flow properties changes due to the porosity. To verify the theoretical model, two numerical analyses were performed for the case that the flow inside the preform is zero and the case that the flow inside the preform is calculated by fluid mechanics. The numerical results showed good agreement with the experimental data.

Preparation and Characterization of Poly(phenylene sulfide)-Functionalized MWNTs (폴리(페닐렌 설파이드)로 기능화된 다중벽 탄소나노튜브의 제조와 특성분석)

  • Hong, Sung Yeon;Kim, Young Ho
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.791-800
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    • 2014
  • 4-Chlorobenzoyl (CB) group-attached multi-walled carbon nanotube (c-MWNT) was prepared via a direct Friedel-Crafts acylation of MWNT with 4-chlorobenzoic acid (CBA) in a $P_2O_5$/poly(phosphoric acid) medium. c-MWNT with a maximum chlorine content of 5.3 wt% (CB group content of 20.9 wt%) was obtained by controlling the amount of CBA during the reaction. Using a self-condensation polymerization of 4-chlorobenzenethiol (CBT) to poly(phenylene sulfide) (PPS), MWNT-g-PPS was prepared by adding c-MWNT of chlorine content of 5.3 wt% during the self-polymerization of CBT and removing homo PPS after polymerization in order to increase the interfacial interaction between PPS and MWNT. Thermal and surface properties of the MWNT-g-PPS were characterized. The results showed that PPS was formed on the surface of c-MWNT by the condensation of c-MWNT and CBT.

An Interpretive Analysis of Magnetotelluric Response for a Three-dimensional Body Using FDM (FDM을 이용한 MT 탐사의 3차원 모형 반응 연구)

  • Han Nuree;Lee Seong Kon;Song Yoonho;Suh Jung Hee
    • Geophysics and Geophysical Exploration
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    • v.7 no.2
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    • pp.136-147
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    • 2004
  • In this study, the characteristics of magnetotelluric (MT) responses due to a three-dimensional (3-D) body are analyzed with 3-D numerical modeling. The first model for the analysis consists of a single isolated conductive body embedded in a resistive homogeneous half-space. The second model has an additional conductive overburden while the other conditions remain the same as the first one. The analysis of apparent resistivities shows well that the 3-D effects are dominant over some frequency range for the first model. Two mechanisms, current channeling and induction, for secondary electric fields due to the conductive body are analyzed at various frequencies: at high frequencies induction is more dominant than channeling, while at low frequencies channeling is more dominant than induction. Tippers have a strong relation to the position of anomalous body and the real and imaginary parts of induction vector also indicate the position of anomalous body. off-line conductive anomaly sometimes causes severe problem in 2-D interpretation. In such case, induction vector analysis can give information on the existence and location of the anomalous body. Each parameter of the second model shows similar responses as those of the first model. The only difference is that the magnitude of all parameters is decreased and that the domain showing the 3-D effects becomes narrower. As shown in this study, the analysis of 3-D effects provides a useful and effective means to understand the 3-D subsurface structure and to interpret MT survey data.

LNAPL Detection with GPR (GPR 탐사방법을 이용한 유류오염물질(LNAPL) 탐지)

  • Kim, Chang-Ryol
    • 한국지구물리탐사학회:학술대회논문집
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    • 2001.09a
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    • pp.94-103
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    • 2001
  • An experiment was conducted using a sand and gravel-filled tank model, to investigate the influence on the GPR response of vadose zone gasoline vapor phase effects and residual gasoline distributed by a fluctuating water table. After background GPR measurements were made with only water in the tank, gasoline was injected into the bottom of the model tank to simulate a subsurface discharge from a leaking pipe or tank. Results from the experiment show the sensitivity of GPR to the changes in the moisture content and its effectiveness for monitoring minor fluctuation of the water table. The results also demonstrate a potential of GPR for detecting possible vapor phase effects of volatile hydrocarbons in the vadose zone as a function of time, and for detecting the effects of residual phase of hydrocarbons in the water saturated system. In addition, the results provide the basis for a strategy that has the potential to successfully detect and delineate LNAPL contamination at field sites where zones of residual LNAPL in the water saturated system are present in the subsurface.

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A Technical Review on Principles and Practices of Self-potential Method Based on Streaming Potential (흐름 전위에 기초한 자연 전위 탐사법의 원리 및 활용)

  • Song, Seo Young;Nam, Myung Jin
    • Geophysics and Geophysical Exploration
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    • v.21 no.4
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    • pp.231-243
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    • 2018
  • Streaming potential (SP) arises from fluid flow through effectively connected pores. From this potential, formation water information as well as fluid flow properties can be estimated. As micro particles being located in boundary between subsurface porous media and fluid are charged to form electrical double layer, fluid flow caused by several reasons generates SP, one of electrokinetic phenomena. Occurrence mechanism of SP is complex and signal strength is relatively weak compared to noise. However, application of self potential survey using SP to monitoring of formation fluid is expanding because of its' convenience of exploration without artificial source and repetitiveness of signal. This paper accounts for the occurrence mechanism of SP studied before, including governing equations and analyzes previous various case studies of SP according to the change of physical properties of materials. It helps to increase understanding about SP and also lays the foundations of the application of SP to fields.

확산능을 이용한 지하 LPG 저장기지의 W/C 효율성 진단

  • 한일영;정일문;유홍정
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.31-34
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    • 2001
  • 지하 LPG 저장기지의 수벽시설이 저장공동 주변 암반에 미치는 영향을 진단하기 위해서 수벽시설의 주입압력을 강하시키면서 간극수압계와 관측공에서의 지하수두 변화를 모니터링하였다. 수벽시설의 관측지점에 대한 효율성은 수치해석으로부터 수벽시설과 관측지점간 매질의 확산능을 구함으로써 분석하였다. 확산능 산출결과를 검증하기 위해서 수벽시설의 압력강하에 따른 관측지점에서의 수두강하비와 수두강하율을 구하여 확산능 결과와 비교하였다. 비교결과, 확산능은 수두강하비, 수두강하율과 일관된 변화를 보여주었으며 확산능의 값이 클수록 수벽공의 압력변화에 따른 관측지점에서의 반응성이 양호함을 나타내었다

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Optimization of design parameters on the shroud of air conditioner outdoor unit (실외기 shroud 형상 최적 설계)

  • Ryu, Ki-Jung;Ye, Huee-Youl;Lee, Sang-Bong;Lee, Kwan-Soo;Cha, Woo-Ho
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.453-458
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    • 2009
  • This paper presents a numerical evaluation of the flow rate of air conditioner outdoor unit as function of shroud design parameters. To determine the optimal design parameters, we investigated the flow rate by changing bell mouth height, fan height, fan guide height, fan width. The evaluation of the relative priority of the design parameters was performed to choose three important parameters in order to use a response surface method. The flow rate of the optimum model, compared to that of the base model, was increased by about 6.25%.

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Optimization of Shroud Shape and Fan Location for Increasing Exhaust Flow Rate of Air Conditioner Outdoor Unit (실외기 토출 유량 증대를 위한 Shroud 형상 및 휀 위치 최적 설계)

  • Ryu, Ki-Jung;Kim, Yoo-Yil;Lee, Kwan-Soo;Cha, Woo-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.11
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    • pp.599-605
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    • 2009
  • This paper presents a numerical evaluation of the flow rate of air conditioner outdoor unit by investigating the effects of fan location and shroud shape. To determine optimal design parameters, we investigated the exhaust flow rate by changing shroud height, fan height, fan guide height, and fan width. The 3rd order central composite design was performed to select three most important parameters affecting the exhaust flow rate. According to the result of response surface method, the exhaust flow rate of the optimum model increased by 6.25% compared to that of the base model.

Design of Continuous-flow Micro-PCR System (연속류형 Micro-PCR 시스템의 설계)

  • Kim, Duck-Jong;Kim, Jae-Yun;Park, Sang-Jin;Heo, Pil-Woo;Yoon, Eui-Soo
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.115-120
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    • 2003
  • In this work, a continuous-flow micro-PCR system is systematically designed. From the numerical simulation based on the finite volume method, adapting oneself to a new environmental temperature without an external temperature controller is shown to be possible and a cooler as well as a heater is shown to be necessary to obtain three individual temperature zones for polymerase chain reaction. In addition, appropriate geometry of a heat sink for the cooler is determined by using a compact modeling method, the porous medium approach.

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