• Title/Summary/Keyword: 반응동역학

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An Optimization of Dynamic Elements for Eddy Current Braking System of High Speed Train (고속전철의 와전류 제동장치 동적 최적화 연구)

  • Park, Chan-Kyoung
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.345-350
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    • 2001
  • Dynamic behavior of high speed train is very important because the high speed train should be safe and satisfied with the ride comfort. An eddy current brake system is mounted on trailer bogie and wheelset. The eddy current braking force longitudinally exerts on the articulated trailer bogie and the attraction force vertically exerts on the wheelset. Because a frame of eddy current brake system is flexible, these forces generate the vertical vibration at middle point of the frame. Also, the vibration change the vertical clearance between an electromagnet and top of rail which affect the magnitude of braking and attracting forces. Therefore, the dynamic behavior of the eddy current braking system must be predicted for design the dynamic characteristic of its mounting system when normally operate on rail which have irregularity. Vampire program is used for prediction of the dynamic behavior of an eddy current braking system. Five design variables and five performance index are considered for optimization through D-optimal experimental design in this paper. Also model center is used to search the optimal point for sum of performance index with variational matric method.

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Frequency-Equivalence Ratio Correlation Analysis of Methane-Air Premixed Flame Influenced by Ultrasonic Standing Wave (II) (정상초음파의 영향을 받는 메탄-공기 예혼합화염의 주파수-당량비 상관도 분석(II))

  • Kim, Min Sung;Bae, Dae Seok;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.4
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    • pp.45-51
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    • 2015
  • An experimental study was performed for the analysis of frequency-equivalence ratio correlation in the methane-air premixed flame influenced by ultrasonic standing wave. The propagating flame was caught by high-speed Schlieren photography, and the variation of flame-behavior including the flame structure was investigated in detail employing a post-processing analysis of the high-speed images. It was found that a structural variation and propagation-velocity augmentation of the methane-air premixed flame by the intervention of ultrasonic standing wave were more caused off around the stoichiometry. Also, a dependency of the flame behaviors on the driving frequency and equivalence ratio of the reactants was confirmed.

Adsorption Characteristics of Brilliant Green by Coconut Based Activated Carbon : Equilibrium, Kinetic and Thermodynamic Parameter Studies (야자계 입상 활성탄에 의한 brilliant green의 흡착 특성 : 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.25 no.3
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    • pp.198-205
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    • 2019
  • The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.

Design of Aim Angle Following Guidance Law Using Lyapunov Theory (르야프노프 이론을 이용한 목표각 추종 유도법칙 설계)

  • Kim, Ki-Seok;Kim, You-Dan
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.7
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    • pp.81-89
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    • 2002
  • Guidance laws can be conceptually classified into three categories although their mathematical representations are various and different. In this paper, a generalized conceptual guidance law including the concepts of the above categories is proposed. The aim angle is introduced using the geometry of the collision triangle. The aim angle represents the arbitrary angle between the pursuit angle and the expected collision angle. The objective of the proposed guidance law is to make the aim angle zero asymptotically. It can be shown that the aim angle error response for the considered system is same as that of the first order system. When the autopilot of the missile system has slow dynamics, autopilot time lag may deteriorate the performance of the guidance law performance. In this case, another new guidance law compensating the autopilot time lag effect is proposed. To verify the proposed guidance laws, several numerical simulations are performed.

A Study on Movement of the Free Face During Bench Blasting (전방 자유면의 암반 이동에 관한 연구)

  • Lee, Ki-Keun;Kim, Gab-Soo;Yang, Kuk-Jung;Kang, Dae-Woo;Hur, Won-Ho
    • Explosives and Blasting
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    • v.30 no.2
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    • pp.29-42
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    • 2012
  • Variables influencing the free face movement due to rock blasting include the physical and mechanical properties, in particular the discontinuity characteristics, explosive type, charge weight, burden, blast-hole spacing, delay time between blast-holes or rows, stemming conditions. These variables also affects the blast vibration, air blast and size of fragmentation. For the design of surface blasting, the priority is given to the safety of nearby buildings. Therefore, blast vibration has to be controlled by analyzing the free face movement at the surface blasting sites and also blasting operation needs to be optimized to improve the fragmentation size. High-speed digital image analysis enables the analyses of the initial movement of free face of rock, stemming optimality, fragment trajectory, face movement direction and velocity as well as the optimal detonator initiation system. Even though The high-speed image analysis technique has been widely used in foreign countries, its applications can hardly be found in Korea. This thesis aims at carrying out a fundamental study for optimizing the blast design and evaluation using the high-speed digital image analysis. A series of experimentation were performed at two large surface blasting sites with the rock type of shale and granite, respectively. Emulsion and ANFO were the explosives used for the study. Based on the digital images analysis, displacement and velocity of the free face were scrutinized along with the analysis fragment size distribution. In addition, AUTODYN, 2-D FEM model, was applied to simulate detonation pressure, detonation velocity, response time for the initiation of the free face movement and face movement shape. The result show that regardless of the rock type, due to the displacement and the movement velocity have the maximum near the center of charged section the free face becomes curved like a bow. Compared with ANFO, the cases with Emulsion result in larger detonation pressure and velocity and faster reaction for the displacement initiation.

Kinetic Analysis for the Pyrolysis of Solid Refues Fuel Using Livestock Manure (축분 고형연료의 열분해 동역학 연구)

  • Jang, Eun-Suk;Song, Eunhye;Yoon, Jonghyuk;Kim, Young-Min
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.443-451
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    • 2020
  • In this study, the physico-chemical properties and pyrolysis kinetics of livestock mature solid fuel were investigated to know its feasibility as a fuel. Ultimate and proximate analysis results showed that livestock mature solid fuel has high contents of volatile matter (64.94%), carbon (44.35%), and hydrogen (5.54%). The low heating value of livestock mature solid fuel (3880 kcal/kg) was also higher than the standard requirement of solid fuel (3000 kcal/kg). Thermogravimetic analysis results indicated that livestock mature solid fuel has three decomposition temperature regions. The first temperature zone (130~330 ℃) was consisted with the vaporization of extracts and the decomposition of hemicellulose and cellulose. The second (330~480 ℃) and third (550~800 ℃) temperature regions were derived from the decomposition of lignin and additional decomposition of carbonaceous materials, respectively. The activation energy derived from model free kinetic analysis results including Friedman, Flynn-Wall-Ozawa (FWO), and Kissinger-Akahira-Sunose (KAS) methods for the pyrolysis of livestock mature solid fuel was in the range of 173.98 to 525.79 kJ/mol with a conversion rate of 0.1 to 0.9. In particular, the activation energy increased largely at the higher conversion than 0.6. The kinetic analysis using a curve-fitting method suggested that livestock mature solid fuel was decomposed via a multi-step reaction which can be divided into five decomposition steps.

Evaluation of the Impact of Land Surface Condition Changes on Soil Moisture Field Evolution (지표면 조건의 변화에 따른 토양수분의 변화 평가)

  • Yu, Cheol-Sang
    • Journal of Korea Water Resources Association
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    • v.31 no.6
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    • pp.795-806
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    • 1998
  • Soil moisture is affected by regional climate, soil characteristics and land surface condition, etc,. Especially, the changes in land surface condition is more than other factors, which is mainly due to rapid urbanization and industrialization. This study is to evaluate how the change of land surface condition impacts on soil moisture field evolution using a simple model of soil moisture dynamics. For the quantification of soil moisture field, the first half of the paper is spared for the statistical characterization based on the first- and second-order statistics of Washita '92 and Monsoon '90 data. The second half is for evaluating the impact of land cover changes through simulation study using a model for soil moisture dynamics. The model parameters, the loss rate and the diffusion coefficient, have been estimated using the observed data statistics, where the changes of surface conditions are considered into the model by applying various parameter sets with different second-order statistics. This study is concentrated on evaluating the impact due to the changes of land surface condition variability. It is because we could easily quantify the impact of the changes of its areal mean based on the linear reservoir concept. As a result of the study, we found; (1)as the variability of land surface condition, increases, the soil moisture field dries up more easily, (2)as the variabilit y of the soil moisture field is the highest at the beginning of rainfall and decreases as time goes on to show the variability of land surface condition, (3)the diffusion effect due to surface runoff or water flow through the top soil layer is limited to a period of surface runoff and its overall impact is small compared to that of the loss rate field.

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A Study on the Variation of the Surface and Groundwater Flow System Related to the Tunnel Excavation in DONGHAE Mine Area (II) - Hydrogeochemical Consideration (동해신광산 터널굴착공사와 관련된 지표수 및 지하수의 유동변화에 대한 조사연구 (II)-수리지구화학적 고찰)

  • 전효택;이희근;이종운;이대혁;류동우;오석영
    • Journal of the Korean Society of Groundwater Environment
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    • v.4 no.1
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    • pp.27-40
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    • 1997
  • The hydrogeochemical study on the 15 natural waters was carried out in the vicinity of tunnel excavation site of Donghae largely composed of granite and limestone. The water samples can be classified based on their chemical characteristics into two groups; waters draining in the granitic region(group 1) and the limestone region(group 2). This classification was also confirmed by statistical examination through cluster analysis, and the tunnel seepage waters collected at the same site appear to be included in group 1 and 2 by their sampling period, respectively. According to factor analysis, the waters of group 1 art mainly represented by the weathering of plagioclase to kaolinite and those of group 2 are characterized by the dissolution of calcite. Different properties of the tunnel seepage waters are thought to be resulted from the effective waterproofing processes conducted during the sampling interval to the surface and subsurface leakage zones at the granitic region, which contributed to the change of groundwater flow system. However both the tunnel seepage waters seem to have thermodynamically interacted with rock-forming minerals in their wallrocks. The mixing ratio of the waters from two groups and water-rock interactions are evaluated quantitatively for the tunnel seepage waters through the mass balance approach, and the results are identical with the previous conclusions in this study.

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Applicability of Theoretical Adsorption Models for Studies on Adsorption Properties of Adsorbents(III) (흡착제의 흡착특성 규명을 위한 흡착모델의 적용성 평가(III) - 열역학적 특성을 중심으로)

  • Na, Choon-Ki;Jeong, Jin-Hwa;Park, Hyun-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.4
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    • pp.260-269
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    • 2012
  • The aim of this study is to evaluate the applicability of adsorption models for understanding the thermodynamic properties of adsorption process. For this study, the adsorption isotherm data of $NO_3$-N ion onto a commercial anion exchange resin obtained at various experimental conditions, i.e. different initial concentrations of adsorbate, different dosages of adsorbent, and different temperatures, were used in calculating the thermodynamic parameters and the adsorption energy of adsorption process. The Gibbs free energy change (${\Delta}G^0$) of adsorption process could be calculated using the Langmuir constant $b_M$ as well as the Sips constant, even though the results were significantly dependant on the experimental conditions. The thermodynamic parameters such as standard enthalpy change (${\Delta}H^0$), standard entropy change (${\Delta}S^0$) and ${\Delta}G^0$ could be calculated by using the experimental data obtained at different temperatures, if the adsorption data well fitted to the Langmuir isotherm model and the plot of ln b versus 1/T gives a straight line. As an alternative, the empirical equilibrium constant(K) defined as $q_e/C_e$ could be used for evaluating the thermodynamic parameters instead of the Langmuir constant. The results from the applications of D-R model and Temkin model to evaluate the adsorption energy suggest that the D-R model is better than Temkin model for describing the experimental data, and the availability of Temkin model is highly limited by the experimental conditions. Although adsorption energies determined using D-R model show significantly different values depending on the experimental conditions, they were sufficient to show that the adsorption of $NO_3$-N onto anion exchange resin is an endothermic process and an ion-exchange process.

A Study on Vibration Control Performance of Macpherson Type Semi-Active Suspension System (맥퍼슨 타입 반 능동 현가장치의 진동제어 성능 고찰)

  • Dutta, Saikat;Han, Chulhee;Lee, TaeHoon;Choi, Seung-Bok
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.2
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    • pp.157-164
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    • 2016
  • The paper studies a comparison analysis of semi-active control strategies for a Macpherson strut type suspension system consisting of MR(magneto-rheological) damper. As a first step, in order to formulate governing, a dynamic full model of a Macpherson strut is developed considering the kinematics. The nonlinear equation of motion of the strut is then linearized around the equilibrium point. A new adaptive moving sliding model controller is developed for fast response of the system. A newly proposed adaptive moving sliding mode control strategy is then compared with conventional sliding mode controller and skyhook controller. The comparison is made for two different types of road inputs; bump and random road profiles showing superior vibration control performance in time and frequency domains.