• Title/Summary/Keyword: 반응기준

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Hydrodesulfuriztion of Thiophene over Neodymium Added Nickel Catalysts (네오디뮴이 첨가된 니켈 촉매의 티오펜 탈황 반응)

  • Moon, Young-Hwan;Ihm, Son-Ki
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.913-924
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    • 1996
  • In this study HDS(hydrodesulfurization) of thiophene was researched over nickel catalysts added with small amounts of neodymium which were prepared by different methods such as unsupported coprepricipitated NdNi catalysts, unsupported intermetallic $NdNi_5$ catalysts, and carbon supported NdNi catalyst. The HDS activity was remarkably increased when a small amounts of neodymium was added to unsupported coprecipitated Ni catalysts. Thus it was known that the role of Nd is important in HDS of thiophene of Ni catalysts. For the case of unsupported intermetallic $NdNi_5$, the intermetallic crystallinity was destroyed to oxide and sulfide after calcination and presulfidation respectively. The HDS activity of thiophene can be explained by surface area of unsupported catalysts. And Nd acts like as structural promoter keeping the high surface area of unsupported catalysts. The HDS activity was increased by each ten times based on 1 gr. of nickel in the order of unsupported intermetallic $NdNi_5$, unsupported coprecipitated NdNi, and carbon supported NdNi catalysts according to different preparation method of catalysts.

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Development of Simple Colorimetric Method for Detecting Contamination of Liquid Spawn of Oyster Mushroom by pH Indicator (pH지시약을 이용한 느타리버섯 액체종균 오염 간이진단법 개발)

  • Jang, Myoung-Jun;Lee, Yun-Hae;Ju, Young-Cheol
    • The Korean Journal of Mycology
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    • v.36 no.1
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    • pp.9-15
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    • 2008
  • For the detection of contaminated liquid spawn, we selected suitable medium, indicator and developed method of diagnosis. The growth of pathogenic bacteria, Pseudomonas sp., and fungi, Trichoderma sp., in YPL media was better than in PDA and NA. In addition, the changes of color and absorbance of media were obviously showed when contaminated liquid spawn by pathogenic bacteria and fungi was incubated on YPL including phenol red for 48 hour at $25^{\circ}C$. The color of YPLP after incubating of infected liquid spawn by Pseudomonas sp. and Trichoderma sp. were changed from orange to red and to scarlet, respectively. Whereas, the color of YPLP after incubation of only Pleurotus ostreatus indicated yellow at liquid spawn. Therefore, it is possible to easily distinguish contaminated liquid spawn by color of change in YPLP.

The Photocatalytic Decomposition of Trichloroethylene(TCE) with $TiO_2$ ($TiO_2$광촉매를 이용한 Trichloroethylene(TCE)의 광분해 반응)

  • 하진욱
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.1 no.2
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    • pp.57-62
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    • 2000
  • The photocatalytic degradation of trichloroethylene(TCE) in water on various types of$TiO_2$ was studied. Surface properties of $TiO_2$were characterized by XRD, SEM, and BET in our previous work(23) . $TiO_2$from Aldrich has 100$\%$pure anatase, TiO$_2$from KIER has 100$\%$ pure rutile structure, and P25-TiO$_2$from Degussa has mixed structure of anatase(75$\%$) and rutile(25$\%$) . Firstly, optimum conditions for TCE degradation were examined in this study. Results showed that optimum loading amount of catalyst was 0.1 wt% and recirculation flow rate of mixture(distilled water and TCE) was 200 cc/min. Secondly, the effect of $TiO_2$structure on TCE degradation was examined. Results revealed that anatase structure generally has better photocatalytic activity than rutile structure. Especially, mixed structure(Degussa P25-$TiO_2$) has the highest activity due to small particle size and large specific surface area.

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Rock-support Interaction behavior for Ground Condition Based on Numerical Modelling (암반조건에 따른 암반-지보 반응거동의 수치해석적 연구)

  • 전양수;한공창;신중호
    • Proceedings of the Korean Society for Rock Mechanics Conference
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    • 2000.09a
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    • pp.155-161
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    • 2000
  • It is very important to control the final load that acts on a support system, in tunnel engineering. A reliable analysis is needed to carry out technically reasonable design and safe construction. Also, a series of procedures of construction and the rock-support interaction behavior must be considered. Most existing studies have been performed as the limited analysis based on the simplified assumption. In this study, through the analysis of a circular tunnel using a 2-D finite differential code, the rook-support interaction behaviors in the variation of rock and stress conditions are analyzed and compared with the results from the closed form solutions. Consequently, more realistic rock-support interaction curves are obtained by including the effects of initial stresses and rock condition. These cures are very useful to predict the required support pressure in the initial design stage.

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Rock-support Interaction behavior for Ground Condition based on Numerical Modelling (암반조건에 따른 암반-지보 반응거동의 수치해석적 연구)

  • 전양수;한공창;신중호
    • Tunnel and Underground Space
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    • v.10 no.3
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    • pp.403-409
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    • 2000
  • It is very important to control the final load that acts on a support system, in tunnel engineering. A reliable analysis is needed to carry out technically reasonable design and safe construction. Also, a series of procedures of construction and the rock-support interaction behavior must be considered. Most existing studies have been performed as the limited analysis based on the simplified assumption. In this study, through the analysis of a circular tunnel using a 2-D finite differential code, the rock-support interaction behaviors in the variation of rock and stress conditions are analyzed and compared with the results from the closed form solutions. Consequently, more realistic rock-support interaction curves are obtained by including the effects of initial stresses and rock condition. These curves are very useful to predict the required support pressure in the initial design stage.

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The Study on Minimum Smoke Propellant to Reduce Afterburning Reaction (후연소 반응이 감소된 무연계 고체 추진제에 관한 연구)

  • Yim, Yoojin;Lee, Jongseop;Park, Euiyong;Choi, Sunghan;Yoo, Jichang;Cho, Young
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.10-17
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    • 2013
  • This paper describes a study on after-burning suppressant in a solid propellant to reduce the plume formed outside of rocket nozzles, which could expose the launch site and the flight track. The minimum smoke propellant to enhance the stealth ability was formulated in terms of the kinds and the effects of after-burning suppressant on the ballistic performance and the amount of primary smoke. A after-burning suppressant, $K_2SO_4$ of about 1.1% weight content was found to show profound reduction of the rocket plume, giving negligibly slight increase in pressure exponent of burning rate. Also minimum smoke propellant with less than 1.1% of $K_2SO_4$ corresponds to A-class satisfaction in primary smoke by AGARD standard.

Decomposotion of EtOH and Oxidation of H2S by using UV/Photocatalysis System (UV/Photocatalysis 시스템을 이용한 EtOH의 분해 및 H2S의 산화)

  • Kim, Jin-Kil;Kim, Sung-Su;Hong, Sung-Chang;Lee, Eui-Dong;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.297-302
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    • 2013
  • Enhancement of photocatalytic activity of UV/photocatalysis was carried out to oxidize the gaseous $H_2S$ in a tubular reactor coated with photocatalyst of sol type $TiO_2$. EtOH was used as the standard material to select the photocatalyst, and it was confirmed that the reactor activity was dependent on the coated surface characteristics. The selected photocatalytic reactor, which coated with STS-01, showed about 80% conversion when the gas linear velocity was 0.01 m/s and relative humidity was 40%. However, the conversion level of the reaction decreased significantly with increasing gas linear velocity. Pt was loaded on the photocatalyst to enhance and maintain the performance of the reactor, which enhanced the conversion level of $H_2S$ more than 95% under the same experimental condition.

The Effect of User Experience Characteristics of AI Cashierless Store Service on Revisit Intention through Emotional Response (AI 활용 무인 매장 서비스의 사용자 경험특성이 감정반응을 통해 재방문 의도에 미치는 영향)

  • Noh Hyeyoung;Sinbok Lee
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.3
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    • pp.791-800
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    • 2024
  • The cashierless store, which is rapidly spreading with the development of AI, is providing new shopping experiences to customers. However, the existing retail service research mainly focused on evaluation based on employees (people). This study was initiated to evaluate services by reorganizing these service evaluations according to the characteristics of cashierless store. In addition, the effect of the service experience characteristics of AI cashierless store on customers' positive or negative emotions was identified, and the effect on revisit intention was verified. As a result of this study, it was confirmed that the service experience characteristics of AI cashierless store had some effect on emotional response. In addition, it was confirmed that the positive emotional response caused by the characteristics of the AI cashierless store service experience induces revisiting, but the negative emotional response hinders revisiting. The results of this study are expected to contribute to the research and development of AI cashierless store services.

금융위기 전후의 시장간 동태적 균형관계 분석

  • Kwak, Jong-Mu
    • The Korean Journal of Financial Studies
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    • v.5 no.1
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    • pp.191-212
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    • 1999
  • 1997년에 우리 나라는 외환충격으로 인한 금융위기 속에서 시장가격이 급격하게 변동하였다. 이로 인해 차익거래를 가능하게 하는 차입과 대출이 크게 제약되었고, 이것은 시장간 균형관계에 중요한 영향을 줄 수 있다. 이에 이러한 금융위기에서도 주요 시장간의 균형관계가 유지되었는지를 검정하는 것이 이 연구의 목적이다. 분석자료로 KOSPI 200 현물 종가 및 선물 결제가격, 연간 회사채 수익률, 양도성 예금 연간이자율, 기준환율의 일일 자료를 사용하였다. 1996년 5월 3일부터 1998년 5월 21일까지의 기간을 외환충격에 의한 금융위기 전, 중, 후의 3단계로 구분하여 각 단계별로 백터오차수정모형 분석과 충격반응분석을 하였다. 금융위기 이전인 제1단계에서는 5개 내생변수간의 균형관계가 존재하였다. 금융위기가 급속하게 진행된 제2단계에서는 균형관계가 존재하지 않았다. 그러나 주가지수, 주가지수 선물가격 및 기준환율 변수를 내생변수로 하고, 나머지 변수를 외생변수로 분석한 경우에는 균형관계가 존재하였다. 금융위기 진정단계인 제3단계에서는 5개 내생변수간의 균형관계가 성립하였다.

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Transformation of Glutamic Acid to Glutamine by E. coli Glutamine Synthetase (E. coli Glutamine Synthetase에 의한 Glutamic Acid로부터 Glutamine 으로의 전환)

  • 전복환;신형순;이왕식;방원기
    • Microbiology and Biotechnology Letters
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    • v.17 no.4
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    • pp.379-384
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    • 1989
  • Glutamine production from glutamate was carried out using glutamine synthetase from E. coli K-12 pgln 6 and baker's yeast, which supplies ATP into the reaction system through alcohol fermentation, simultaneously. With whole cells of E. coli K-12 pgln 6 as an enzyme source of glutamine synthetase, 11.8 g/ι of glutamine produced after 18-h incubation (60% yield based on a substrate, glutamate). Using the partially purified glutamine synthetase, 19.8 git of glutamine was produced after 5-h incubation. This amount of glutamine was correspond to 90% yield, based on substrate, glutamate.

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