• Title/Summary/Keyword: 반응기준

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Economic Evaluation of Two-step Biohydrogen/biomethane Production Process (이단계 바이오 수소/메탄 생산공정의 경제성 평가)

  • Oh, You-Kwan;Kim, Yu-Jin;Kim, Mi-Sun;Park, Sung-Hoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.98-108
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    • 2006
  • 본 연구에서는 이 단계 연속 바이오 수소/메탄 생산공정의 경제성을 조사하였다. 경제적 관점에서 다양한 수소 및 메탄 발효용 생물반응기를 비교 평가하였다. 이를 바탕으로 포도당으로부터 일 단계 수소발효를 위해 고온 trickling biofilter 반응기 (TBR, $100\;m^3$ 규모)를, 일 단계 반응의 부산물로 생성된 유기산과 알콜류의 이 단계 메탄전환을 위해 고온 upflow anaerobic sludge 반응기 (UASB; $700\;m^3$ 규모)를 선정하였다. 본 이 단계 공정의 수소생산 비용은 $$\;0.26/Nm^3$으로 계산되었고, 이는 고온 TBR 반응기만을 이용한 경우보다 약 30 % 낮았다. 이 단계 공정의 낮은 수소생산 비용은 높은 에너지 회수율과 낮은 슬러지 처리비용에 의한 것이었다. 생물학적 수소 생산공정의 경제성은 탄소원의 종류, 생물반응기의 형태 등 여러 인자에 의해 변경될 수 있으나, 본 연구결과는 향후 연구를 위한 유용한 기준으로 고려될 수 있다.

Transportation noise annoyance in a simulated environment (가상의 음 재현 환경에서의 교통소음에 대한 주관적 반응)

  • Kim J.;Lim C. W.;Jeong W.;Hong J.;Lee S.;Jeung W.
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.225-228
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    • 2004
  • 환경소음에 관한 연구는 주로 소음노출지역에 대한 소음 측정 및 사회적 조사(Social Survey)를 토대로 이루어 졌다. 이는 장기간 소음에 노출된 사람에 대한 소음평가의 수단뿐만 아니라 소음관련 법안 제정에 있어서 규제치를 결정하는 기준으로도 사용될 수 있다. 이에 반하여 본 논문에서는 소음에 대한 순간적인 반응 즉, 짧은 순간의 소음노출에 대한 주관적 반응을 알아보고자 하였으며, 방법적 측면(Methodology)에서의 제약으로 인하여 가상의 음 재현장치의 구성을 통하여 일반인을 대상으로 청감반응실험을 할 수밖에 없다. 먼저 항공기, 기차, 자동차 소음의 샘플을 녹음하여 일련의 신호처리 과정을 통하여 청감반응실험에 사용될 음원을 만들고, 청력검사를 통하여 청각에 이상이 있다고 판단되는 피검자의 데이터는 배제시킨 후 실험을 행하였다. 이러한 청감반응실험을 통하여 소음원의 종류, 성별, 연령, 소음 민감도 등에 따라 소음에 대한 성가심, 불쾌감의 정도는 다르게 나타남을 알 수 있었다.

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화강암 지역 암반 지하수 내의 불소의 기원과 거동에 관한 실험 연구

  • 김이섭;윤성택;소칠섭;채기탁;김성용;염승준
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.252-257
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    • 2000
  • 연구 결과를 간단히 요약하면 다음과 같다. 1) 온천 목적으로 개발된 국내 심부 암반 지하수(조사 대상 시료수 419개)는 화강암 및 화강편마암 지역에서 가장 높은 불소 함량을 보이며, 최소 75% 이상의 시료에서 먹는 물 수질 기준을 초과하였다. 2) 화강암 및 화강편마암 지역의 심부 지하수 내 불소 함량은 특히 Na-HCO$_3$ 유형의 지하수에서 높게 나타났는데, 이 유형의 지하수 수질은 사장석, 흑운모를 위시한 규산염 광물의 비조화 용해 반응에 의해 조절된다 이들 지하수는 비교적 깊은 관정심도를 나타내었다. 3) 백악기 화강암과 물과의 용출 반응 실험 결과, 전암 분말과의 반응에서는 최대 7 mg/l의 불소가, 흑운모의 용출 실험에서는 최대 35 mg/1의 불소가 용출되었다. 형석의 포화지수는 비교적 반응 초기에 침전 조건에 근접한 반면, 흑운모의 포화지수는 지속적으로 용해 조건에 놓여 있음을 확인하였다. 따라서, 국내 화강암 지역 심부 지하수 내의 불소는 대부분 흑운모의 비조화 용해 반응에 의해 용출되며, 용출 이후에는 형석의 용해/침전 평형 반응에 의해 그 농도가 조절되는 것으로 확인된다. 4) 앞으로, 보다 자세한 평형 열역학적 해석과 다른 이온종과의 상호 관계 규명 및 광물학적 검토를 통하여 불소의 기원과 거동에 관한 보다 정확한 해석을 시도할 계획이다.

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A Review on the Problem of Korean Blast Damage Criterion (우리나라 발파진동 허용기준의 문제점에 대한 고찰)

  • 두준기;류창하
    • Explosives and Blasting
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    • v.22 no.3
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    • pp.85-95
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    • 2004
  • A damage criterion by blast vibration & noise has to be established through a engineering view point. Though a blast vibration has effects on human and structure, they have experienced a different damage. Thus, a damage criterion for structure needs to get a peculiar criterion which are different from one for human. At present, blast damage criterions authorized by government are Vibration & Noise Act made by Ministry of Environment and blast damage criterion of specifications for tunnel made by Ministry of Construction & Transportation. Vibration & Noise Act is based on the response of human, and while it has some application problems, it turns out to be partly rational. But, blast damage criterion of specifications for tunnel has unreasonable guidelines. In this article, its problems are reviewed and a alternative blast damage criterion is suggested.

Reference Values and Water quality Assessment Based on the Regional Environmental Characteristics (해역의 환경특성을 고려한 해양환경 기준설정과 수질등급 평가)

  • Rho, Tae-Keun;Lee, Tong-Sup;Lee, Sang-Ryong;Choi, Man-Sik;Park, Chul;Lee, Jong-Hyun;Lee, Jae-Young;Kim, Seung-Su
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.17 no.2
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    • pp.45-58
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    • 2012
  • For the development of reference values and evaluation of water quality in various environmental conditions, we divided the coastal region around Korean peninsular into 5 distinctive ecological regions based on the influence of surface current, depth, tidal range, turbidity, and climate condition. We used national marine environment monitoring data collected by National Fisheries Research & Development Institute(NFRDI) from 2000-2009. For the reference values, we used maximum seasonal mean from 2000 to 2007 for DIN, DIP, and chlorophyll-a and minimum seasonal mean for secchi depth measured at stations without the influence of river runoff in each ecological regions. For the reference value of bottom dissolved oxygen saturation, we used minimum mean value of 90% calculated from minimal riverine influence stations of whole regions. We calculated enrichment score for each assessment criteria. The enrichment score of DIN, DIP, and Chlorophyll-a was 1 (=< reference value), 2 (< 110% of reference value), 3 (< 125% of reference value), 4 (< 150% of reference value), and 5 (> 150% of reference value). The enrichment score of DO saturation and Secchi depth was 1 (> reference value), 2 (> 90% of reference value), 3 (>75 % of reference value), 4 (> 50% of reference value), and 5 (< 50% of reference value). We calculated water quality index using weighted linear combination of five enrichment score for the comparison of whole regions. From the water quality index distribution calculated from all stations between 2000 and 2007 period, we classified into 5 grade based on the standard deviation calculated from total water quality index. We assigned grade very good(I), good(II), moderate(III), bad(IV), and very bad(V) when the water quality index was less than 23, minimum + 1 sd, +2 sd, +3 sd, and grater than minium+ 3 sd, respectively.

Nitritation at Various Temperature Conditions - Using Anaerobic Digester Supernatant (다양한 온도 조건에서 아질산화 반응 유도 - 혐기 소화 상징액을 대상으로)

  • Gil, Kyung-Ik;Im, Ji-Yeol
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.3
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    • pp.237-243
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    • 2011
  • As the effluent quality standard of the municipal wastewater treatment plant (MWTP) has been strengthened, the treatment of the recycle water containing high concentration of ammonium nitrogen has been considered as one of retrofit methods for upgrading the exising MWTPs. In this study, nitritation, economic nitrogen removal process, was induced by laboratory-scale reactor at the $35^{\circ}C$, $20^{\circ}C$, and $10^{\circ}C$ temperature conditions using anaerobic digester supernatant. The stable nitritation was achieved over $20^{\circ}C$, but nitrification was induced at $10^{\circ}C$. It means that the nitritation was affected by SRT and temperature. SRT, demanded for nitritation, is changed according to the temperature. Therefore, it is considered that SRT and temperature are important factors in nitritation. Also, it is approved that inducing the ammonium nitrogen removal and the nitritation are more beneficial over $20^{\circ}C$. The conclusion of this study can be used for the important basic reference when nitritation process is applied for MWTPs.

Response Prediction after Neoadjuvant Chemotherapy for Colon Cancer Using CT Tumor Regression Grade: A Preliminary Study (대장암 환자의 수술 전 항암화학요법의 반응을 CT 종양퇴행등급을 이용한 반응 예측: 예비 연구)

  • Hwan Ju Je;Seung Hyun Cho;Hyun Seok Oh;An Na Seo;Byung Geon Park;So Mi Lee;See Hyung Kim;Gab Chul Kim;Hunkyu Ryeom;Gyu-Seog Choi
    • Journal of the Korean Society of Radiology
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    • v.84 no.5
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    • pp.1094-1109
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    • 2023
  • Purpose To investigate whether CT-based tumor regression grade (ctTRG) can be used to predict the response to neoadjuvant chemotherapy (NAC) in colon cancer. Materials and Methods A total of 53 patients were enrolled. Two radiologists independently assessed the ctTRG using the length, thickness, layer pattern, and luminal and extraluminal appearance of the tumor. Changes in tumor volume were also analyzed using the 3D Slicer software. We evaluated the association between pathologic TRG (pTRG) and ctTRG. Patients with Rödel's TRG of 2, 3, or 4 were classified as responders. In terms of predicting responder and pathologic complete remission (pCR), receiver operating characteristic was compared between ctTRG and tumor volume change. Results There was a moderate correlation between ctTRG and pTRG (ρ = -0.540, p < 0.001), and the interobserver agreement was substantial (weighted κ = 0.672). In the prediction of responder, there was no significant difference between ctTRG and volumetry (Az = 0.749, criterion: ctTRG ≤ 3 for ctTRG, Az = 0.794, criterion: ≤ -27.1% for volume, p = 0.53). Moreover, there was no significant difference between the two methods in predicting pCR (p = 0.447). Conclusion ctTRG might predict the response to NAC in colon cancer. The diagnostic performance of ctTRG was comparable to that of CT volumetry.

Optimization of Maillard Reactions of Tagatose and Glycine Model Solution by Appyling Response Surface Methodology (반응표면분석법을 응용한 tagatose와 glycine 모델 용액의 Maillard 갈변반응의 최적화)

  • Ryu, So-Young;Roh, Hoe-Jin;Noh, Bong-Soo;Kim, Sang-Yong;Oh, Deok-Kun;Lee, Won-Jong;Yoon, Jung-Ro;Kim, Suk-Shin
    • Korean Journal of Food Science and Technology
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    • v.35 no.5
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    • pp.914-917
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    • 2003
  • This study was undertaken to find the optimum condition for the Maillard browning reaction of tagatose and glycine model solution by applying the response surface methodology. Independent variables were pH (3, 5, 7), temperature (70, 85, $100^{\circ}C$), and time (60, 180, 300 min), while the dependent variables were absorbance, yellowness, color difference, and organoleptic score. The quadratic models with the cross-product proved to be suitable, due to the high coefficients of determination and the lack of fit results. Since all the dependent variables had saddle points, the optimal points were determined through ridge analysis. For absorbance, yellowness, and color difference, the optimal points were the lowest values; in contrast, the optimal point of organoleptic score was the highest value.

Comparison of Characteristics of Acid-catalyzed Hydrothermal Fractionation for Production of Hemicellulose Hydrolyzate from Agricultural Residues (농경잔류물로부터 헤미셀룰로오스 가수분해물 생산을 위한 산촉매 열수 분별공정의 특성 비교)

  • Hwang, Jong Seo;Oh, Kyeong Keun;Yoo, Kyung Seun
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.414-422
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    • 2022
  • The objective of this work was to investigate the feasibility of acid-catalyzed hydrothermal fractionation for maximum solubilization of the hemicellulosic portion of two typical agricultural residues. The fractionation conditions converted into combined reaction severity (CS) in the range of 1.2-2.9 was used to establish a simple reaction criteria at glance. The hemicellulosic sugar yield of 56.6% was shown when rice straw was fractionated at the conditions at the conditions; 160 ℃ of temperature 0.75% (w/v) of H2SO4, 20 min of reaction time, 1:15 solid/liquid ratio. The hemicellulosic sugar yield of 83.0%, however, was achieved when barley straw was fractionated at the conditions at the conditions; 150 ℃ of temperature 0.75% (w/v) of H2SO4, and 15 min of reaction time, 1:10 solid/liquid ratio. For barley straw, acid-catalyzed hydrothermal fractionation could be effectively performed. After the fractionation process, the remaining fractionated solids were 48.5% and 57.5% from raw rice and barley straws, respectively. The XMG contents in the solid residues decreased from 17.3% and 17.6% to 6.0% and 2.6%, which corresponded to 16.7% and 8.5% on the basis of the raw straws, respectively. In another way, only 5.6% of cellulose and 8.5% of XMG were lost due to excessive decomposition during the acid-catalyzed hydrothermal fractionation of barley straw, compared to cellulose and XMG losses of 6.4% and 26.6% in rice straw. Hemicellulosic sugars from the rice straw were considered more over-decomposed due to the somewhat higher reaction severity at the acid-catalyzed hydrothermal fractionation.

Measurement of ECF for $CaSO_4:Dy$ Thermoluminescent Dosimeters ($CaSO_4:Dy$ 열형광선량계의 소자보정인자(ECF) 산출)

  • Lim, Kil-Sung;Kim, Jang-Lyul
    • Journal of Radiation Protection and Research
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    • v.30 no.4
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    • pp.231-236
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    • 2005
  • Dosimeters are manufactured from same process in the manufacturer but the deviation of TL raw counts exists among the dosimeters. TL raw counts are also gradually degrade due to multiple readings and physical abuse. ECF (Element Correction Factor) correct the degradation and deviation of TL raw counts to the average TL raw counts of reference dosimeters. Procedures for producing ECF of thermoluminescent dosimeters were described In detail. ECFs of 319 reference, control and field dosimeters were measured three times and average of three ECF values was calculated. Also, % CV(Coefficient of Variation) of three ECF values was calculated to verify ECF. ECF & % CV distributions for the field and control dosimeters are presented. TL raw counts of field dosimeters, being used about 6 times for the past 3 years, were almost unchanged, but those of control dosimeters being used more frequently, were degraded about 4.7 %.