• Title/Summary/Keyword: 반응기준

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Thermal Degradation Characteristics of Carbon Tetrachloride in Excess Hydrogen Atmosphere (과잉수소 반응조건하에서 사염화탄소의 고온 분해반응 특성 연구)

  • Won, Yang-Soo;Jun, Kwan-Soo;Choi, Seong-Pil
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.569-577
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    • 1996
  • pure compound chloromethanes; methyl chloride, methylene chloride, chloroform and The carbon tetrachloride were used as a model of chlorocarbon system with Cl/H ratio to investigate thermal stability and hydrodechlorination process of carbon tetrachloride under excess hydrogen atmosphere. The parent thermal stability on basis of temperature required for 99% destruction at 1 second no was evaluated as $875^{\circ}C$ for $CH_3Cl$, $780^{\circ}C$ for $CH_2Cl_2$, $675^{\circ}C$ for $CHCl_3$ and $635^{\circ}C$ for $CCl_4$. Chloroform was thermally less stable than $CCl_4$ at fairly low temperatures $(<570^{\circ}C).$ The lion of $CCl_4$ became more sensitive to increasing temperature, and $CCl_4$ was degraded CHCl3 at above $570^{\circ}C.$ The number and quantity of chlorinated products decreases with increasing temperature for the Product distribution of $CCl_4$ decomposition reaction system. Formation of non-chlorinated hydrocarbons such as $CH_4$, $C_2H_4$ and C_2H_6$ increased as the temperature rise and particularly small amount of methyl chloride was observed above $850^{\circ}C$ in $CC1_4$/$H_2$ reaction system. The less chlorinated products are more stable, with methyl chloride the most stable chlorocarbon in this reaction system.

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Performance Analysis on The Reactive Repeater Jamming Techniques Against an RCIED Using Mobile Devices (모바일 단말을 이용한 RCIED에 대한 repeater 방식의 반응 재밍 기법 성능 분석)

  • Kim, Yo-Han;Kim, Dong-Gyu;Kim, Hyoung-Nam
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.12
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    • pp.55-63
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    • 2015
  • Recently, terroristic threats using a radio controlled improvised explosive device (RCIED) that is remotely controlled and exploded have been increased around the world. In order to prevent the explosion of an RCIED, jamming techniques that interrupt an RCIED receiver can be used, so that the receiver can not demodulate the trigger code. Conventional jamming technique is a type of active barrage jamming that always emits the noise jamming signal for all the frequency band. However, it needs large power consumption and thus is limited in operation time for a vehicle. In order to overcome the shortage of the active barrage jamming, reactive jamming technique has drawn attention. In reactive jamming, all the frequency band is firstly scanned, and then if any trigger signal exists, one emits the jamming signal to the corresponding frequency band. Therefore, the reactive jamming is superior to the active barrage jamming in terms of power efficiency. However, a reactive jammer emits a jamming signal only after the trigger signal is intercepted, which means that the jamming signal may be late for interrupting an RCIED receiver. In this sense, it is needed to evaluate a delay in an RCIED receiver. To achieve this, we analyze the reaction time and present the simulation result for jamming performance of reactive jamming against an RCIED using mobile devices.

Catalytic Oxidation of 1.2-Dichloroethane on Precious Metal Catalysts (귀금속 촉매를 이용한 1.2-Dichloroethane의 산화분해에 관한 연구)

  • Lee, Hae-Wan;Kim, Young-Chai;Moon, Sei-Ki
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.497-503
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    • 1998
  • The catalytic oxidation of 1.2-dichloroethane was investigated over precious metal supported on alumina using a fixed bed microreactor. Among the catalysts tested, the conversion of 1.2-dichloroethane decreased in the following order : Ru > Pt > Pd $${\sim_=}$$ Rh and Pt was found to be the most active catalyst for the complete oxidation of 1.2-dichloroethane to $CO_2$. Major products containing carbon were vinyl chloride and $Co_2$ at temperature ranging from 200 to $400^{\circ}C$. The presence of vinyl chloride in products suggests that the first step in the oxidation of 1.2-dichloroethane is dehydrochlorination and the second is oxidation of vinyl chloride to $CO_2$. To investigate the effect of HCl on the activity of the complete oxidation, some experiments were conducted by adding HCl to the feed. The presence of HCl increased the conversion of 1.2-dichloroethane below $300^{\circ}C$ owing to the increase of surface acidity, but it didn't affect the conversion above $300^{\circ}C$. The reversible adsorption of HCl onto catalyst surface inhibited the complete oxidation to $CO_2$.

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A Study on the Characteristics of Manufactured Mg Crown on the Calcining Conditions of Dolomite (백운석의 소성 조건에 따른 제조 Mg crown의 특성에 관한 연구)

  • Hwang, Dae Ju;Yu, Young Hwan;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.611-625
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    • 2021
  • Mg crowns were manufactured using domestic dolomite (Ca·Mg(CO3)2) (20~30 mm). In order to manufacture the calcined dolomite (CaO·MgO), (a) electric furnace (950 ℃, 480 min) and (b) microwave furnace (950 ℃, 60 min) processes were used. As a result of XRD analysis, it was analyzed as (a) CaO 56.9 wt%, MgO 43.1 wt% by electric furnace process and (b) CaO 55 wt%, MgO 45 wt% by microwave furnace process. Even when the decarbonation reaction time of dolomite was shortened by 1/8 in microwave furnace process compare with electric furnace process, the calcined dolomite could be produced. The hydration reaction (ASTM C 110) is a standard for the hydration reactivity of calcined dolomite, and the calcined dolomite produced by electric furnace process showed a high hydration reactivity (max temp 79.8 ℃/1.5 minutes). Such hydration reactivity was occurred by only CaO hydration reaction and that was confirmed by XRD analysis. The calcined dolomite produced by microwave furnace process showed low hydration reactivity (max temp 81.7 ℃/19.5 minutes). Such low hydration reactivity was occurred by CaO and MgO hydration reaction due to the hydration reaction of CaO thereafter occurring of the hydration reaction of MgO, and that was confirmed by XRD analysis. The prepared Mg crown were 58.8 g and 74.6 g by electric furnace and microwave furnace processes, respectively, under the reaction conditions of 1,230 ℃, 60 min, 5 × 10-2 torr by silicothermic reduction.

A Study on the Analysis of Measurement Errors of Specific Gravity Meter (기준 밀도계의 측정 오차 분석에 관한 연구)

  • Lee, Kang-Jin;Her, Jae-Young;Ha, Young-Cheol;An, Seung-Hee;Lee, Seung-Jun;Lee, Cheol-Gu
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.676-680
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    • 2002
  • The specific gravity meter is the instrument used to measure the density of fluids under the reference conditions and it can be widely used in industrial areas, especially in massive flow rate natural gas industry. This study has been carried out in an attempt to improve measurement accuracy of natural gas flow rate calculation, providing the adequate installation and proper operation conditions of specific gravity meter. The test results are 1) the density measurement errors in case of using methane and standard gas as calibration gases are smaller than using methane and nitrogen gas, 2) the periodical calibration to maintain accurate density measurements is essential, and 3) the specific gravity meter is sensitive to changes of environmental conditions, especially environmental temperature surrounding the specific gravity meter.

Evaluation of Oxygen Permeability of Soft Contact Lenses Based on Thickness (두께 기준에 따른 소프트 콘택트렌즈의 산소투과성 평가)

  • Yu, Dong-Sik;Moon, Byeong-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.8
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    • pp.2157-2163
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    • 2009
  • The oxygen permeability of a soft contact lens is an important parameter for determining corneal health when considering the physiological response of the eye. The aim of this study is to evaluate the oxygen permeability of soft contact lenses based on thickness, using the polarographic method. The thickness of lens was measured using contact and non-contact method. To assess accuracy and reliability, the Bland-Altman plot was used. The reliability was high for the oxygen permeability based on center thickness measured by contact method, whereas the accuracy was high for the oxygen permeability based on center thickness measured by non-contact method. These results indicate that the permeability characteristics were variable according to the measurement and criteria of thickness of soft contact lenses and the measurement of soft contact lenses by non-contact method was more reasonable. Thus, contact lens practitioners should consider some basic differences between methodologies when interpreting or quoting oxygen performance data.

A study on working out arc detector related regulations (아크 검출기 관련 규정 마련에 관한 연구)

  • Park, Yong-Seo
    • Journal of Digital Convergence
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    • v.16 no.11
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    • pp.115-122
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    • 2018
  • More than 70% of the electric fire cases happen in this country are caused by arc. This paper aims to prepare measures of preventing electric fires resulted from arc by analyzing the technical standards and related regulations on the existing circuit breaker. Based on the study, we concluded that the technical and legal standards of the arc detector should be separately regulated from those of existing circuit breaker, considering the characteristics of arc detectors. Accordingly, we suggested in this paper that the arc detector related regulations should either be added to the existing circuit breaker related regulations, or to be handled separately. For effective prevention of electric fires caused by arc, it is urgently required to install arc detector and it is, therefore, appropriate to make it mandatory to install an arc detector. Under the given circumstance, it is suggested that the arc detector related regulations should be added to the existing regulations for the circuit breaker. The technical standards of arc detectors should reflect the arc judgement specification, breaking threshold of arc and the range of unnecessary signal that breaker should not react to respond.

Catalytic Wet Air Oxidation by TiO2 Supported Mn-Ce Based Catalysts (Mn-Ce계/TiO2 촉매에 의한 아세트산의 습식산화 반응특성)

  • Park, K.S.;Park, J.W.;Kim, Y.J.;Yoon, W.L.;Park, J.S.;Rhee, Y.W.;Kang, Y.
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2263-2273
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    • 2000
  • Catalytic wet air oxidation of acetic acid over Mn-Ce based catalysts deposited on various supports ($SiO_2$, $TiO_2$, $ZrO_2$), $ZrSiO_4$, $ZrO_2(10wt%)/TiO_2$) have been carried out in high pressure microreactors. Also, promotional effects by small addition(O.5~1.0 wt%) of p-type semiconductors (CoO, $Ag_2O$, SnO) have been investigated. From the screening tests for initial activity ranking, both Mn(2.8)-Ce(7.2 wt%) and Ru(O.4)Mn(2.7)-Ce(6.9 wt%) supported on $TiO_2$ were selected as the promising reference candidates. In $Mn-Ce/TiO_2$ reference catalyst, addition of small amount of each p-type semiconductor (Co, Sn and Ag) resulted in activity promotional effect and the degree of the increase was in the following order: Co> Ag > Sn. Especially, $Mn-Ce/TiO_2$ promoted with 0.5 wt% Co gave the 2.6 folds activity increase compared to the reference case attributing to the surface area increase as well as synergy effect. In $Ru-Mn-Ce/TiO_2$ reference catalyst, only Co(1.0 wt%) promoted case showed a little reaction rate increase.

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Relation Among Parameters Determining the Severity of Bronchial Asthma (기관지천식 환자의 증상의 중증도를 나타내는 지표들간의 연관성)

  • Lee, Sook-Young;Kim, Seung-June;Kim, Seuk-Chan;Kwon, Soon-Suk;Kim, Young-Kyoon;Kim, Kwan-Hyoung;Moon, Hwa-Sik;Song, Jeong-Sup;Park, Sung-Hak
    • Tuberculosis and Respiratory Diseases
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    • v.49 no.5
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    • pp.585-593
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    • 2000
  • Background : International consensus guidelines have recently been developed to improve the assessment and management of asthma. One of the major recommendation of these guidelines is that asthma severity should be assessed through the recognition of key symptoms, such as nocturnal waking, medication requirements, and objective measurements of lung function. Differential classification of asthma severity would lead to major differences in both long term pharmacological management and the treatment of severe exacerbation. Methods : This study examined the relationship between the symptom score and measurements of $FEV_1$ and PEF when expressed as a percentage of predicted values in asthmatics (n=107). Results : The correlation of $FEV_1$ % with PEFR% was highly significant (r=0.83, p<0.01). However, there was agreement in terms of the classification of asthma severity in 76.6% of the paired measurements of $FEV_1$ % and PEFR%. Agreement in the classification of asthma severity was also found in 57.1% of the paired analysis of $FEV_1$ % and symptom score. 39% of the patients classified as having moderate asthma on the basis of $FEV_1$ % recording would be considered to have severe asthma if symptom score alone were used. Low baseline $FEV_1$ and high bronchial responsiveness were associated with a low degree of perception of airway obstruction. Conclusion : The relationships between the symptom score, PEFR and $FEV_1$ were generally poor. When assessing asthma severity, age, duration, $PC_{20}$, and baseline $FEV_1$ should be considered.

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Culture of Nile Tilapia (Oreochromis niloticus) in Recirculating Aquaculture System (순환여과식 양식 시스템에서 나일 틸라피아(Oreochromis niloticus)의 사육)

  • Seo Kuen Hack;Kim Byong Jin;Jo Jae Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.27-34
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    • 2002
  • The performances of fish culture were evaluated in the integrated recirculating aquaculture system consisting of a double drain type rearing tank ($2.5 m^3$), a sedimentation tank, a floating bead filter, a foam separator and a rotating biological contactor. A system was stocked with nile tilapia at an initial rearing densities of $5\%$ (A), $5\%$ (B) and $7\%$ (C) oyer 30 days. Feed coefficient was 1.62, 1,79 and 1.80 and average daily growth rate was $0.452\%$, 0.u5% and $0.423\%$, respectively. The level of TAN was maintained below $1 g/m^3$ for $5\%$ of initial rearing density and $2-4 g/m^3$ for $7\%$. The dissolved oxygen level ($2-4 g/m^3$) was not optimum but should not be inhibitory to fish growth. The total suspended solid was completely removed during overall experimental period.