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원자력발전소 중대사고시 수소 제어 방법

  • 진영호
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.11a
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    • pp.34-39
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    • 2002
  • 원자력발전소(원전)에서 발생 가능성이 거의 없지만, 그래도 핵연료의 용융을 가져오는 중대사고가 발생하면 다량의 수소가 발생한다. 즉, 노심이 노출됨에 따라, 노심은 과열되고 핵연료 피복재인 지르코늄이 수증기와 반응을 하여 산화되면서 수소를 생성하게된다. 원자로내에서 생성된 수소는 발생된 수소는, 원자로 냉각재계통(Reactor Coolant System, RCS)이 건전하다면 RCS내에 축적되고, RCS에 누설 경로가 있다면 격납건물로 방출되어 격납건물에 축적된다.(중략)

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Partial Oxidation of Cyclohexane with Fe(II) Complexes (Fe(II) 착화합물에 의한 Cyclohexane의 부분 산화반응)

  • Kim, Sa-Heum;Oh, Seung-Mo
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.238-246
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    • 1994
  • Partial oxidation of cyclohexane by HOOH was carried out with the transition metal complexes composed of Fe(II) or Fe(III)/picolinic acid derivatives. The major products were turned out to be cyclohexanone and cyclohexanol wlth the one/ol ratios of 3~10. The best performance was observed in a mixed solvent of pyridine/acetic acid(volume ratio 2.5:1, pH 5.3) and optimal temperature was $25{\sim}40^{\circ}C$. It was known that cyclohexyl hydroperoxide is the reaction intermediate, and that the reaction dominantly follows non-radical pathways which was ascertained from the results of the adamantane oxidation and radical trap experiments.

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Eupatorium chinensis var. simplicifolium Root Extract Inhibits the Lipopolysaccharide-Induced Inflammatory Response in Raw 264.7 Macrophages by Inhibiting iNOS and COX-2 Expression (Raw 264.7 대식세포에서 등골나물 뿌리 추출물의 염증반응 조절 분자 iNOS와 COX-2 발현 억제 효과)

  • Lee, Jin-Ho;Kim, Dae-Hyun;Shin, Ji-Won;Park, Sae-Jin;Kim, Yoon-Suk;Shin, Yu-Su;Yu, Ji-Yeon;Kim, Tack-Joong
    • Journal of Life Science
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    • v.22 no.9
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    • pp.1137-1144
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    • 2012
  • Inflammation is a host defense mechanism that is activated in response to harmful substances or pathogens. However, an excessive inflammatory response is a problem in itself. Macrophages secrete inflammatory mediators such as nitric oxide (NO) or cytokines through various pathways such as the nuclear factor kappa B (NF-${\kappa}B$)-activated pathway after recognizing pathogen-like lipopolysaccharides (LPSs). In this study, anti-inflammatory effects of Eupatorium chinensis var. simplicifolium (EUC) extracts were investigated using LPS-stimulated RAW 264.7 macrophages. The EUC root extract significantly reduced NO production, inducible nitric oxide synthase (iNOS) expression, and cyclooxygenase-2 expression in a concentration-dependent manner. In addition, the EUC root extract reduced phosphorylation of mitogen-activated protein kinases and protein kinase B, which is upstream of NF-${\kappa}B$. The EUC root extract also reduced the degradation of inhibitory kappa B. These results indicate that EUC root extract exerts anti-inflammatory effects, which are mediated by inhibition of iNOS expression and the NF-${\kappa}B$ pathway.

Effects of Low-Level Visual Attributes on Threat Detection: Testing the Snake Detection Theory (저수준 시각적 특질이 위협 탐지에 미치는 효과: 뱀 탐지 이론의 검증)

  • Kim, Taehoon;Kwon, Dasom;Yi, Do-Joon
    • Science of Emotion and Sensibility
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    • v.23 no.3
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    • pp.47-62
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    • 2020
  • The snake detection theory posits that, due to competition with snakes, the primate visual system has been evolved to detect camouflaged snakes. Specifically, one of its hypotheses states that the subcortical visual pathway mainly consisting of koniocellular cells enables humans to automatically detect the threat of snakes without consuming mental resources. Here we tested the hypothesis by comparing human participants' responses to snakes with those to fearful faces and flowers. Participants viewed either original images or converted ones, which lacked the differences in color, luminance, contrast, and spatial frequency energies between categories. While participants in Experiment 1 produced valence and arousal ratings to each image, those in Experiment 2 detected target images in the breaking continuous flash suppression (bCFS) paradigm. As a result, visual factors influenced the responses to snakes most strongly. After minimizing visual differences, snakes were rated as being less negative and less arousing, and detected more slowly from suppression. In contrast, the images of the other categories were less affected by image conversion. In particular, fearful faces were rated as greater threats and detected more quickly than other categories. In addition, for snakes, changes in arousal ratings and those in bCFS response times were negatively correlated: Those snake images, the arousal ratings of which decreased, produced increased detection latency. These findings suggest that the influence of snakes on human responses to threat is limited relative to fearful faces, and that detection responses in bCFS share common processing mechanisms with conscious ratings. In conclusion, the current study calls into question the assumption that snake detection in humans is a product of unconscious subcortical visual processing.

A Study on NOx Formation Pathway of Methane-Air Lean Premixed Combustion by using PSR Model (PSR 모델을 이용한 메탄-공기 희박 예혼합 연소의 NOx 생성 경로 연구)

  • Lee, Bo-Rahm;Kim, Hyun;Park, Jung-Kyu;Lee, Min-Chul;Park, Won-Shik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.5
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    • pp.46-52
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    • 2009
  • In this study the predictions of NOx in methane-air lean premixed combustion in PSR were carried out with GRI 3.0 methane-air combustion mechanism and Zeldovich, nitrous oxide, prompt, and NNH NO formation mechanism by using CHEMKIN code. The results are compared to the JSR experimental data of Rutar for the validation of the model. This study concerns about the importance of the chemical pathways. The chemical pathway most likely to form the NO in methane-air lean-premixed combustion was investigated. The results obtained with the 4 different NO mechanisms for residence time(0.5-1.6ms) and pressure(3, 4.7, 6.5 atm) are compared and discussed.

Prophenoloxidase Activating System in the Coelomic Fluid of the Redworm, Lmbricus rubellus (붉은지렁이 체액내 Prophenoloxidase 효소활성계)

  • 박윤경;손영종
    • The Korean Journal of Zoology
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    • v.38 no.1
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    • pp.125-135
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    • 1995
  • 붉은지렁이 (Lumbricus rubellus)의 체내에 존재하는 prophenoloxidase-phenoloxidase(prPO$\longrightarrow$PO)의 활성계는 몇 종류의 다른 경로에 의해 활성화 됨을 발견하였다 Propo는 exogenous trypsin $\beta$ 1.3-glucan, Ca2' 이온. lipopolysaccharide (LPS) 및 열처리 등에 의하여 활성도가 증가 되었고 Ca2' 이온이 나머지 4가지 종류의 처리와 함께 병행되었을 때 그 효과가 더욱 증가하였다 Propo의 활성도는 LPS나 Ca2' 이온의 농도가 각각 1 5H 10-s g Lps/r리, 15 mM(Ca2')의 농도에서 propo의 최대활성치를 나타냈으나 그 이상의 농도에서는 propo의 활성이 오히려 감소하였다. LPS. $\beta$ 1,3-glucan 및 Ca2' 이온 등은 trypsin 억제인자인 soybean trypsin inhibitor(571)가 함께 존재할 경우 전혀 propo를 활성화 시킨지 못하는 것으로 미루어 $\beta$ 1,3-glucan 및 Ca2' 이온 등은 체내의 trypsin 유사 효소의 활성을 증가시켜 궁극적으로는 proPO$\longrightarrow$PO의 활성화 반응에 간접적으로 작용한다고 생각되었다. 한편. 571의 존재하에서도 50"C의 열처리는 propo의 활성화에 아주 효과적인 물리적 요인으로 작용하였다. 따라서 열처리는 Ca2'이나 LPS. f 1,3-glucan파는 달리 직접적으로 proPO$\longrightarrow$PO의 활성화 반응에 작용하는 것으로 생각되어 붉은 지렁이의 체내에서 proPO가 활성화되는 괴정(propo-activating system)에는 최소한 2가지 이상의 경로가 있다고 생각된다.생각된다.

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Ecohydrological response of P inus densiflora to climate change: Interactions between soil moisture and photosynthetic pathway (기후변화에 대한 소나무 반응: 토양 수분과 광합성 경로 사이의 상호작용)

  • Woo, Dong Kook
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.481-481
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    • 2022
  • 본 연구에서는 기후 변화 완화에 대한 잠재력을 평가하기 위해 국내에서 가장 우세한 소나무 종인 Pinus densiflora의 기후변화에 대한 반응을 평가하였다. 기후변화의 시나리오로 4가지 대표 농도경로(RCP)에 기반 하여 CO2, 강수량, 온도의 변화를 개별 및 조합하였다. 생태수문학적 및 지구화학적 모델인 ecosys를 활용 및 보완하여 광릉 시험림에 적용하였다. 본 연구에서는 대기 중 CO2 증가가 총일차생산량(GPP)과 순일차생산량(NPP)에 미치는 긍정적인 영향이 강수량과 기온 변화로 인한 부정적인 영향보다 더 큰 것으로 나타났다. 특히, 기준 시나리오와 비교하여 각각 RCP2.6, 4.5, 6.5, 8.5에서 3.79%, 13.44%, 18.26%, 28.91%의 NPP 개선이 모의되었다. 또한, 본 연구에서는 지표하 질소 유출과 지표 N2O 플럭스가 기후 변화가 심해짐에 따라 소나무 생장 향상 및 토양 수분 저하로 인하여 토양 질소 손실 감소가 모의되었다. 기후변화의 강도가 증가함에 따라 증발산량이 증가하였지만, 기공 감소는 토양에서 흡수하는 물이용 및 광합성 효율 증진을 가져왔다. 이러한 결과는 소나무가 기후 변화를 완화하는 환경 친화적인 선택으로 작용할 수 있는 잠재성을 나타낸다.

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The Kinetic Study of Carbon Deposition in CO2 Reforming of CH4 (메탄의 이산화탄소 개질반응의 탄소퇴적속도에 관한 연구)

  • Lee, Dong-Kyu;Lee, Sung-Hee;Hwang, Kap-Sung;Kwon, Young-Du
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.337-341
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    • 2005
  • This paper reports the study on coking rate and carbon formation route as a function of reaction temperature using the Ni catalysts in the $CO_2$ reforming of methane. In this paper, carbon deposition on catalysts and its kinetics during reforming reaction were studied by using a thermogravimetric analyzer. Kinetic studies show that reaction orders of carbon formation obtained 1.33 ($CH_4$) and -0.52 ($CO_2$) by experiments on partial pressure of reactant gas, respectively. On the basis of model equation, the kinetic parameters for the coking reaction at different temperatures indicated that methane decomposition dominated carbon formation at lower temperatures ($<600^{\circ}C$), while $CH_4$decomposition and Boudouard reactions become significant for coking in the temperature range of $600{\sim}700^{\circ}C$.

A Multi-path Search Algorithm for Multi-purpose Activities (다목적 정보 제공을 위한 다경로 탐색 기법 개발)

  • Jeong, Yeon-Jeong;Kim, Chang-Ho
    • Journal of Korean Society of Transportation
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    • v.24 no.3 s.89
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    • pp.177-187
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    • 2006
  • It is known that over one million car navigation devices are being currently used in Korea. Most. if not all, route guidance systems, however, Provide only one "best" route to users, not providing any options for various types of users to select. The current practice dose not consider each individual's different preferences. These days, a vast amount of information became available due to the rapid development in information processing technology. Thus, users Prefer choices to be given and like to select the one that suits him/her the "best" among available information. To provide such options in this Paper, we developed an algorithm that provides alternative routes that may not the "least cost" ones, but ones that are close to the "least cost" routes for users to select. The algorithm developed and introduced in the paper utilizes a link-based search method, rather than the traditional node-based search method. The link-based algorithm can still utilize the existing transportation network without any modifications, and yet enables to provide flexible route guidance to meet the various needs of users by allowing transfer to other modes and/or restricting left turns. The algorithm developed has been applied to a toy network and demonstrated successful implementation of the multi-path search algorithm for multi-purpose activities.

Catalytic Recycling of Waste Polymer II. A Study of the Mechanism on the Catalytic Glycolysis of Flexible Polyurethane Foam (촉매를 이용한 폐고분자 물질의 자원화 II. 연질 폴리우레탄 폼의 글리콜분해반응 메카니즘)

  • Park, Chong-Rae;Kim, Sung-Ick;Kim, Young-Chul;Park, Nam-Cook;Seo, Gon
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.388-393
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    • 1999
  • Polyurethane foams are polymeric material with repeating groups of urethane and urea. When these are heated with ethylene glycol and K acetate catalyst at $200^{\circ}C$, the transesterification of them leads to soluble products. The mechanisms of the reaction were investigated from the molecular weight and the component distributions of the products by GPC and IR analysis. The degradation of the urethane groups was faster than that of urea groups in transesterification reaction. K acetate catalyst accelerated the rate of the transesterification because it had a high ionization tendency. Each reaction, using K or Sr acetate as a catalyst, progressed in the same reaction path but yielded different compositions in products because of the difference of the reaction rate.

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