• Title/Summary/Keyword: 반사각

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The Crystal and Molecular Structure of Sulfadiazine (Sulfadiazine의 結晶 및 分子構造)

  • Shin Hyun So;Ihn Gwon Shik;Kim Hoon Sup;Koo Chung Hoe
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.329-340
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    • 1974
  • Sulfadiazine, $C_{10}H_{10}N_4O_2S$, forms monoclinic crystals of space group $P21}c$ from a mixture of acetone and ethanol with $a=13.71{\pm}0.04,\;b=5.84{\pm}0.03,\;c=15.11{\pm}0.05{\AA},\;{\beta}=115.0{\pm}0.3^{\circ}$, and four molecules per cell. Three dimensional photographic data were collected with $CuK\alpha$ radiation. The structure was determined using Patterson and Fourier synthesis methods and refined by block diagonal least-squares methods with isotropic thermal parameter for all non-hydrogen atoms. The final R value was 0.15 for the 1517 observed independent reflections. The dihedral angle between the planes through the benzene ring and the pyrimidine ring is $76^{\circ}$. The conformational angle formed by the projection of the S-C(5) bond with that of N(1)-C(1) where the projection is taken along the S-N(1) bond is $77^{\circ}$. The imino nitrogen atom, N(1), and pyrimidine nitrogen atom, N(3), form intermolecular $N-H{\cdots}N$ hydrogen bond between the molecules related by center of symmetry. Amino nitrogen atom, N(4), forms two intermolecular $N-H{\cdots}O$ hydrogen bonds, with O(1) and O(2) atoms of different molecules separated by b. A two dimensional network of hydrogen bonds form infinite molecular sheets parallel to the (100) plane. Adjacent sheets are bound together by van der Waals forces.

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Crystal Structure of a Bromine Sorption Complex of Dehydrated Calcium and silver Exchanged Zeolite A (칼슘 및 은 이온으로 치환된 제올라이트 A를 탈수한 후 브롬을 흡착한 결정구조)

  • Bae, Myung-Nam;Kim, Un-Sik;Kim, Yang
    • Korean Journal of Crystallography
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    • v.8 no.2
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    • pp.127-131
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    • 1997
  • The crystal structure of a bromine sorption complex of vacuum-dehydrated Ag+ and Ca2+ exchanged zeolite A(a=12,234(1) Å) has been determined by single-crystal X-ray diffraction methods in the cubic space group Pm3m. The crystal was prepared by flow method using exchange solution in which mole ratio of AgNo3 and Ca(NO3)2 was 1:150 with a total concentration of 0.05M. The crystal was dehydrated at 360℃ and 2 ×10-6 Torr for 2days, followed by exposure to 180 Torr of Br2 vapor for 20min. full-matrix least-squares refinements converged to the final error indices of R1=0.111 and R2=0.101 using 90 reflections for which I>3o(I). About 3.1 Ag+ ions and 4.45 Ca2+ ions lie on the two crystallographically nonequivalent three-fold axes associated with 6-ring oxygens. A total of six bromine molecules are sorbed per unit cell. Each bromine molecule approaches a framework oxide ions axially (Br-Br-O=171(2)', O-Br=3.25(6) Å; and Br-Br=2,61(8) Å by a charge-transfer interaction.

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Structure and Sequence Stratigraphy in the Southwestern Area of the South China Sea (남중국해 남서부 지역에서의 지구조 분석 및 순차층서학적 연구)

  • Lee, Eung Gyu;Lee, Gi Hwa
    • Journal of the Korean Geophysical Society
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    • v.2 no.3
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    • pp.179-190
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    • 1999
  • The overall structural framework was studied using the regional 2D seismic data, followed by the sequence stratigraphic study on the 3D seismic and well- log data in the margin of the South Con Son basin of the South China Sea. This research contributes to delineate depositional stratigraphy, depositional environment and geologic history in the 3D seismic area of highly complicated faulting. Eight Miocene sequences were indicated on the 3D seismic and well-log data, in which the structural maps of each sequence boundary and the isochron maps for the corresponding sequence were made. The seismic facies were analyzed for each sequence volume and sequence boundary surface. The 3D seismic area is characterized by coal beds deposited in the transgression environment (transgression systems tract) and channel distributions just above the sequence boundaries. During the Early Miocene, the coals and thick shales deposited in the mangrove swamp representing the lower coastal plain environment. During the Mid to Late Miocene, thick clastic sediments deposited in the coastal to shallow shelf by regional subsidence and marine transgression. The isochron maps and structural patterns indicate that the sediments were transported from west to east or from northwest to southeast.

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Cable-free Seismic Acquisition System (무선 탄성파 탐사 시스템)

  • Lee, Donghoon;Kim, Byung-Yeop;Jang, Seonghyung
    • Geophysics and Geophysical Exploration
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    • v.19 no.3
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    • pp.164-173
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    • 2016
  • Cable-free seismic technology is to acquire seismic data with independent receivers which are not connected by cables. This is an effective method for survey designs with less topographical conditions. With technology advancement for cable-free receivers, reliable data quality, easy deployment, and picking up the receivers, the cable-free technology has begun to apply to land seismic acquisition. In this study we introduced a cable-free seismic system and its equipment. We tried to build up the cable-free seismic technology through the field application. In the seismic tomography field applications, the seismic signals of the cable-free receiver and cabled receiver with the same distance from the source show the same phase in early stage. The difference of the first arrival times between two signals is less than 0.4 ms, which could be accepted. In the field application for seismic reflection exploration, we acquired shot gathers with different source depth and dynamite charge. The shot gathers from cable-free and cabled system are similar to each other. With an efficient method for receiver deployment and survey design, the application of the cable-free technology will increase.

Correlation Analysis with Vegetation Indices and Vegetation-Endmembers From Airborne Hyperspectral Data in Forest Area (산림지역의 항공기 탑재 하이퍼스펙트럴 영상에 대한 식생-Endmember와 식생지수의 상관 분석)

  • Kim, Tae-Woo;We, Gwang-Jae;Suh, Yong-Cheol
    • Journal of the Korean Association of Geographic Information Studies
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    • v.15 no.3
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    • pp.52-65
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    • 2012
  • The net biomass accumulation (or net primary production, NPP) and gross primary production (GPP) have closely related with carbon accumulations(or carbon exchange) in vegetation. There are many approaches to estimate biomass using remote sensing techniques. The vegetation indices (VIs) can be a methodology to estimate biomass which assumes total chlorophyll contents. Various VIs were characterized with difference development conditions as vegetation species, input datasets. The hyperspectral data have also different spatial/spectral resolutions for aerial surveying. Additionally they need particular spectral bands selection difficulty to calculate the VIs. The objective of this study is to evaluate the correlations with airborne hyperspectral data (compact airborne spectrographic imager, CASI) and spectral unmixing model (or spectral mixture analysis, SMA) to characterize vegetation indices in forest area. The spectral mixture analysis was used to model the spectral purity of each pixel as an endmember. The endmembers are the fraction components derived from hyperspectral data through the SMA. In this study, we choose three endmembers represented vegetation pixels in the hyperspectral data. These endmembers were compared with 9 VIs by the Pearson's correlation coefficient. The results show MTVI1 and TVI have same correlation coefficient with 0.877. The MCARI, especially has very high relationship with vegetation endmembers as 0.9061 at less vegetation and soil distributed site. The MTVI1 and TVI have high correlations with the vegetation endmembers as 0.757 in whole test sites.

The Crystal Structure of an Iondine Sorption Complex of Dehydrated Calcium and Silver Exchanged Zeolite A ($Ag^+$이온과 $Ca^{2+}$이온으로 치환한 제올라이트 A를 탈수한 후 요오드를 흡착한 결정구조)

  • Bae, Myung-Nam;Kim, Yang;Kim, Un-Sik
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.118-124
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    • 1995
  • The crystal structure of an iodine sorption complex of vacumm-dehydrated Ag+ and Ca2+ exchanged zeolite A(a=12.174(3)Å) has been determined at 21℃ by single-crystal X-ray diffraction techniques in the cubic space group Pm3m. The crystal was prepared by flow method for three days using exchange solution in solution in which mole ratio of AgNO3 and Ca(NO3)2 was 1:150 with total concentration of 0.05 M. The complex was prepared by dehydration at 360℃ and 2×10-6 Torr for 2 days, followed by exposure to about 14.3 Torr of iodine vaporat 80℃ for 24 hours. Full-matrix least-squares refinement converged to the final error indices of R1=0.082, R2=0.068 using 122 reflections for which I > 3σ(I). Two Ag+ ions, 1.1 Ag+ ions, and 4.45 Ca2+ ions per unit cell are located on three different three-fold axes associated with 6-ring oxygens. Two Ag+ ions per unit cell are in the large cavity, 1.399(4)Å from the (111) plane of three oxygens. Another 1.1 Ag+ ions are found at opposite sites. Six iodine molecules are sorbed per unit cell. Each I2 molecule approaches a framework oxide ion axially (O-I=3.43(2)Å, I-I=2.92Å, I-I-O;166.1(3)°), by a charge transfer complex interaction. Two Ag+ ions make a close approach to the iodine molecules (Ag-I ; 2.73(2)Å).

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A Typology of Maritally Violent Men: Testing the Three Batterer Subtypes Derived from Theory (가정폭력 행위자의 유형: 이론에 따른 세 하위유형의 검증)

  • Chang, Hee-Suk;Kim, Ye-Sung
    • Korean Journal of Social Welfare
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    • v.56 no.3
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    • pp.303-325
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    • 2004
  • This study investigated subtypes of men who batter, and explored the differences among them. It was based on 217 subjects from all around the nation who received legal punishment. In the analysis of the typology, we specifically tested whether the Holtzworth-Munroe and Stuart proposed typology was verified. The results of the cluster analysis revealed support for their theoretical distinction for three types of abusers. These results imply that Holtzworth-Munroe and Stuart's batterer typology is applicable to Korean batterers to some degree. Type 1 men demonstrated the lowest levels of physical and psychological abuse toward their wives and were the least likely to have had a history of child abuse or alcohol problems. These men had lower MCMI scores and did not show any extraordinary personality traits. Men in this category were violent only against their wives, had relatively liberal sex role attitudes and had the most satisfaction in their intimate relationships. Type 2 men were violent only at home, using a moderate level of violence. These men had very high levels of dependency on others and showed a borderline, avoident or passive-aggressive personality. The amount of alcohol consumption was similar to Type 1, but scores of jealousy, self-esteem, and attitudinal variables were similar to Type 3 men. They lacked assertiveness skills and reported the least marital satisfaction. Type 3 men used the most severe violence and were violent both inside and outside the home. These men showed signs of antisocial and aggressive personality. They had experienced frequent physical abuse during childhood, were the most likely to abuse alcohol and had lower self-control. Type 3 were the most traditional in their views of women's roles and had attitudes supporting violence. Based upon the study findings, practical implications of enhancing treatment efficacy were considered.

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Multicomponent RVSP Survey for Imaging Thin Layer Bearing Oil Sand (박층 오일샌드 영상화를 위한 다성분 역VSP 탐사)

  • Jeong, Soo-Cheol;Byun, Joong-Moo
    • Geophysics and Geophysical Exploration
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    • v.14 no.3
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    • pp.234-241
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    • 2011
  • Recently, exploration and development of oil sands are thriving due to high oil price. Because oil sands reservoir usually exists as a thin layer, multicomponent VSP, which has the advantage of the high-resolution around the borehole, is more effective than surface seismic survey in exploring oil sand reservoir. In addition, prestack phase-screen migration is effective for multicomponent seismic data because it is based on an one-way wave equation. In this study, we examined the applicability of the prestack phase-screen migration for multicomponent RVSP data to image the thin oil sand reservoir. As a preprocessing tool, we presented a method for separating P-wave and PS-wave from multicomponent RVSP data by using incidence angle and rotation matrix. To verify it, we have applied the developed wavefield separation method to synthetic data obtained from the velocity model including a horizontal layer and dipping layers. Also, we compared the migrated image by using P-wave with that by using PS-wave. As a result, the PS-wave migrated image has higher resolution and wide coverage than P-wave migrated image. Finally, we have applied the prestack phase-screen migration to the synthetic data from the velocity model simulating oil sand reservoir in Canada. The results show that the PS-wave migrated image describe the top and bottom boundaries of the thin oil sand reservoir more clearly than the P-wave migrated image.

Fine Structural Analysis of Principal and Secondary Eyes in Wandering Spider, Pardosa astrigera (배회성 거미 (Pardosa astrigera) 주안과 부안의 미세구조적 분석)

  • Jeong, Moon-Jin;Lim, Do-Seon;Moon, Myung-Jin
    • Applied Microscopy
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    • v.30 no.1
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    • pp.1-9
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    • 2000
  • The wandering spider, Pardosa astrigera, had four pairs of ocelli that arranged in three rows on the cephalothorax. Along the anterior margin lay a pair of small anterior median (AM) eye flanked on each side by anterior lateral (AL) eye. Two large posterior median (PM) eye was situated on the clypeus behind the anterior row and still more posteriorly was a pair of posterior lateral (PL) eye. The visual cell of retina consisted of cell body, rhabdome, and intermediate segment. Bipolar neuron was found in anterior median eye (principal eye) and unipolar neuron in others (secondary eye). Rhabdome showed that arranged in PMeye and PLeye. But rhabdomes of AMeye and ALeye were irregular in retina. Except AMeye, incontinuous tapetum found in ALeye, PMeye, PLeye. Anterior median eye was similar to anterior lateral eye in length and posterior median eye similar to posterior lateral eye. Component size of eye were similar to 4 pairs eye in cornea. Size of lens, cell body, and rhabdome was similar not only anterior median eye and anterior lateral eye but also posterior median eye and posterior lateral eye. Vitreous body was large posterior median eye than others.

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A Study of Roughness Measurement of Rock Discontinuities Using a Confocal Laser Scanning Microscope (콘포컬 레이저 현미경을 이용한 불연속면의 거칠기 측정 연구)

  • Byung Gon Chae;Jae Yong Song;Gyo Cheol Jeong
    • The Journal of Engineering Geology
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    • v.12 no.4
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    • pp.405-419
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    • 2002
  • Fracture roughness of rock specimens is observed by a new confocal laser scanning microscope (CLSM; Olympus OLS1100). The wave length of laser is 488 nm, and the laser scanning is managed by a light polarization method using two galvano-meter scanner mirrors. The function of laser reflection auto-focusing enables us to measure line data fast and precisely. The system improves resolution in the light axis (namely z) direction because of the confocal optics. Using the CLSM, it is Possible to measure a specimen of the size up to $10{\;}{\times}{\;}10{\;}cm$ which is fixed on a specially designed stage. A sampling is managed in a spacing $2.5{\;}\mu\textrm{m}$ along x and y directions. The highest measurement resolution of z direction is $10{\;}\mu\textrm{m}$, which is more accurate than other methods. Core specimens of coarse and fine grained granite are provided. Fractures are artificially maneuvered by a Brazilian test method. Measurements are performed along three scan lines on each fracture surface. The measured data are represented as 2-D and 3-D digital images showing detailed features of roughness. Line profiles of the coarse granites represent more frequent change of undulation than those of the fine granite. Spectral analyses by the fast Fourier transform (FFT) are performed to characterize the roughness data quantitatively and to identify influential frequency of roughness. The FFT results suggest that a specimen loaded by large and low frequency energy tends to have high values of undulation change and large wave length of fracture roughness.