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Semi-Empirical MO Calculations on ${\pi}$-Nonbonded and ${\sigma}$-Conjugative Interactions (반경험적 분자궤도함수 계산법에 의한 ${\pi}$-비결합 및 ${\sigma}$-컨쥬게이션 상호작용에 관한 연구)

  • Ikchoon Lee;Young Gu Cheun;Kiyull Yang;Wang Ki Kim
    • Journal of the Korean Chemical Society
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    • v.26 no.4
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    • pp.195-204
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    • 1982
  • Semi-empirical MO calculations, EHT, CNDO/2, MINDO/3, and MNDO met hods, were performed on various geometries of n-butane, n-alkyl radical and tetramethylene diracal (triplet) in order to compare eigenvalue and eigenvector properties with those obtained by STO-3G method. All methods predicted the same relative order of stabilities of various geometries for n-butane; geometrical preferences were found to be dominated by one-electron factor, ${\pi}$-orbital energy changes being more impotant in the semi-empirical methods. The hyperconjugative energy changes accompanying structural changes from $(n-{\sigma}{\ast})_{trans}$ to (n-{\sigma}{\ast})cis were underestimated in the EHT, CNDO/2 and MINDO/3, whereas those were overestimated in the MNDO. The net destabilizing effect of $(n-{\sigma}{\ast})_{trans}$ structure was mainly due to the large internuclear energy involved in the structure. Through-space interaction between $n_1$ and $n_2$ orbitals of diradical caused energy gap narrowing of ${\Delta}E_{sp}$ and ${\Delta}{\varepsilon}={\varepsilon}_0$-${\varepsilon}_{av}$; through-space interaction had opposing effect to that of through-bond interaction. Due to the less severe neglect of differential overlaps in the MNDO, this energy gap narrowing effect appeared amplified in the MNDO. In general orbital properties were found to be reproduced satisfactorily, but eigenvalue properties were not, in all the semi-empirical methods especially when ${\sigma}-{\sigma}{\ast}$ and n-$n-{\sigma}{\ast}$interactions were involved.

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Regional Difference in Distribution of Glycoconjugates in Mouse Epididymis (생쥐 부정소 부위별 당쇄 분포의 차이)

  • 계명찬
    • Development and Reproduction
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    • v.5 no.2
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    • pp.167-173
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    • 2001
  • To characterize the difference in glycoconjugates of mouse epididymis, lectin labeling of the tissue section was conducted using Ulex europaeus agglutinin I(UEA I), succinylated wheat germ agglutinin(sWGA), and Griffonia simplicifolia lectin-I(GSL-I). UEA I which binds to outer $\alpha$-L-fucose residue that is a terminal sugar of the side chain branched from oligosaccharide chain gave the labeling in the proximal caput epithelia exclusively. Lumen was commonly labeled in all of the organ. It suggested that the glycoconjugates bearing outer $\alpha$ -L-fucose residue were largely expressed in the initial segments ot epididymis and subjected to secretion. GSL-I which binds to terminal $\alpha$ -D-galactosyl residue of glycoconjugates gave the labeling in the cytoplasm of clear cells and basal cells, and cilia in corpus and cauda regions but not in the caput region. There was no vast difference in labeling pattern by sWGA which binds to N-acetyl-glucosamine residue among the epididymal regions. Clear cells in corpus and cauda epithelia showed more intense labeling by sWGA compared to principal cells, suggesting the functional specialization of this type of cells. The labeling intensities of luminal content by UEA I and sWGA decreased in cauda region compared to corpus region suggesting the presence of enzymatic activities responsible for processing the $\alpha$-L-fucose and N-acetyl-glucosamine residues from secreted glycoconjugates. In summary, the difference in glycoconjugates bearing the $\alpha$-L-fucose, $\alpha$-D-galactose, and N-acetyl-glucosamine residues according to the type of epithelial cells and epididymal segments suggests functional specialization and different roles of each segment in the processing of sperm surface antigens during the epididymal transit.

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The Clothes Tendensy of Korean Sericultural Women (한국 양잠부녀자의 의복변천에 관한 연구)

  • 이양후
    • Journal of Sericultural and Entomological Science
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    • no.11
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    • pp.87-94
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    • 1970
  • This study was conducted in order to find out the tendency of sericultural woman's clothes. This data was based on random samples of 183 sericultural women throughout the country, and was derived from the investigation of c1othes (western and Korean-style) which had been made during the years, 1967∼1969. The results obtained are summarized as follows: 1. Western-style clothes were about twice as popular as Korean-style, and more evident among the young women. It was also shown that the ratioes mentioned above were gradually decreased year by year. 2. Most popular among the western-style clothes were blouses, one-piece dresses and skirts. Jogori(coat) and Cheema(long skirt) were favorites among the Korean-styled clothes. One-piece dresses showed increasing tendency of use year by year. 3. Costume-made clothes were much more in number than the home-made and the ready-made types. The home-made and the ready-made clothes increased as the ages increased. 4. Western-styled clothes were popular in summer seasons while Korean-styled clothes were popular in the winter time. Among the western-styled clothes one-pieces dresses and two-piece suits were most popular during the spring through autumn. In Korean clothes the Cheema was popular all year round. 5. Western-style clothes were mostly made of polyester and their blends. Silk was the least used fabric. On the contrary, most of Korean-style clothes were made of silk and their blends. The synthetic fibers showed increasing use year by year. 6. Favorite colors were in order; white, blue, brown, and black in western-style clothes; white, blue, green, and gray were in Korean style clothes. Young women teaded to have a wider preference of colors than the older women.

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양성 고분자로 표면 사이징된 원지에 의한 도공층의 조기 구조화 및 도공지의 물성 개선

  • 이학래;전대구
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.62-62
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    • 2000
  • 도공지 제조 시 적절한 표면특성을 지닌 원지를 사용하는 것은 최종 도공지 품질향상은 물론 조업성 개선에도 필수적인 요소이다. 이러한 목적을 달성하기 위해 도공원지의 표면 사이징이 실시되고 있다. 도공원지의 표면 사이정 시 양성전분을 이용할 경우 서로 반대로 하전된 전분 과 섬유 사이에 발현되는 정전기적 인력에 의해서 표면 사이정 전분의 원지로의 전분 침투가 억제되어 도공원지의 불투명도, 광택도 인쇄적성 둥의 물성 향상을 꾀할 수 있다. 또 이러한 원지를 이용하여 도공을 할 경우 음전하를 띤 도공액 구성성분과 양전하를 띤 원지 표면의 정 전기적 작용에 의해 도공액의 부동화가 촉진될 수 있으므로 도공액의 표면 잔류성이 향상되 며, 도공층 공극 구조 개선에 따른 광학적인 성질의 개선도 기대할 수 있을 것으로 기대된다. 본 연구에서는 양성전분으로 표면 사이정 된 원지를 사용한 도공지와 기존의 산화전분을 이용하여 표면 사이정한 원지를 이용하여 제조된 도공지의 특성을 비교하였다. 또 양성전분에 의한 표면 사이징 효과를 보다 극대화하고 도공안료와 원지 표면과의 반응성을 증가시키기 위 해 양이온성 폴리머를 표면 사이정 시 첨가하여 표면 사이칭을 하는 방법을 평가하였다. 아울 러 양성전분과 도공안료와의 반응에 따라 도공층의 부동화가 촉진될 수 있다는 근거를 구명하 기 위해 레올로지적인 접근을 시도하였으며, 도공층의 공극 특성 관찰, 광산란 및 광홉수 계수 측정 등을 통해 양성전분으로 표면 사이정된 도공층의 구조적 특성을 분석하였다. 그 결과 산화전분에 비해 양성전분으로 표면 사이징한 원지의 경우 도공지의 불투명도가 높게 나타났다. 이는 양성전분으로 표면 사이정한 원지를 사용한 경우 도공층의 구조가 광 산란계수를 향상시킬 수 있도록 변화되었기 때문임을 확인하였다. 표면 사이징시 양이온성 폴리머를 첨가할 경우 불투명도 개선에 상당한 효과가 있었으며, 전분 대비 1% 이하의 첨 가량에서도 어느 정도의 개선이 가능하였다. 양성전분에 의한 도공액의 조기 부동화가 발현 된다는 것을 구명하기 위해서 도공액의 점탄성적 평가를 실시한 결과 산화전분에 비해 양성 전분 상에서 도공액의 storage modulus가 높고 critical strain point 역시 높은 값을 나타낸 다는 것을 확인하였다. 이는 양성전분과 도공액, 특히 클레이와의 정전기적 인력에 의한 반 응 결과로 생각된다. 양성전분을 이용한 도공원지의 표면 사이정 기술은 특히 평량이 낮은 도공지의 경우 수분 의 침투를 억제함으로써 도공공정에서의 지절을 감소시킬 뿐 아니라 불투명도 등 광학적 성질 을 개선시키고, 표면 커버리지를 향상시키는 효과를 나타낼 것으로 기대된다.

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설기(薛己)의 생애(生涯)와 의학사상(醫學思想)에 관한 연구(硏究) -관어설기지생애급의학사상적연구(關於薛己之生涯及醫學思想的硏究)-

  • Park, Jae-Jeong;Yun, Chang-Yeol
    • Journal of Korean Medical classics
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    • v.18 no.2 s.29
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    • pp.1-19
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    • 2005
  • 통과대명대저명의가(通過對明代著名醫家), 온보파창시자설기(溫補派創始者薛己)$(1487{\sim}1559)$적생애화의학사상(的生涯和醫學思想), 득출여하결론(得出如下結論): 설기생여의학세가(薛己生於醫學世家), 종소학습유학화의학(從小學習儒學和醫學), 기부사후(其父死後), 체부진입태의원성료의사(替父進入太醫院成了醫士), 지후선후역임태의원이목(之後先後歷任太醫院吏目), 남경태의원원판(南京太醫院院判), 원사등직(院使等職), 병어1540년(44세)기관회향(幷於1540年(44歲)棄官回鄕), 전심여치료환자여저술(專心於治療患者與著述). 설기적저작대부분내(薛己的著作大部分內) 용이의안형식서사(容以醫案形式書寫), 기내용포함내과(其內容包含內科), 외과(外科), 부산과(婦産科), 소아과(小兒科), 침구과(鍼灸科), 치과(齒科), 안과(眼科), 골과(骨科), 본초등(本草等). 기본인친(其本人親) 자저술적유이(自著述的有以)${\ulcorner}$내과적요(內科摘要)${\lrcorner}$위시약12종(爲始約12種), 교주적유이(校注的有以)${\ulcorner}$부인대전양방(婦人大全良方)${\lrcorner}$위시8종(爲始8種), 교감적의서약유6종(校勘的醫書約有6種), 공계대약(共計大約) 유26종지다(有26種之多). 설기수(薛己受)${\ulcorner}$내경(內經)${\lrcorner}$, ${\ulcorner}$난경(難經)${\lrcorner}$급장원소화금원사대가적영향교심(及張元素和金元四大家的影響較深). 재사대가중(在四大家中), 우기수동원화단계적영향최심(尤其受東垣和丹溪的影響最深). 차외(此外), 가지기수교주의서적영향역교대(可知其受校注醫書的影響亦較大), 기통과박람군서(其通過博覽群書), 대담실천(大膽實踐), 광수자료(廣收資料), 선우총결(善于總結), 최종성료일명의가(最終成了一名醫家). 설기수이동원(薛己受李東垣)${\ulcorner}$비위론(脾胃論)${\lrcorner}$적영향(的影響), 강조비위적중요성(强調脾胃的重要性), 병수차제출비통혈적이론(幷首次提出脾統血的理論) 기여이동원적학설부동지처시(其與李東垣的學說不同之處是), 재치료화쇠토약형허한증시(在治療火衰土弱型虛寒證時), 주장이보화생토지법내치료(主張以補火生土之法來治療), 인위비여신적생리작용호위관련(認爲脾與腎的生理作用互爲關聯), 비토화생정미(脾土化生精微), 이자양신여명문(以滋養腎與命門) 반과래(反過來), 신여명문역대위토기온후작용(腎與命門亦對緯土起溫煦作用); 이재병리방면(而在病理方面), 비토구허(脾土久虛), 가치신허(可致腎虛), 신허즉불능생토(腎虛則不能生土), 역가치비허(亦可致脾虛). 설기적극반대명대의가수금원지유풍(薛己積極反對明代醫家受金元之遺風), 이한양약공하(以寒凉藥攻下), 혹남용지백이강화(或濫用知柏以降火), 극벌생기적작법(克伐生氣的作法), 이주장용편온적약물진행조보(而主張用偏溫的藥物進行調補), 기상용적전인처방유보중익기탕(其常用的前人處方有補中益氣湯), 사물탕(四物湯), 사군자탕(四君子湯), 육군자탕(六君子湯), 독삼탕(獨蔘湯), 삼부탕(蔘附湯), 육미환(六味丸), 팔미환(八味丸), 신기환(腎氣丸), 회양탕(回陽湯), 당귀보혈탕등(當歸補血湯等).

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The Relationship of Nearly White Background Colors and Readability of Tablet PC (Tablet PC에서 Nearly White 배경색과 가독성의 관계)

  • Yun, Bo-Ram;Park, YungKyung
    • Science of Emotion and Sensibility
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    • v.17 no.2
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    • pp.35-44
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    • 2014
  • The purpose of this paper is to investigate the readability of Nearly White background color in display environment. To perform the experiment, warmup experiment was carried out to for cognitive of whiteness using a Tablet PC. The experiment environment was by a indoor window seat under a mixture of fluorescent light and sunlight. The result of previous test was that the most whiteness perception was a color white a medium wavelength and followed by the short wavelength. The main experiment was to find readability, color combination and visual strains using 4 nearly whites background colors (Reddish, Greenish, Blueish, Yellowish) and one white background color, also text color is limited on black. As a result, readability and color combination had the highest score against a Greenish white background. Visual strain is also the lowest against a Greenish background. On the contrary, readability and color combination preference has the lowest score against the Reddish background. Visual strain is also the highest against a Reddish background. We propose the background color, which improves readability and reduces visual strain in visual display terminals environment through the research results.

Aging and Research Performance of the Government-funded Research Institutes in the Field of Science and Technology (과학기술분야 정부출연연구기관의 평균연령 증가 추세가 연구성과에 미치는 영향)

  • Kim, Seung Tai;Jung, Su Hyeon;Lee, Kijong
    • Journal of Technology Innovation
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    • v.25 no.3
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    • pp.25-50
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    • 2017
  • Declining research competitiveness and inefficiency are constantly being raised in the National Assembly and the media for the Government-funded Research Institutes(GFRIs), which are highly dependent on government funding. These external stakeholders point to the workforce aging of the GFRIs as one of the main causes of inefficiency. They insist that the aging leads to an increase in labor costs, a discontinuity in research, a decrease in employment of new researchers, and a decrease in research competitiveness. However, the GFRIs argue that the aging is a natural phenomenon due to an increase in the age of recruitment, and even if there is an side effect, it is extremely small or even vice versa. It is interesting that there is no empirical study identifying the correlation between the workforce aging and the research performance of the GFRIs, despite the discussion. This study tracked and analyzed the changes of the research performance and the workforce for the five years from 2011 to 2015, and tried to demonstrate the correlation between the workforce aging and the research performance. As a result, we confirmed that there is an inverted U-type correlation between the aging and the papers, one of the research performance, and that the optimal age is 44.96 years. Also, we could not find any correlation between the aging and the patents.

Comparison of Setup Deviations for Two Thermoplastic Immobilization Masks in Glottis Cancer (성문암 세기변조방사선치료에서 두 가지 열가소성 마스크에 대한 환자위치잡이 오차 평가)

  • Jung, Jae Hong
    • Journal of radiological science and technology
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    • v.40 no.1
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    • pp.63-70
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    • 2017
  • The purpose of this study was compare to the patient setup deviation of two different type thermoplastic immobilization masks for glottis cancer in the intensity-modulated radiation therapy (IMRT). A total of 16 glottis cancer cases were divided into two groups based on applied mask type: standard or alternative group. The mean error (M), three-dimensional setup displacement error (3D-error), systematic error (${\Sigma}$), random error (${\sigma}$) were calculated for each group, and also analyzed setup margin (mm). The 3D-errors were $5.2{\pm}1.3mm$ and $5.9{\pm}0.7mm$ for the standard and alternative groups, respectively; the alternative group was 13.6% higher than the standard group. The systematic errors in the roll angle and the x, y, z directions were $0.8^{\circ}$, 1.7 mm, 1.0 mm, and 1.5 mm in the alternative group and $0.8^{\circ}$, 1.1 mm, 1.8 mm, and 2.0 mm in the alternative group. The random errors in the x, y, z directions were 10.9%, 1.7%, and 23.1% lower in the alternative group than in the standard group. However, absolute rotational angle (i.e., roll) in the alternative group was 12.4% higher than in the standard group. For calculated setup margin, the alternative group in x direction was 31.8% lower than in standard group. In contrast, the y and z direction were 52.6% and 21.6% higher than in the standard group. Although using a modified thermoplastic immobilization mask could be affect patient setup deviation in terms of numerical results, various point of view for an immobilization masks has need to research in terms of clinic issue.

Analysis of lipid composition and fatty acids in poultry eggs -cage system, open barn system's hen egg, moscovy duck's egg mallard's egg- (난류(卵類)의 지질성분 및 지방산 조성 분석 - 달걀, 기러기알, 청둥오리알 -)

  • Hong, I-Jin;Yoon, Hae-Kyung;Koo, Sung-Ja
    • Korean journal of food and cookery science
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    • v.15 no.6
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    • pp.645-651
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    • 1999
  • The lipid and fatty acid composition of various poultry eggs were examined after extracting yolk oils from the eggs of caged hen, open barn-reared hen, mallard, and muscovy duck. Total lipid content in 100 g of each edible portion was the highest in muscovy duck egg followed by open barn-reared hen, mallard, caged hen, and natural hen eggs. The triglyceride contents in the egg were in the order of caged hen, open barn-reared hen, natural hen, mallard, and muscovy duck. The cholesterol contents in total lipid were the highest in caged hen and muscovy duck eggs(4.5%), and the lowest in mallard(3.3%). Caged hen eggs had higher neutral lipid ratio among total lipid, but had lower ratio of glycolipid and phospholipid compared with those of the open barn-reared hens. For fatty acid composition, linoleic acid was the highest in the muscovy and linolenic acid was the highest in open barn-reared hen eggs. The contents of arachidonic acid and Eicosapentaenoic acid(EPA) were the highest in muscovy eggs. On the other hand, the content of Docosahexaenoic acid(DHA) was the highest in muscovy duck eggs.

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The Study of Grashey Method Viewing the Glenohumeral(shoulder) Joint (어깨관절의 접시오목을 나타내는 Grashey법에 대한 연구)

  • Lee, Jaeseob;Kim, Youngjae
    • Journal of the Korean Society of Radiology
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    • v.9 no.6
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    • pp.331-335
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    • 2015
  • Consideration of Glenohumeral joint's image with the Changed Body angle of the Glenohumeral joint's Oblique Position in Erect Position. Glenohumeral joint's of Grashey method is a shoulder oblique method available to view the shoulder joint. Grashey method projects AP view of the Glenohumeral joint's so that the Humerus head's subluxation or joint degeneration can be easily visualized. However in this view, the patients, erect position, have to keep their body obliquely. Oblique position is will be needed to get the good quality Glenohumeral joint's view. Therefore, we thought of examining a method which shows the Glenohumeral joint's well by angling the patient one side upward in erect position. For this study, total 20 subject with no history of neurological or psychiatric illness, were recruited for examinations. They consisted of 13 mails and 7 femails, Statistic group analysis was performed with ANOVA test. Score of the evaluation of the expects were $30^{\circ}$ at $0.40{\pm}0.499$, $35^{\circ}$ at $1.34{\pm}0.657$, $40^{\circ}$ at $1.84{\pm}0.573$, $45^{\circ}$ at $0.76{\pm}0.649$, and they were significant(P<0.05). The degree of $40^{\circ}$ views were shown to yield good quality shoulder oblique images.