• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.1
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• pp.110-118
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• 2010

Supercritical treatment of liquefaction technology for rice hull was investigated the biomass conversion rate and evaluated its crude oil in respect to feasibility of burner in order to heat the green house. The reaction was carried out in a 5,000 mL liquefaction system with dispenser and external electrical furnace. Raw materials (160 g) of rice hull and 3,000 mL of different solvents were fed into the reactor. It was observed that the maximum crude oil yield was about 84.4 % with 1-butanol. The calorific value of crude oil from ethanol solvent were 7,752 kcal/kg. Furthermore, in case study of co-solvent with ethanol and bulk-glycerol, it observed that more than 80 % of rice hull was decomposed and liquefied in its solvent at $315{\sim}326^{\circ}C$ for 30 min. For the development of applicable bio-fuel from rice hull, it was considered that its feasibility is necessary to be carried out for co-solvent soluble portions. Regarding to utilize the crude oil into burner as fuel, it was observed that its calorific value was lower at approximately 24 % than the diesel. Also, flame length from crude oil at lower temperature was decreasing due to incomplete incineration. The temperature of warm wind on the burner was maintained between 63 and $65^{\circ}C$, and the temperature of emission line was appeared at $350{\sim}380^{\circ}C$.

• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.135-139
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• 2016

We developed a liquid-liquid extraction method using an inorganic salt to dramatically improve the recovery efficiency of the anticancer agent paclitaxel from plant cell cultures. As a result of liquid-liquid extraction using a diverse types of inorganic salt (NaCl, KCl, $K_2HPO_4$, $NaH_2PO_4$, $NaH_2PO_4{\cdot}2H_2O$), NaCl gave the highest yield (~96%) and lowest partition coefficient (0.053) of paclitaxel. The optimal NaCl/solvent ratio, methylene chloride/MeOH ratio, and pure paclitaxel content for liquid-liquid extraction using NaCl were 1% (w/v), 26% (v/v), and 0.066% (w/v), respectively. Under the optimal conditions developed in the present method, most of the paclitaxel (~96%) was recovered from biomass by a single extraction step. In addition, this method facilitated 3-fold higher recovery efficiency of paclitaxel in a shorter extraction number than the conventional liquid-liquid extraction method.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.97-97
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• 2015

전 세계적으로 화석연료의 고갈 및 환경오염 문제를 해결하기 위해 신재생에너지에 대한 관심이 급증하고 있다. 이러한 신재생에너지에는 수소 에너지, 자연 에너지(태양열, 지열 등), 바이오 매스 에너지 등이 포함된다. 이 중 수소 에너지는 지구상에 풍부하게 존재하고 있는 물과 탄화수소로부터 얻어지며, 연소 시에도 다시 물을 형성하여 오염 물질을 배출하지 않는 차세대 무공해 에너지원으로써 주목을 받고 있다. 수소 제조를 위한 공정에는 수증기 개질 공정(steam reforming), 부분 산화(partial oxidation) 및 자열개질(autothermal reforming) 등이 있으며 실제로 생산되는 대부분의 수소는 탄소/수소비(1:4)가 높은 메탄($CH_4$) 가스를 이용한 메탄 수증기 개질 공정(steam methane reforming)을 통하여 제조된다. 이 때 수소 제조의 고효율화 및 저비용화를 위해서는 반응물에 대한 높은 선택도, 고활성도 및 높은 안정성을 갖는 촉매가 반드시 필요하며, 대표적으로 Ni, Pt, Ru 등이 보고되고 있다. 이러한 촉매들은 대부분 세라믹 pellet 형태로 제작되어 왔으나 열전도도가 낮고 물리적 충격에 취약하다는 단점이 존재한다. 따라서 우리는 이러한 단점을 극복하고, 촉매의 활성을 높이기 위하여 다공성 금속 합금 폼을 촉매 지지체로 도입하였다. 또한, 다공성 금속 합금 폼 표면에 촉매의 분산 및 안정성을 향상시키기 위해 지지체와 촉매 사이에 원자층 증착법을 이용하여 inter-layer를 도입하였다. 이들의 구조, 형태, 및 표면의 화학적 상태는 주사전자현미경, EDS (energy dispersive spectroscopy)가 탑재된 주사전자현미경, X-선 회절, 및 X-선 광전자 분광법을 이용하여 규명하였다. 더하여 정전압-전류 측정법 및 유도 결합 플라즈마 분광 분석기을 이용하여 전기 화학 반응을 유도하고, 반응 후 전해질의 성분분석을 통해 촉매와 지지체 간의 안정성을 평가하였다. 따라서 본 결과들은 한국진공학회 하계정기학술대회를 통해 좀 더 자세히 논의될 것이다.

• KSBB Journal
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• v.14 no.2
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• pp.212-219
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• 1999

lactic acid production from cellulose by simultaneous saccharification and fermentation(SSF) was studied. The SSF using cellulase enzyme Cytolase CL and Lactobacillus delbrueckii was strongly inhibited by the end product(lactic acid). An ion-exchange resin(RA-400) was used for in-situ product removal during SSF. The sorption capacity of the resin was 200mg/g-resin. The simple SSF and the extractive SSF resulted in lactic acid concentrations of 30.4g/L and 32.0g/L, respectively, at the initial substrate concentration of 50g/L. A model was developed to simulate the extractive SSF. The lactic acid conversion for the initial substrate of 100g/L was estimated to be improved from 60% to 09% by in-situ product removal. The experimentally determined kinectic parameters were pH dependent, and fitted as empirical expressions to establish their values at different pH's. Lactic acid productivity was predicted to be maximum at pH 4.5-5.0.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.617-620
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• 2008

지열에너지는 지구 내부의 깊은 곳에서부터 발생하는 열과 상부 지각에서 방사성 동위원소의 붕괴에 의한 열에 의해 발생한다. 지열에너지는 다른 신재생에너지(수력, 풍력, 태양력, 조력, 바이오 매스등)에 비하여 가동효율이 높고, 지속가능한 재활용 자원으로 경제적 효율성이 높아 전 세계적으로 활용도와 잠재성이 높은 신재생에너지의 하나로 각광 받고 있다. 따라서, 지열에너지의 사용은 화석 연료 사용의 상당부분을 대체할 수 있고, 온실가스의 배출도 줄일 수 있다. 현재 우리나라의 지열에너지 이용은 저온성 지열에너지를 이용한 냉난방에 국한되어 있지만, 앞으로의 지열에너지 이용은 Enhanced Geothermal System(EGS) 을 이용한 지열에너지 개발에 초점이 맞추어질 것이다. 현재의 지열에너지 개발을 용이하게 하고, 또한 미래의 지열에너지 개발에 대비하여 우리나라의 이용가능한 지열에너지 부존량을 파악하기 위해 본 연구를 수행하였다. 연구 수행에는1560개 열물성 자료(밀도, 비열, 열전도도), 353개 지표 지열류량 자료, 180개 열생산율 자료와 54개의 지표온도 자료가 사용되었다. 우리나라의 지표에서부터 1 km 깊이 간격별로 5 km 깊이까지 지열에너지 부존량을 산출한 결과 지표에서 부터 5 km 깊이까지의 추출 가능한 지열에너지의 총 부존량은 $1.01{\times}10^{23}$ J로 산출되었다. 지열에너지 부존량을 Toe(석유환산톤) 로 환산하면 $2.40{\times}10^{12}$ Toe 가 된다. 추출한 지열에너지 자원의 2%를 사용한다고 가정 했을때 약 480억 Toe 이다. 이는 2006년 우리나라 전체 1차 에너지 총 소비량(2.33억 Toe)을 고려 했을때 약 200년 동안 사용할 수 있는 양이다.

• Clean Technology
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• v.17 no.1
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• pp.31-36
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• 2011

All types of ${\gamma}-Al_2O_3$ such as acidic, neutral and basic forms were chemically modified with (3-mercaptopropyl) trimethoxysilane (3-MPTMS) and oxidized by 30 wt% $H_2O_2$ solution. As a result, sulfonic acid modified ${\gamma}-Al_2O_3$ catalysts were obtained. Their formation was achieved more easily by treating 1M HCl solution. Their catalytic performance was tested by dehydration reaction of D-xylose to furfural. The sulfonic acid modified ${\gamma}-Al_2O_3$ catalysts showed high conversion (>90%) of D-xylose, and the selectivity to furfural was increased with the amount of sulfonic acid anchored on the catalyst.

• Journal of Environmental Science International
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• v.29 no.4
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• pp.339-349
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• 2020

This study aims to identify participating resident awareness of the improvements to forest carbon cycle villages created by the Korea Forest Service by introducing a system for district heating basedon forest biomass in mountainous areas. Hwacheon Forest Carbon Circulation village was established in Paroho-neureup village in Yuchon-ri, Hwacheon-gun between 2011 and 2013. However, its operation has not been smooth due to the increasing number of households rapidly leaving the district heating system. This study surveyed 76 households that participated in the district heating system using forest biomass in the early stages of the project. This includes households participating in the district heating system(participating households) and households not currently participating in the district heating system(withdrawal households) from September 2019. Surveys focused on the process of participating in forest carbon cycle village projects, and satisfaction in local heating and policy requirements. Of the 67 households, excepting those not allowed to participate in the survey due to death or having moved elsewhere, 36 households participated and 31 households the were in the process of leaving the village were also included. As a result, there was a significant difference between participating and exiting households in the motivation and satisfaction level of district heating. The results of this study are expects to reflect the importance of awareness of residents in the operation of the forest carbon cycle village. This will be utilized as an important dataset for improvement as a means to promote the re-entry if outgoing households. It will also help set the direction of the forest town revitalization project, utilizing forest biomass in the future.

• Journal of the Korean Wood Science and Technology
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• v.33 no.6 s.134
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• pp.71-78
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• 2005

For the utilization of chestnut inner bark as forest biomass, this studies have been carried out cleary investigated about phenolic compounds from the diethyl ether solubles and ethyl acetate solubles of hot water extract from chestnut inner bark. 3 compound were isolated and their structures were identified by spectroscopic methods. They were known compounds, 3,5-dihydroxybenzoic acid, 3,4,5-trihydrixybenzoic acid and catechin. Electron donating ability (EDA) of 3 compounds were investigated. Gallic acid and catechin were found to higher EDA than control, ascorbic acid and $\alpha$-tocopherol in 10 ppm, and especially gallic acid has very higher EDA, 21 times than ascorbic acid. This gallic acid of chemical structure were substituted with free phenolic hydroxyl groups at meta and para position. It was supposed that phenolic hydroxyl groups in chemical structure was a EDA factor.

• Journal of the Korean Wood Science and Technology
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• v.43 no.4
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• pp.518-527
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• 2015

In this study, nanocomposite mats consisting of cellulose nanocrystals (CNCs) and poly(lactic acide) (PLA) were electrospun from a suspension mixture consisting of tetrahydrofuran at room temperature. Morphology study showed that fibers of electrospun composite mats were aligned in three dimensional surface along the fiber long-axis. Average diameter of the electrospun fibers decreased with an increase in the CNC loading level. Tensile strength of the electrospun fibers mat decreased with an increase in the CNC loading level because of bead formation in the formed fibers and low interfacial bond strength between PLA and CNC. Meanwhile, thermal stability of the electrospun nanocomposite mats was effectively improved as the amount of CNC increased.

• Journal of the Korean GEO-environmental Society
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• v.13 no.3
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• pp.59-70
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• 2012

In this study, to select the best stabilizer for the heavy metals-contaminated soil from a smelter area during phytoremediation, a plant uptake experiment and a soil stabilization were simultaneously applied using Pteris multifida Poir. and five pre-screened stabilizers(zeolite, Mn dioxide, slag, Ca oxide, and magnetite). The extracted heavy metal was measured and compared using a 3 step sequential extraction for the soil samples. The growth rate of the plant was also evaluated. The stabilizers stabilized heavy metals in soil and reduced the extraction rate. Magnetite and calcium oxide showed better results than other stabilizers. The stabilizers enhanced the growth of the plant. All the heavy metals except for arsenic were concentrated in roots while arsenic was concentrated in leaves of the plant. It is concluded that the stabilizers can minimize the heavy metal release from the contaminated soil during phytoremediation and stimulated the growth of plant. These effects of stabilizers could compensate for some weak points of phytoremediation such as reaching of heavy metals by rainwater.