• Title/Summary/Keyword: 미정상수결정

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A study on development of reaction rate equation for reactive flow simulation in energetic materials (고에너지 물질의 연소반응 해석을 위한 반응속도식 개발 및 정의에 관한 연구)

  • Kim, Bo-Hoon;Yoh, Jai-Ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.331-341
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    • 2012
  • A modified Ignition and Growth(I&G) model which is necessary to simulate the combustion phenomena of energetic materials and an analytical model determining the unknown parameters of the reaction rate equation are proposed. The modified I&G model sustains important physical implications with overcoming some problems of previous rate equations. This rate model consist of Ignition term which represent the formation of the hotspot due to void collapse and Growth term which means the shock to detonation transition phenomena. Also, the theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, b, G, x, I. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

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A Study on Development of Reaction Rate Equation for Reactive Flow Simulation in Energetic Materials (고에너지 물질의 연소반응 해석을 위한 반응속도식 개발 및 정의에 관한 연구)

  • Kim, Bo-Hoon;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.5
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    • pp.47-57
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    • 2012
  • A modified ignition and growth(I&G) model which is necessary to simulate the combustion phenomena of energetic materials and an analytical model determining the unknown parameters of the reaction rate equation are proposed. The modified I&G model sustains important physical implications with overcoming some problems of previous rate equations. This rate model consists of ignition term which represents the formation of the hotspot due to void collapse and growth term which means the shock to detonation transition phenomena. Also, the theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, $b,\;G,\;x,\;I$. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

Analytic model to determine the unknown parameters of JWL++ rate equation (JWL++ 반응속도식의 미정상수 결정을 위한 화약의 이론적 모델)

  • Kim, Bohoon;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.283-286
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    • 2012
  • The analytical model determining the unknown parameters of reaction rate equation which is necessary to simulate the combustion phenomena of energetic materials is proposed. The relationship between detonation velocity and size effect of energetic materials is derived from simplified JWL++ model. Theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, b. When b=0.8, the behavior of HANFO gunpowder is in the form of concave-up and ANFO explosives has the concave-down form in case of b=1.5. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

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Dielectric and Piezoelectric Properties of $Fe_2O_3$-Added $0.4Pb(Ni_{1/3}Nb_{2/3})O_3-0.6Pb(Zr_xTi_{1-x})O_3$ Ceramics with Variatior of Zr/Ti Ratio ($Fe_2O_3$가 첨가된 $0.4Pb(Ni_{1/3}Nb_{2/3})O_3-0.6Pb(Zr_xTi_{1-x})O_3$ 세라믹스에서의 PZ/PT비 변화에 따른 유전 및 압전 특성)

  • Paik, Jong-Hoo;Lim, Eun-Kyeong;Kim, Sei-Ki;Lee, Mi-Jae;Jee, Mi-Jung;Choi, Byung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.338-339
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    • 2005
  • 본 연구에서는 $Fe_2O_3$를 첨가한 $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr_xTi_{1-x})O_3$ 세라믹스에서 Zr/Ti 비 변화에 따른 소결 및 압전, 유전특성을 조사하였다. $0.4Pb(Ni_{1/3}Nb_{2/3})O_3-0.6Pb(Zr_xTi_{1-x})O_3$+0.25Wt% $Fe_2O_3$ 계에서 Zr/(Ti+Zr)비(x)를 0.39에서 0.42까지 변화시킨 조성을 1100 - $1250^{\circ}C$ 온도에서 2시간 소결하여 이의 결정구조 및 미세조직을 분석하였고, 압전, 유전 특성 및 RAINBOW 액츄에이터로의 응용을 조사하였다. $1150^{\circ}C$에서 소결한 0.405 조성(x)에서 유전상수(${\varepsilon}r$) = 4669, 전기기계결합계수(kp) = 0.75, 압전상수($d_{33}$) = 810 pC/N의 우수한 특성 값을 나타내었으며, 닥터블레이드법에 의해 RAINBOW 액츄에이터를 제작하여 변위특성을 조사하였다.

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Dielectric and Piezoelectric Properties of $MnO_2$-Added 0.4P$(Ni_{1/3}Nb_{2/3})O_3-xPbTiO_3-yPbZrO_3$ Ceramics with Variation of PZ/PT Ratio ($MnO_2$ 가 첨가된 0.4P$(Ni_{1/3}Nb_{2/3})O_3-xPbTiO_3-yPbZrO_3$ 세라믹스에서의 PZ/PT비 변화에 따른 유전 및 압전 특성)

  • Paik, Jong-Hoo;Kim, Chang-Il;Lim, Eun-Kyeong;Lee, Mi-Jae;Ji, Mi-Jeong;Choi, Byung-Hyun;Kim, Sei-Ki
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.169-170
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    • 2005
  • 본 연구에서는 초음파 센서에 응용 가능한 $0.4Pb(Ni_{1/3}Nb_{2/3})O_3-0.6Pb(Zr_xTi_{1-x})O_3+0.5Wt%$ $MnO_2$ 세라믹스에 Zr/(Ti+Zr)비를 0.37에서 0.41로 변화시킨 조성을 1175 $\sim$ 1200$^{\circ}C$ 온도에서 소결하여 이의 결정구조 및 미세조직을 분석하였고, 압전, 유전 특성을 고찰하였다. 본조성에서 x=0.385 조성에서 최대 유전상수 값 3490 이 나타났으며, 그 이상의 첨가에서는 감소하였다. 상경계 영역인 x=0.385 조성에서 $\varepsilon$r, $K_p$, $d_{33}$ 값이 최대값을 나타내었다. $0.4Pb(Ni_{1/3}Nb_{2/3})O_3-0.6Pb(Zr_xTi_{1-x})O_3+0.5Wt%$ $MnO_2$, 세라믹스에서는 kp 와 $d_{33}$ 는 Zr/(Ti+Zr)비 0.385조성까지 증가하였다가 그 이상 조성에서 감소하였다. $1175^{\circ}C$에서 2시간 소결한 x=0.385조성에서 $\varepsilon$r=3490, kp=0.71, Qm=476의 우수한 압전 특성을 나타내었다.

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