• Title/Summary/Keyword: 미소수화발열

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Properties of Hydration Heat with Compressive Strength Level of High Flowing Self-Compacting Concrete (고유동 자기충전 콘크리트의 압축강도 수준에 따른 수화발열 특성)

  • Choi, Yun Wang;Jung, Jea Gwone;Lee, Jae Nam;Kim, Byoung Kwon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5A
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    • pp.531-541
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    • 2009
  • The research analyzes and investigates conventional concrete, hydration heat, set, and mechanical properties by making high flowing self-compacting concretes of binary blend and ternary blend as one of evaluations about the properties of the hydration heat of high flowing self-compacting concrete with a strength of 30, 50, and 70 MPa. In addition, it estimates concrete adiabatic temperatures by calculating a thermal property value of powder obtained by measuring a heat evolution amount for powder used in concrete, a thermal property value of concrete obtained by conducting a simple adiabatic temperature test, and a normal thermal property value of material used in concrete, using a simple equation. Moreover, it analyzes and investigates the hydration heat property of high flowing self-compacting concrete and the thermal stress caused by hydration heat by conducting a 3D temperature stress analysis for the hydration heat and the adiabatic temperature obtained by temperature analysis, using MIDAS CIVIL 06 program.

Investigation of the Effects of CNT Dosages on the Hydration and Heating Properties of Cement Composites with Low Water-to-binder Ratio (낮은 물-바인더 비를 갖는 시멘트 복합체의 CNT 첨가량에 따른 수화특성 및 발열특성)

  • Oh, Sungwoo;Jung, Sang-hwa;Chung, Wonseok;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.182-188
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    • 2018
  • Recently, various researches on the utilization of carbon nanotube(CNT) with superior electrical conductivity and large surface areas into concrete have been actively conducted. Thus, mechanical and thermal properties of cement-flyash composites were evaluated concerning the CNT replacements. Based on the low binder-to-water ratio, the cement composites were produced with 0.2 % and 0.5 % of CNT solids. The compressive strengths with various ages, isothermal calorimetry measurement, SEM analysis, thermal conductivity of cement composites and thermal gravimetry analysis were implemented. As the amount of CNT addition was increased, the thermal conductivity of cement composites were also increased. Also, there was no significant mechanical property differences between mixtures with and without CNTs.

Hydration Heat Properties of High Flowing Self-Compacting Concrete with Normal Strength (보통강도 고유동 자기충전 콘크리트의 수화발열 특성)

  • Choi, Yun-Wang;Kim, Byoung-Kwon;Lee, Jae-Nam;Ryu, Deug-Hyun;Song, Yong-Kyu;Jung, Woo-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.497-500
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    • 2008
  • This research carries out experiments for hydration exothermic rate and adiabatic temperature rise of concrete to examine the characteristics of the hydration heat of high flowing self-compacting concrete with a normal strength. As a result of the hydration exothermic rate experiment, the high flowing self-compacting concrete that used Lime stone powder and fly ash as polymers shows that its hydration heat amount reduces due to the reduction of unit cement. The result measured the adiabatic temperature rise of concrete presents that high flowing self-compacting concrete having lots of binder contents has a good performance in temperature reduction due to the effect of polymer and that triple adding high flowing self-compacting concrete has a similar temperature rise speed with conventional concrete. As a result of the research, high flowing self-compacting concrete shows a better temperature reduction performance for the binder content per unit than conventional concrete. In addition, it is judged that triple adding high flowing self-compacting concrete with a specified concrete strength 30 MPa is more beneficial in temperature reduction and early hydration heat than double adding high flowing self-compacting concrete.

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The Experimental Study on the Heat Hydration Properties of Concrete According to Binder Conditions (결합재 조건에 따른 콘크리트의 수화발열 특성에 관한 연구)

  • Choi, Sung-Woo;Jo, Hyun-Tae;Ryu, Deuk-Hyun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.769-776
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    • 2006
  • Recently, owing to the development of industry and the improvement of building techniques, concrete structures are becoming larger and higher. In hardening of these large connote structures, the heat of hydration gives rise to considerable thermal stress depending on the size and environmental condition of concrete, which might cause thermal cracking. Especially, the crack may cause severe damage to the safety and the durability of concrete structure. This study investigates the thermal properties of concrete according to several binder conditions, such as OPC, Belite rich cement(BRC), slag cement(SC), blast furnace slag(B) added cement fly ash(F) added cement and blast-furnace-slag and fly ash added cement. As a result of this study, the properly of concrete is most better BRC than others, and fly ash(25%) added cement and BFS(35%)-fly ash(15%) added cement gets superior effect in the control of heat hydration. But synthetically considered properties of concrete, workablity, strength heat hydration, etc, it is more effective to use mineral admixture. Especially, to be used Blast Furnace slag is more effective.

Study on the Hydration and Strength Properties of Fly-ash Modified Cement Paste and Mortar Using a CSA and Pulp Ash (CSA 및 제지애쉬를 혼합재료 사용한 플라이애쉬 시멘트 모르타르의 수화 및 강도 특성에 관한 연구)

  • Song, Tae-Hyeob;Lee, Sea-Hyun;So, Chee-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.81-88
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    • 2005
  • The fly ash has been widely used in the latest to complement the performance and economical efficiency of the concrete which uses only a normal portland cement, the pulp ash gained through the incineration of paper sludge is possible to be used as the material of concrete because it contains the properties similar to the previous fly ash in ingredients and physical characteristics. Therefore, this research has tested physical characteristics by replacing 20% of fly ash used with the paper ash to solve the problem which lowers the early strength caused when the fly ash was used. As a result, it showed that the fluidity becomes lower and the compressive strength becomes increased by using paper ash. In addition, after mixing the paper ash with the fly ash, it showed that time and heating amount of the 2nd peak of the minor heat of hydration affecting the revelation of strength was equivalent to the combination for normal portland cement, and also indicated that the compressive strength for 3 days is superior to the combination of the fly ash. Therefore, if the paper ash having a regular fineness is used, it was effective in improving the early strength of concrete used the fly ash.

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An Experimental Study on Hydration and Strength Development of High Blain Cement at Low Temperature (저온환경에서 고분말도 시멘트의 수화반응 및 강도발현 특성에 관한 실험적 연구)

  • Mun, Young-Bum;Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Kim, Jae-Young;Lee, Han-Seung;Kim, Mok-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.367-373
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    • 2015
  • In this study, fundamental properties of cement were reviewed to apply high fineness cement at low temperature environment. The classified high fineness cement has large proportion of particles below $10{\mu}m$ which affects early hydration: an overall reaction of cement hydration faster. As a result of using high fineness cement, setting time of concrete was reduced and compressive strength was higher than OPC at all ages. Especially, compressive strength was more than double its value compared with OPC after three days curing in low temperature. Faster reaction and higher heat of hydration was verified by calorimetry early and maximum heat of hydration was analyzed by adiabatic temperature raising test. The analysis of this study confirmed that high fineness cement can be suitable to be used in low temperature environment.

A Fundamental Properties of the Concrete Using Coarse Particle Cement and Mineral Admixture (굵은입자 시멘트와 광물질 혼화재를 조합 사용하는 콘크리트의 기초적 특성)

  • Han, Cheon-Goo;Jang, Duk-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.131-138
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    • 2010
  • This research intends to analyze the basic characteristics of cements(hereinafter "CC") with affordable price and particle distribution effective as hydration heat face which are discharged at the outlet of smashing process of ordinary portland cement(hereinafter "OPC") manufacturing process such as fluidity, rigidity, temporary insulation temperature increase amount etc to review the potential of developing "CC" to 3 ingredients low heat cement that substitutes fly ash and blast furnace slag(hereinafter "BS"). As a result of experiment, fluidity tended to decrease with increase in CC substitution rate, and increase with increase in FA+BS substitution rate. Air amount tended to slightly decrease with increase in CC substitution rate, and decrease with increase in FA+BS substitution rate. Condensation characteristics were such that condensation time was delayed with increase in CC and FA+BS substitution rate. As for the temperature rising amount by temporary insulation, peak temperature decreased with increase in CC substitution rate and increase in FA+BS substitution rate in general, and thereafter, temperature tended to decrease slowly. Compressive strength decreased with increase in CC and FA+BS substitution rate, and as aging goes on, long term strength was equivalent to plain or higher. By and large, when FA+BS was substituted to CC, fluidity and air amount tended to decrease, but hydration heat face showed good reduction effects, suggesting possibility of development to 3 ingredients low heat cement.

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Evaluation of Hydration Characteristics and NOx-removal Performances of Cement Paste Containing Refined TiO2 Obtained from Waste Sludge (폐수 슬러지에서 정제된 TiO2를 혼입한 시멘트 페이스트의 수화특성 및 질소산화물 제거 성능 평가)

  • Yoon, Hyunno;Seo, Joonho;Kim, Seonhyeok;Bae, Jinho;Kil, Taegeon;Lee, Haeng-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.357-364
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    • 2021
  • The present study investigated the hydration properties and NOx-removal performances of the cement pastes containing three different types of TiO2. Two commercially available TiO2 (P-25 and NP-400) and refined TiO2 (GST) obtained from waste sludge were incorporated to cement paste at levels of 0, 5, 10, and 20 wt%. Isothermal calorimetry test results indicated that the TiO2 incorporation induced a notable influence on the reaction kinetics of cement paste, showing the highest cumulative heat release in the samples containing P-25, followed by NP-400 and GST. Quantitative X-ray diffractometry as calculated by the Rietveld method identified that the incorporated TiO2 promoted the formation of C-S-H, ultimately leading to the enhancement in the 28 day-compressive strength of cement pastes. As revealed by SEM/EDS analysis, the content of distributed Ti elements on the surface of the samples was in the order of P-25, GST, and NP-400. Regardless, the NOx-removal performance was the highest in the sample containing P-25, followed by NP-400 and GST.

Investigation on the Characteristics of Interfacial Transition Zone (ITZ) of High-Strength Cement Mortar Incorporating Graphene Oxide (그래핀 옥사이드 혼입 고강도 시멘트 모르타르의 Interfacial Transition Zone (ITZ) 특성에 관한 연구)

  • Im, Su-Min;Cho, Seong-Min;Liu, Jun-Xing;Lim, Seungmin;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.343-350
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    • 2022
  • In recent years, nanomaterials, such as nano-silica, carbon nanotubes, and graphene oxide (GO), have been suggested to improve the properties of the interfacial transition zone (ITZ) between aggregates and cement pastes, which has most adversely affected the strength of quasi-brittle concrete. Among the nanomaterials, GO with superior dispersibility has been reported to be effective in improving the properties of ITZ of normal-strength concrete by forming interfacial chemical bonds with Ca2+ ions abundant in ITZ. In this study, the effect of GO on the properties of ITZ in the high-strength mortar was elucidated by calculating the change in hydration heat release, ITZ thickness, and the porosity around ISO sand, which was obtained with isothermal calorimetry tests and scanning electron microscope image analysis, respectively.