• Title/Summary/Keyword: 미세 기공

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아크릴 폐직물을 이용하여 제조한 활성탄소의 기공구조 발현 과정

  • 유소영;윤창훈;박연흠;박종래
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.489-492
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    • 1998
  • 흡착 기능을 가지는 소재로서 오래 전부터 사용되어 온 활성탄소는 최근 환경에 대한 관심이 고조되면서 새삼 주목의 대상이 되고 있는 소재이다. 제품의 형태는 사용 목적에 따라 다르지만 보편화 된 것은 주로 입상 및 분말 상이다. 하지만 이러한 형태는 비표면적이 작고 기공분포가 넓은 단점 때문에 미세 오염물의 제거에는 부적합한 면이 있다[1]. (중략)

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Porosity in Thick Aluminium Alloy Welds (Causes and Prevention) (후판 알루미늄 합금 용접의 기공 발생과 방지대책)

  • 김종희;박동환
    • Journal of Welding and Joining
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    • v.12 no.1
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    • pp.7-15
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    • 1994
  • 알루미늄합금의 용도가 우주 항공기 부품에서 자동차, 선박, 건축 등 다양화되면서 이들 재료에 대한 용접기술 또한 산업현장의 주요한 과제로 등장하게 되었다. 알루미늄합금은 극히 활성이 높고, 열전도율이나 열팽창계수가 매우 큰 물리적 특성 및 액상과 고상간의 매우 큰 수소 용해도 차이 등의 특이한 성질을 가지고 있기 때문에 용접에 있어서는 기공이나 미세한 융합 불량이 발생하기 쉽고, 또 용접변형의 제어에도 세심한 배려를 요하는 등 우수한 용접부를 만들기 위해서 고려해야 할 문제를 가지고 있다. 특히 기공이 후판 알루미늄 합금 용접에 있어서 보수공사의 대부분을 차지하고 있으므로 기공 방지법을 확립하는 것은 매우 중요하다. 알루미늄 합금의 용접에 있어서 기공의 발생원인은 수소에 의한 것이라고 정립되어 있으나 그 방지법에 대해서는 많은 연구검토가 행해지고 있음에도 불구하고 수소의 공급경로가 매우 다양하고 복잡하기 때문에 아직 체계적으로 확립되어 있지 못한 실정이다. 본 해설에서는 후판 알루미늄 용접시 가장 큰 문제가 되는 기공의 발생 원인과 방지대책을 기 발표된 자료를 기초로 하여 요약 정리함으로써 앞으로 여러 생산현장에서의 알루미늄합금 용접 특히 MIG 용접 관련 문제점 해결에 도움이 되고자 한다.

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Well-Aligned Nano-Sized Pores Using Aluminum Thin Film Fabricated by Aluminum Anodized Oxidation Method (알루미늄 박막을 이용하여 양극산화법으로 제작한 규칙적으로 정렬된 미세기공)

  • Han, Ga-Ram;Yun, Tae-Uk;Kang, Min-Ki;NamGung, Hyun-Min;Kim, Chang-Kyo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.207-207
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    • 2010
  • 알루미늄 양극산화 기술은 저가로 공정이 가능하고, 경제적이며 규칙적인 배열의 나노 미터 크기의 미세기공을 형성할 수 있다는 장점을 가지고 있다. 인가전압, 양극산화 용액의 종류, 용액의 농도 및 온도 등의 양극산화 조건을 변화시킴에 따라 나노 기공의 직경 및 길이, 밀도 조절이 용이하다. 알루미늄 판 (aluminum plate)을 이용한 양극산화 기술은 상대적으로 많이 알려져 있으나 알루미늄 박막을 이용한 양극산화기술은 아직도 확립되어 있지 않다. 본 실험에서는 실리콘 기판에 Al을 $5000{\AA}$$8000{\AA}$으로 증착시켜서 기판으로 이용하였다. 아주 얇은 두께의 Al은 작은 변화에도 민감하게 반응하기 때문에 공정 변수인 온도와 전압의 정밀한 제어가 되어야 나노 기공의 크기 조절이 가능한 것을 확인하였다.

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Oxidation of Phenol Using Ozone-containing Microbubbles Formed by Electrostatic Spray (전기장에 의해 생성된 미세기포를 이용한 페놀의 오존산화)

  • Shin, Won-Tae;Jung, Yoo-Jin;Sung, Nak-Chang
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1292-1297
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    • 2005
  • The use of ozone in water and wastewater treatment systems has been known to be a process that is limited by mass transfer. The most effective way to overcome this limitation is to increase the interfacial area available for mass transfer by decreasing the size of the ozone gas bubbles that are dispersed in solution. Electrostatic spraying(ES) of ozone into water was investigated in this work as a method of increasing the rate of mass transfer of ozone into a solution and thereby increasing the rate of phenol oxidation. Results were obtained for ES at input power levels ranging from 0 to 4 kV and compared with two different pore-size bubble diffusers($10{\sim}15{\mu}m$ and $40{\sim}60{\mu}m$). It was determined that the rate of mass transfer could be increased by as much as 40% when the applied voltage was increased from 0 to 4 kV as a result of the smaller bubbles generated by ES. In addition, ES was shown to be more effective than the medium-pore-size($10{\sim}15{\mu}m$) bubble diffuser and the best results were achieved at low gas flow rates.

Influence of the Micropore Structures of PAN-based Activated Carbon Fibers on Nerve Agent Simulant Gas (DMMP) Sensing Property (PAN계 활성탄소섬유의 미세기공 구조가 신경작용제 유사가스(DMMP) 감응 특성에 미치는 영향)

  • Kang, Da Hee;Kim, Min-Ji;Jo, Hanjoo;Choi, Ye Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.191-195
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    • 2018
  • In this study, the influence of microporous structures of activated carbon fibers (ACFs) on dimethyl methylphosphonate (DMMP) gas sensing properties as a nerve agent simulant was investigated. The pore structure was given to carbon fibers by chemical activation process, and an electrode was fabricated for gas sensors by using these fibers. The PAN based ACF electrode, which is an N-type semiconductor, received electrons from a reducing gas such as DMMP, and then electrical resistance of its electrode finally decreased because of the reduced density of electron holes. The sensitivity of the fabricated DMMP gas sensor increased from 1.7% to 5.1% as the micropore volume increased. It is attributed that as micropores were formed for adsorbing DMMP whose molecular size was 0.57 nm, electron transfer between DMMP and ACF was facilitated. In conclusion, it is considered that the appropriate pore structure control of ACFs plays an important role in fabricating the DMMP gas sensor with a high sensitivity.

Electrochemical Characteristics of Microporous Polymer Electrolytes Based on Poly(vinylidene-co-hexafluoropropylene) (PVdF계 미세기공 고분자 전해질의 전기화학적 특성)

  • Jung Kang-Kook;Kim Jong-Uk;Ahn Jou-Hyeon;Kim Ki-Won;Ahn Hyo-Jun
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.183-188
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    • 2004
  • In order to develop polymer electrolyte for lithium/sulfur batteries, highly microporous P(VdF-HFP) membranes were prepared by phase inversion method. Porous structure was controlled by extracting NMP with mixture of deionized water and methanol. Porous structure of the membranes was observed with SEM. Polymer electrolytes were prepared by soaking the porous membranes in 1M $LiCF_3SO_3-TEGDME/EC$. The ionic conductivity of polymer electrolyte was found to be at high as $2\times10^{-3}S/cm$ when the polymer membrane extracted by $80\%$ methanol was used. The microporous polymer electrolyte optimized in this work displayed high ionic conductivity, uniform pore size, low interfacial resistance and stable ionic conductivity with storage time. The ionic conductivity of polymer electrolytes was measured with various lithium salts, and the conductivity showed $3.3\times10^{-3}S/cm$ at room temperature when $LiPF_6$ was used as a lithium salt.

Effect of Granulation and Compaction Methods on the Microstructure and Its Related Properties of SOFC Anode (과립형성 및 성형방법에 따른 SOFC 음극의 미세구조 및 특성)

  • Heo, Jang-Won;Lee, Jong-Ho;Hwang, Jin-Ha;Moon, Joo-Ho
    • Journal of the Korean Electrochemical Society
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    • v.6 no.1
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    • pp.53-58
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    • 2003
  • It is well known that the anode substrate of anode-supported type SOFC should have high electrical conductivity and high gas permeability to minimize the polarization loss of the cell performance during operation. In this study, we made anode substrates of SOFC with two different methods, which gave different anode microstructures, especially different pore structures with each other. We performed electrical and microstructural characterization of Ni/YSZ cermet anode via extensive measurements of its electrical conductivity and gas permeability combined with adequate image analysis based on quantitative stereological theory

Effect of the Pore Structure on the Anodic Property of SOFC (SOFC 음극의 기공구조가 음극특성에 미치는 영향)

  • 허장원;이동석;이종호;김재동;김주선;이해원;문주호
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.86-91
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    • 2002
  • Solid Oxide Fuel Cells (SOFC) are of great interest of next generation energy conversion system due to their high energy efficiency and environmental friendliness. The basic SOFC unit consists of anode, cathode and solid electrolyte. Among these components, anode plays the most important role for the oxidation of fuel to generate electricity and also behaves as a substrate of the whole cell. It is normally requested that the anode materials should have the high electrical conductivity and gas permeability to reduce the polarization loss of the cell. In this study, the effect of pore former on the microstructure of anode substrate was investigated and thus on the electrical conductivity and the gas permeability. According to the results, microstructure and electrical conductivity of anode substrate were greatly influenced by the shape of pore former and especially by the anisotrpy of the pore former. The use of anisotropic pore former is supposed to deteriorate the cell performance by which the electrical conduction path is disconnected but also the effective gas diffusion path for the fuel is reduced.

Analysis of Pore Structure for Porous Body with Coal Fly ash and Clay (석탄회-점토계 다공체의 기공구조 분석)

  • 이기강;박천주
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.64-70
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    • 1998
  • Porous body was prepared from coal fly ash 70 wt%0clay 30 wt% slip using DCC(Direct Coagulated Casting) method. Effect of the specific gravity of the slip on the pore size and distribution of the sintered body was examined by the SEM observation of microstructure and mercury porosimetry measurement of the pore size distribution. Average pore size of the porous sintered body was about 2.5μm for all slips with specific gravity of 1.55, 1.60 and 1.65g/cm3, respectively. Sintered body prepared from the slip of specific gravity of 1.60g/cm3 have the narrowest pore size distribution. slip of specific gravity of 1.55g/cm3 shows broader pore size distribution due to slow gellation process. Slip of specific gravity of 1.65g/cm3 required large amount of deflocculant and showed large variation of the viscosity with addition of coagulant which resulted in very unstable slip properties.

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Thickness-dependent Film Resistance of Thin Porous Film (얇은 다공 구조 박막에서의 두께에 따른 박막 저항 변화)

  • Song, A-Ree;Kim, Chul-Sung;Kouh, Tae-Joon
    • Journal of the Korean Magnetics Society
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    • v.22 no.1
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    • pp.6-10
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    • 2012
  • We have observed the change in the film resistance of thin nickel film up to 13 nm, which is deposited on a porous anodic alumina substrate, prepared by two-step anodization technique under phosphoric acid. The resulting film grows as a porous film, following the pore structure on the surface of the alumina substrate, and the value of the resistance lies above $150k{\Omega}$ within the range of thickness studied here, decreasing very slowly with the film thickness. The observed resistance value is much higher than the reported value of a uniform film at the same thickness. Since the observed value of the surface coverage with the pores is smaller than the critical value, expected from the percolation theory, the pore structure limits the formation of conduction channel across the film. In addition, by comparing to the typical model of thickness-dependent resistivity, we expect that the scattering at the pore edge further increases the film resistance.