• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.5
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• pp.545-552
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• 2018

In this study, we performed a mesocosm experiment to estimate the mass balance of Nutrients (DIN, DIP) in a phragmites australis community. We developed 4 mesocosm tanks which is available to circulate seawater with adjustable tide levels and flooding times. Each of the mesocosm tanks were filled with phragmites australis and sediment from Jinudo in Nakdong Estuary. We investigated DIN, DIP concentrations in three layers (seawater-phragmites australis-sediment) to estimate the mass balance of Nutrients and biomass. Growth rates were also investigated. The results can be summarized as follows. 1) In spring, rhizome biomass was higher than that of aerial stem by about 6.3~9.7%. In summer, aerial stem biomass was higher than that of rhizome about 19.2~21.2 %. 2) Th Growth rate of phragmites in Mesocosm Tank A was faster than in Mesocosm Tank D by about 2 to 3 times for aerial stem and rhizome. 3) The Concentration of nutrients (DIN, DIP) in each mesocosm Tank showed 2~3 % variance in spring and summer. 4) The biomass in each mesocosm varied by about 23 % which was higher than the concentration variance for each mesocosm tanks.

• Journal of Energy Engineering
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• v.12 no.4
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• pp.289-301
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• 2003

To develop a chemical-looping combustion technology, conceptual design of 50 kW thermal chemical-looping combustor, which is composed of two interconnected pressurized circulating fluidized beds, was performed by means of mass and energy balance calculations. A riser type fast fluidized bed was selected as an oxidizer and a bubbling fluidized bed was selected as a reducer by mass balance for the chemical-looping combustor. Calculated values of bed mass, solid circulation flux, and reactor dimension by mass and energy balance calculations were suitable for construction and operation of chemical-looping combustor. It is concluded from the comparison of the design results and operating values of commercial circulating fluidized bed that the process outline is realistic. Moreover, the previous results support that oxygen carrier particle, NiO/bentonite, fulfills the conversion rates needed for the proposed design. The effects of system capacity, metal oxide content in a oxygen carrier particle, amount of steam input, gas velocity, and solid depth on design values were investigated and the changes in the system performance can be estimated by proposed design tool.

• Journal of the Korean Society for Marine Environment & Energy
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• v.3 no.3
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• pp.50-57
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• 2000

Budgets of fresh water, salt, DIN and DIP in the Nakdong river estuary were estimated in order to clarify the characteristics of material cycling and fluxes of nutrients with a simple box model. Freshwater inflow into this system was approximately 1.1E＋10m³/y, water exchange was 3.3E＋10m³/y and water residence time was 2.03 day assumed with salinity between estuary and adjacent ocean. Nutrients loadings were 3.2E＋09mol DIN/y3.7×10³, 2.7E＋07mo1 DIP/y, respectively. net ecosystem metabolism was 2.4E＋07mo1 C/y. Although the Nakdong river discharge was the main source of nutrients but Jang-rim sewage treatment plant effluent take parts of 16% of nitrogen and 10.2% of phosphorus loadings.

• Proceedings of the Korea Water Resources Association Conference
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• 2008.05a
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• pp.1713-1716
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• 2008

최근 배출되는 미량유해물질로 1991년 페놀, 2004년 1,4-다이옥산, 2006년 퍼클로레이트 검출 등 빈번하게 원수수질 오염사고가 발생하고 새로운 미량유해 화학물질의 배출이 우려됨에 따라, 일부 시민단체, 시의회, 언론 등에서 깨끗하고 안전한 상수원수 확보를 위한 근본적인 대책을 요구하는 목소리가 커지고 있다. 이에 대한 대책의 일환으로 취수원 이전에 대한 타당성 등이 검토되고 있다. 이러한 요구를 바탕으로 본 연구에서는 K-WEAP 모형을 이용하여 낙동강수계 물수지 분석을 실시하였다. 관련된 기존자료를 이용하여 용수수요량을 산정하였으며, 갈수량시 물수지 분석을 실시하였다. 연구에 사용된 K-WEAP 모형은 SEI-B(Srockholm Environment Institute, Boston Center)에서 개발된 WEAP에 기반을 두고 우리나라에 특성에 맞게 모의형태를 개선하고 한글화한 모형으로 분석대상 지역으로서 도시지역과 농업지역, 단일 소유역이나 복잡한 하천유역의 물 수요-공급 시스템에 적용할 수 있다. 또한 K-WEAP 모형은 용수목적별 수요량 분석, 물 절약, 수리권과 배분 우선순위, 지하수와 하천유량 모의, 저수지 운영, 수력발전, 오염물질 추적, 생태계 필요수량 분석과 같은 광범위한 부문의 문제들까지 다룰 수 있다. 본 연구에서 물수지 분석에 사용된 대상구간은 낙동지점에서 고령교지점까지 약 120km이며, 낙동강에 유입되는 지류로는 감천과 금호강을 대상에 포함하였다. 대상구간에 대해서는 3가지의 시나리오를 바탕으로 모의를 진행하였다. 선정된 3가지 시나리오는 현재의 대구 인근지역의 취수와 방류를 고려하는 상태와 현실가능성이 있는 2가지의 대안에 대해서 분석을 실시해 보았다. 대안들은 각각의 대구 취수시설을 구미 상류로 이전하여 취수하는 상황과 구미지역 및 칠곡지역의 방류구 시설을 하류로 이전하여 방류하는 상황으로 가정하여 분석을 실시하였다. 분석결과 현재 상태의 시나리오에서만 갈수기시 만족할 만한 결과를 보여주었고 나머지 2가지의 시나리오에서는 유량이 부족함을 나타났다. 현재의 상태를 모의한 시나리오를 제외한 시나리오의 분석에서는 갈수기 시에 물 부족을 겪게 된다. 이는 낙동강 상류에서 추가방류가 없으면 해결되지 못하는 상황으로 다른 대안들(신규 댐 방류 등)에 대한 추가적인 시나리오 분석이 필요할 것으로 판단된다.

• Journal of the Korean Wood Science and Technology
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• v.44 no.3
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• pp.389-397
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• 2016

In this study, ethanol was produced from a biomass hydrolysate that had been treated by electrodialysis (ED) and Amberlite XAD resin to remove fermentation inhibitors. Most of the acetic acid (95.6%) was removed during the ED process. Non-ionizable compounds such as total phenolic compounds, 5-hydroxymethyl furfural, and furfural were effectively removed by the XAD resin treatment. Ethanol production was improved when the ED-treated hydrolysate was treated with XAD-4 resin for a short reaction time. The highest ethanol production from ED-treated hydrolysate was $6.16g/{\ell}$ (after 72 h of fermentation) when the treatment with XAD-4 resin was for 5 min. Among the lignin-derived fermentation inhibitors tested, syringaldehyde in low concentrations (1 and 2 mM) in the hydrolysate increased ethanol production, whereas a high concentration (5 mM) inhibited the ethanol production process. A synthetic medium containing syringaldehyde and ferulic acid was prepared to investigate the synergistic effect of inhibitors on ethanol fermentation. Ethanol production decreased in the mixture of 1 mM syringaldehyde and 1 mM ferulic acid, implying that the effect of ferulic acid on ethanol fermentation is comparable to that of syringaldehyde.

• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.139-147
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• 1997

펄프폐수 내에 존재하는 대표적인 수지 구성성분의 일종인 wood resin 화합물이 메탄생성균에 미치는 독성을 평가하기 위한 회분식 독성실험을 수행하였다. 수지는 극성용매로 추출가능한 몇몇 wood 구성성분의 혼합물로서 수지의 주요 구성성분은 긴 사슬 휘발성유기산, terpenes, resin acids, 리그난과 극성 페놀류들이다. 메탄생성균의 독성실험은 $30^{\circ}C$에서 표준회분식 실험방법을 채택하였고 식종물질로서는 입상슬러지를 사용하였다. 극성페놀의 한 종류인 4-hydroxystilbene가 가장 높은 독성을 나타내었으며, 50% 저해를 일으키는 농도는 $20mg/\ell$이었다. Resin acid와 휘발성 terpene 역시 메탄생성균에 독성을 나타내었으며, 50% 독성을 일으키는 농도는 $43{\;}~{\;}330mg/\ell$이었다. 반면에 triterpenes은 1,000 to $1,300{\;}mg/\ell$의 상대적으로 높은 농도에서도 메탄생성균에 독성을 일으키지 않았다. 따라서 wood resin의 구성성분이 몇몇 펄프폐수의 혐기성 처리에 있어서 독성을 일으키는 주요물질이었다.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.10a
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• pp.176-179
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• 2003

범용 엔지니어링 플라스틱(Engineering plastic)인 PET(Polyethylene terephthalate)수지는 투명성, 강도특성, 내열특성, 기체차단성 등 물성이 우수하여 합성섬유, 이축연신 film, 식음료용 bottle 등의 용도로 널리 사용되는 적용범위가 매우 넓은 고분자 소재이다. 그러나 폐기된 PET 수지를 물질재활용(material recycling) 방법으로 재가공할 경우 수지 자체가 갖는 가수분해(hydrolysis)와 열분해(thermal degradation) 특성으로 인해 가공성 및 기계적 특성이 현저히 저하되는 단점이 있다.(중략)

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.1
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• pp.1-10
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• 2016

In this paper, an analysis of the inflowing pollution load of the rivers in Hampyeong bay showed the average organic matter pollution loads of BOD, COD, and TOC to be 79.7 kg-BOD/day, 144.06 kg-COD/day, and 93.0 kg-TOC/day, respectively. The inflowing organic matter pollution load was the heaviest in Sonbul dike, followed by Jupo bridge and Yangman complex. With regard to season, the load characteristics were outstanding in July, the rainy period in the summer. The average inflowing pollution loads of nutrients were 20.9 kg-DIN/day, 17.1 kg-DIP/day, 148 kg-TN/day, and 37.4 kg-TP/day A comparison of the inflowing nutrients loads for each river showed the load to be the heaviest in Yangman complex, followed by Baegok bridge and Jupo bridge. In the experiment on the material budgets of Hampyeong bridge conducted using a box model, the detention time of fresh water was found to be 52.4 days, with the bay displaying the characteristics of a so dissolved inorganic nitrogen (DIN) in the nutrients material budgets, ${\Delta}DIN$ values were found to be negative, indicating the tendency of consumption and open sea leak by photosynthesis to be higher than the nitrogen that flowed in. As for dissolved inorganic phosphorus (DIP), ${\Delta}DIP$ showed positive values, indicating a tendency for accumulation as the supply through organic matter decomposition, elution load of sediments, and inflowing load of the river turned out to be higher than the consumption by phytoplankton and outflow to open sea.

• Korean Journal of Heritage: History & Science
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• v.54 no.4
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• pp.78-89
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• 2021

Organic residues analysis is an analysis method that reveals the types of organic material samples by using the characteristic that main components constituting substances are different depending on the species of animals and plants. In this study, scientific analysis of the organic residues attached to wood coffins in the Joseon Dynasty Hoemyo excavated from the site of Singok-dong, Uijeongbu was used to identify the types of remnants and to use them as information to restore the uses of organic materials and the way they lived in the past. As a result of FT-IR analysis of the residue attached to the inside of the wood, it was estimated to be a natural plant resin material. In addition, as a result of analysis by GC-MS to confirm the characteristic factors of natural resins, diterpenoids (abietane) and pimaran (pimarane), such as dehydroabietic acid and pimaric acid (diterpenoid) compounds, and saturated and unsaturated fatty acid components were detected together. Diterpenoid compounds are components mainly found in Pinaceae resins. It is confirmed in the literature that rosin, a representative material of Pinaceae resin, was used as an adhesive material. Considering the situation where an organic material remained at the joint of the wood, the organic material attached to the wood is judged to be an adhesive material made of Pinaceae resin. In addition, the fatty acid component detected together is a component derived from plant oil, and it is presumed to be made by mixing rosin and oil as recorded in previous studies. This study confirms that organic residues remain in the burial environment without losing their characteristics. It is expected that scientific analysis of organic residues will be conducted in the future to accumulate information necessary for the interpretation of past living culture.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.05a
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• pp.120-125
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• 1993

석탄가스화 복합사이클 발전시스템에서 스팀터빈 발전시스템은 1차 사이클인 가스터빈사이클에서 나오는 폐열을 이용하여 발생하는 증기로 구동되며, 증기의 일부는 가스화기로 들어가서 가스화 반응에 이용된다. 이와 같은 시스템의 설계나 평가를 위해서는, 주어진 시스템에 대한 열 및 물질수지 정산을 구할 수 있는 능력을 갖추는 것이 필요하다. 본 연구에서는 주어진 시스템의 성능을 평가할 수 있는 프로그램을 개발하여 IGCC(Integrated Gasification Combined Cycle)System의 증기터빈 사이클과 유사한 증기터빈기계의 열 및 물질정사고 성능 해석에 적용하였다. (중략)