• Title/Summary/Keyword: 물질전달 계수

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Carbon Dioxide Absorption in a Packed Column Using Guanidine-based Superbase Solution (구아니딘계 초염기 흡수제에 의한 충진탑에서의 이산화탄소 포집 특성)

  • Choi, Young Min;Hong, Yeon Ki;You, Jong Kyun
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.648-652
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    • 2016
  • The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.

Solvent diffusion model in polymer membrane (고분자막내에서 용매 확산 모델)

  • 김종수;이광래
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.59-62
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    • 1998
  • 1. 서론 : 막내부에서 물질전달을 설명하는 이론으로 현재 solution-diffusion model과 pore-flow model 두 가지가 있다. 이 중에서 흡착, 확산, 탈착의 3과정을 거치는 solution-diffusion model이 주로 사용되고 있다. 본 연구에서는 solution-diffusion model 에서 상호확산계수를 구하기 위해서 Vrentas-Duda식을 이용하여 자기확산계수를 구하고 Bearman식으로부터 상호확산계수를 구하는 과정을 UNIFAC-FV와 modified UNIFAC-FV을 이용하여 계산하였으며 Flory-Huggins식을 이용한 기존방법과 비교하였다.(생략)

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Effect of Free Stream Turbulence Intensity on Heat/Mass Transfer Characteristics Around a Film Cooling Hole (주유동의 난류강도가 막냉각홀 주위의 열/물질전달 특성에 미치는 영향)

  • 이동호;김병기;조형희
    • Journal of the Korean Society of Propulsion Engineers
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    • v.2 no.2
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    • pp.56-63
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    • 1998
  • The present study investigated local heat transfer characteristics around a film cooling hole with variations of free stream turbulence intensity The film cooling jet is injected through a single hole inclined at $30^{\cire}$ to the surface and laterally at $45^{\cire}$ for the blowing rates of 0.5, 1.0 and 2.0. Turbulence generating grids are used at upstream of the film cooling hole to change the turbulence intensity of free stream. Free stream turbulence intensity without grids is 0.5%. Two different turbulence generating grid is installed at different at locations upstream of the film cooling hole so that turbulence intensity of free stream varies from 3% to 10%. The naphthalene sublimation technique has been employed to determine local heat/ mass transfer coefficients. With low free stream turbulence intensity, heat/mass transfer augmented area by coolant or free stream is distinguished evidently. However, when free stream turbulence intensity is high, heat transfer is enhanced in all region and heat transfer enhanced regions are not clearly divided due to vigorous mixing of coolant and free stream. The peak values of heat/mass coefficients are decreased and the distributions of heat/mass transfer coefficients are more uniform with high turbulence intensity. The effect of turbulence intensity on heat transfer characteristics is more evident as blowing rate is higher.

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The Computer Simulation and Estimation of Membrane Mass Transfer Coefficients of Hollow Fiber Membrane G-L Contactors for SO2 Removal (SO2 제거를 위한 중공사막 기-액 접촉기의 모사 및 분리막 물질 전달 계수 추정)

  • Kim, Yong Kuk;Song, Hee Ouel;Lee, Hyung Keun;Kim, In-Won
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.81-86
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    • 2007
  • Hollow fiber membrane G-L contactors are widely used to remove $SO_2$ emitted from industrial facilities. In this work, the mathematical modeling and computer simulation for hollow membrane G-L contactors is carried out to analyze $SO_2$ absorption behavior in hollow fiber membranes. The model is solved with the finite element method using a commercial software. Investigated is the dependency of $SO_2$ removal efficiency and mass transfer characteristics on gas velocities, membrane mass transfer coefficients and physical properties of contactors. The membrane mass transfer coefficients are estimated by fitting the experimental data with the simulated $SO_2$ removal efficiencies. In addition, a design methodology of membrane contactors is suggested.

Experimental Evaluation Method of Mass Transfer Coefficient on Biotrickling Filtration for Air Pollution Control (대기오염제어를 위한 생물살수여과법에서 물질전달계수 실험평가방법에 관한 연구)

  • Won, Yang-Soo;Jo, Wan-Keun
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.482-488
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    • 2015
  • Biological treatment is promising alternative to conventional air pollution control method. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing volatile organic compounds and odor. The studies of mass transfer in biotrickling filters for air pollution control were of importance in order to control and optimize the purification process. The objectives of this study were to develop the experimental methodologies to evaluate the mass transfer coefficients of gas/liquid(trickling liquid), gas/solid(biomass) and liquid/solid in three phase biotrickling filtration. Also, this study characterized the influence factors on mass transfer such as dynamic holdup volume, gas/liquid flow rate ratio, biomass weight in reactor and recirculation rate of trickling medium for each phase of biotrickling filter.

Effect of Salinity on Dissolved Oxygen Characteristics in an Ejector-Aerator (이젝터-폭기 시스템의 용존산소특성에 미치는 염도의 영향)

  • Yang, Hei-Cheon;Park, Sang-Kyoo
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.5
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    • pp.640-646
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    • 2011
  • Dissolved oxygen (DO) refers to the volume of oxygen that is contained in water, and is a major indicator of water quality. The objective of this paper was to investigate the effect of salinity on the dissolved oxygen characteristics in an ejector-aerator. An experimental aeration system composed of a motor-pump, an ejector, a motor-blower, a set of aeration and recirculation tank and a control panel. The dissolved oxygen concentrations decreased with the water salinity. The volumetric mass transfer coefficient increased with increasing the water salinity.

A Study on the Combustion Properties of Single-Port Hybrid propulsion System with Various Fuel (Single port 하이브리드 추진 시스템의 연료에 따른 연소특성 연구)

  • You Woo-Jun;Kim Jin-Kon;Lee Jung-Pyo;Kim Soo-Jong;Lee Seung-Chul;Kuk Tae-Seung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.368-372
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    • 2005
  • The variation of regression rate of single port hybrid rocket was studied with various fuel. As fuel, PE, PMMA were used and gas oxygen as oxidizer. The regression rate depends on but flow rates of oxidizer also thermodynamic properties of fuel. In this study, the empirical relation for regression rate of solid fuel were found with mass transfer coefficient(B number) and oxidizer flow rate.

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Prediction on heat and mass transfer coefficients in a packed layer of a regenerator with a solar desiccant cooling system (태양열제습냉방시스템 중 재생기의 충진층 내 열물질 전달계수에 관한 예측)

  • Eflita, Yohana;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.30 no.4
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    • pp.36-42
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    • 2010
  • 본 논문은 태양열이용 냉난방시스템 중에서 실제로 액체흡수제를 재생하는 재생탑 내의 충진층에 있어서의 열 및 물질전달의 실험치와 이론적 해석에 의한 결과치와의 비교를 나타내고 있다.특히 물질전달의 극대화를 위하여 충진층 내에서 공기와 흡수제의 접촉면적을 크게 할 필요가 있는데,이를 위해서 본 실험에서는 직경이 3cm인 플라스틱제 충진재를 사용하였으며, 흡수제로는 저농도의 염화리튬 수용액이 사용 되었다. 충진층 내에서의 최적 높이를 예측하기 위하여 해석의 모델인 실험장치를 직접 제작하여 실험을 수행하였고, 이론 해석에 있어서 체적 열전달을 고려한 정상상태를 모델화하여 해석하였다. 이 결과, 충진층 내에서 실험치와 이론적인 계산치가 잘 일치함을 알 수 있었으며, 충진층의 높이가 2m 이상인 경우에는 높이에 따른 재생량의 차이가 없어서 없음을 알 수 있었다.

Analysis of the Behavior of Tubular-Type Equipment for Nuclear Waste Treatment : Sensitivities of the Parameters Affecting Mass Transfer Yield (방사성폐기물의 화학처리공정에 사용되는 유동관식 장치의 해석 : 물질전달 수율에 미치는 매개변수들의 민감도)

  • Yoo, Jae-Hyung;Lee, Byung-Jik;Shim, Joon-Bo;Kim, Eung-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.91-99
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    • 2007
  • It was intended in this study to investigate the effects of various parameters on the chemical reaction or mass transfer yield in a tubular-type nuclear waste treatment equipment. Since such equipments, as a tubular reactor, multistage solvent extractor, and adsorption column, accompany chemical reaction or mass transfer along the fluid-flowing direction, mathematical modeling for each equipment was carried out first. Then their behaviors of the chemical reaction or mass transfer were predicted through computer simulations. The inherent major parameters for each equipment were chosen and their sensitivities. affecting the reaction or mass transfer yield were analyzed. For the tubular reactor, the effects of axial diffusion coefficient and reaction rate constant on the reaction yield were investigated. As for the multistage solvent extractor, the backmixing of continuous phase and the distribution coefficient between fluid and solvent were considered as the major parameters affecting the extraction yield as well as concentration profiles throughout the axial direction of the extractor. For the adsorption column, the equilibrium constant between fluid and adsorbent surface, and the overall mass transfer coefficient between the two phases were taken as the major factors that affect the adsorption rate.

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Local Convective Mass Transfer and Flow Structure Around a Circular Cylinder with Annular Fins (환상핀이 부착된 원봉 주위의 3차원 박리 유동구조 및 물질전달 특성 해석)

  • 박태선;성형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.2132-2146
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    • 1991
  • Extensive experiments were carried out to investigate the mass transfer and flow structures around a circular cylinder with annular fins in crossflow. The naphthalene sublimation method was employed to measure the circumferential and longitudinal variations of mass transfer from the circular cylinder between annular fins and H is the height of the fin from the cylinder surface. A remarkable enhancement of mass transfer due to the horseshoe vortices was observed near the corner junction between the annular fin and circular cylinder. The present results indicate that the local circumferential Sherwood number shows the higher values on the front stagnation point. The maximum augmentation of mass transfer rate at the center of cylinder is found near L/H-0.15 due to the separation bubble along the annular fins. The secondary flows, which are the corner vortices V2 and V3 near the end wall of the annular fin, are fairly predicted from the distributions of local Sherwood number in the spanwise direction. The average Sherwood number of overall surface at L/H=0.15 is larger 2.0 times than that of without annualr fins. The correlations of total average mass transfer rate with L/H and Re$_{L}$ can also be obtained.d.