• Analytical Science and Technology
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• v.28 no.6
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• pp.446-452
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• 2015

In order to evaluate and improve the ability of Korean testing laboratories to measure Polybrominated diphenyl ethers in acrylonitrile-butadiene-styrene (ABS), a proficiency test was organised by Korea Research Institute of Standards and Science (KRISS) based on ISO/IEC 17043. The proficiency test material used was 10 g of a granular ABS fortified with a mixture of congeners of PBDE (BDE-154, 183, 206, 209). Homogeneity and stability were investigated to assess the adequacy of the test material. The certified value established by KRISS based on the national reference was used for assigned value of each PBDE. The test materials were distributed to the 16 participating laboratories. The participating laboratories were requested to analyse the samples employing the methods used in their routine analysis. Each laboratory was given it’s own code to secure the anonymity. Participants results were evaluated with z-scores according to ISO/IEC 17043. The standard deviation for proficiency assessment was set by standard deviation of the participants results except for outlier. The results, the laboratory's performance and improvement of accuracy were discussed.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.3
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• pp.277-282
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• 2007

For more accurate and practical design of the residual treatment train at water treatment plants(WTPs), a computational program based on the commercial spreadsheet, Microsoft Excel, was developed. The computational program for the design of a residual treatment train(DRTT) works in three steps which estimate the residual production to be treated, analyze the mass balance, and determine the size of each unit process. Of particular interest in the DRTT program, is provision for a filter backwash recycle system consisting of surge tank and sedimentation basin for more efficient recycling of backwash water. When the DRTT program was applied to the Chungju WTP, the program was very beneficial in avoiding errors which might have occurred during arithmetic calculations and in reducing the time needed to get the output. It is anticipated that the DRTT program could be used for design of new WTPs as well as the rehabilitation of existing ones.

• The Korean Journal of Ecology
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• v.25 no.2
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• pp.119-125
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• 2002

In order to elucidate the budget and cycling of Nitrogen and Sulfur, esential elements and principal constituents of acid rain, their input through precipitation, and their output by streamflow were quantified in coniferous and deciduous forested watersheds, using combination of nutrient concentration and hydrological analysis, in Kwangnung Experimental Forest from July 1991 to Decmeber 1993. Amount of annual mean precipitation was 12.916 ton·ha/sup -1/·yr/sup -1/, annual mean runoff 5,094 ton·ha/sup -1/·yr/sup -1/(39%), 7,647 ton·ha/sup -1/·yr/sup -1/(59%) in coniferous and deciduous forest watersheds, respectively. Amounts of annual input of N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄ through preciptation were 12.5, 81.7 kg·ha/sup -1/·yr/sup -1/, respectively. Annual output via runoff of N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄were 0.06, 39.23 ton·ha/sup -1/·yr/sup -1/ in the coniferous forest watershed ecosystem, and 0.15, 55.46 ton·ha/sup -1/·yr/sup -1/ in the deciduous one, respectively. On the basis of annual nutrient input and output, the annual budget of N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄were +12.46, +42.49 ton·ha/sup -1/·yr/sup -1/ in the coniferous forest watershed, and +11.35, +26.26 ton·ha/sup -1/·yr/sup -1/ in the deciduous one. Thus N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄were accumulated in both forested watershed ecosystems.

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.549-553
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• 2003

SMB(simulated moving bed) chromatography system has been developed to realize continuous separation and save solvent consumption for binary mixture such as chiral compounds in especial. The parameters of SMB chromatography system can be calculated from mass balance equations of true moving bed chromatography, and they are used in design of 6-column SMB chromatography. We can separate 1'R-25 and 1'S-2S enantiomers as a raffinate product in 95% of purity using assembled SMB chromatography system.

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.506-510
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• 2003

SMB(simulated moving bed) chromatography system has been developed to realize continuous separation and save solvent consumption for binary mixture in especial. The parameters of SMB chromatography system can be calculated from mass balance equations of true moving bed chromatography, and they are used in design of 6-column SMB chromatography. We can separate S-ketoprofen enantiomer as a raffinate product in 85% of purity and 0.3mg/ml using assembled SMB chromatography system.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.148-148
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• 2023

산업 고도화로 인하여 복잡하고 다양한 유기물의 사용량이 증가하였으며, 공공수역 내 새로운 오염물질이 유입됨에 따라 생화학적 산소요구량(BOD) 중심의 수질평가에 한계를 나타내었다. 이후 난분해성 물질을 고려한 유기물관리 정책과 총량관리의 필요성이 제기되었고 국내 하천과 호소에서는 총 유기탄소(TOC)를 유기물 관리지표로 설정하였다. 그러나 부영양 하천과 호소에서 TOC는 외부 부하뿐만아니라 식물플랑크톤의 과잉성장에 의해 증가할 수 있는 항목이므로 TOC 관리정책 추진을 위해서는 유기물의 기원에 대한 파악이 필요하다. 한편, 우리나라와 같이 몬순 기후대에 속한 댐 저수지의 경우 강우시 유입하는 탁수에 의해 다량의 유기물과 인이 유입되기도 하지만 식물플랑크톤의 제한요인 중 광량에 많은 영향을 미친다. 식물플랑크톤의 광합성은 수체 내 유기탄소 내부생성에 매우 중요한 요소이나 점 단위의 실험적 방법을 활용한 유기탄소 순환 해석은 저수지의 시·공간적인 변동성을 고려하기에 한계가 있다. 본 연구의 목적은 금강 수계 최대 상수원인 대청호를 대상으로 3차원 수리-수질 모델을 적용하여 유기탄소 성분 별 유입과 유출, 내부생성 및 소멸량을 평가하고 탁수가 저수지에서의 유기탄소 순환에 미치는 영향을 분석하는데 있다. 유기탄소 물질수지 해석을 위해 AEM3D 모델을 사용하였으며 2018년을 대상으로 입력자료를 구축한 후 보정 및 검정을 수행하였다. 모델은 유기탄소를 입자성, 용존성, 그리고 난분해성과 생분해성으로 구분하여 모의하며 유기물질 성상별 실험결과를 이용하여 입력자료를 구축하였으며 유기탄소순환 해석을 위해 4가지의 탄소성분과 조류 세포 내 탄소의 질량 변화율을 계산하였다. 이를 위해 외부 유입·유출부하율, 수체 내 생성(일차생산, 재부상, 퇴적물과 수체 간 확산) 및 소멸률(POC 및 조류 침강, DOC 무기화, 탈질)을 고려하였으며 탁수의 영향을 분석하기 위해 탁수 포함여부 시나리오를 구성하고 유기탄소 생성 및 소멸기작별 변동성을 비교 분석하였다. 모델은 2018년의 물수지를 적절히 재현하였으며 저수지의 수온 및 탁도 성층구조를 잘 재현해내면서 전반적인 수질을 적절하게 모의하였다. 탁수를 고려하였을 시 연간 TOC 부하량 중 내부기원 부하량은 56% 수준이였으나 탁수를 배제한 경우 내부기원 부하량은 82%로 나타났다. 특히, 연평균 Chl-a 농도가 44~48% 차이가 발생하면서 1차생산량이 약 4배가량 증가하였다. 몬순지역에서의 탁수는 체류시간이 긴 성층 저수지에서 식물플랑크톤 성장제어에 큰 영향을 미쳤으며 전반적인 유기탄소 순환을 해석하는데 있어 매우 중요한 인자로 작용하였다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1995.11a
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• pp.115-115
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• 1995

다중 효용관식 증발기는 보통의 증발기에서 응축하여 제거하는 증기를 다음 효용관의 가열원으로 재사용하는 것으로 그 자체로도 에너지 절감효과가 있는 것으로 알려져 있다[1,2,4]. 기계식증기 재압축 증발기는 보통 증발기에서 응축시켜 제거하는 발생 증기를 압축하여 고온의 증기로 만든 다음 가열원으로 재이용하는 장치로 이에 대한 효용은 문헌에 잘 나타나있다[3,4]. 여기서는 다중효용관과 증기 재압축기를 조합한 증발기 중에서 Forward feed 방식의 다중효응관에 증기 재압축기를 부착한 경우에 대하여 타당한 물질수지, 열수지, 전열 식, 상평형식을 소개하였다. 또한 압축기의 용량을 결정하기 위한 단열압축공정의 지배방정 식을 소개하였다. 원료의 조건, 효용관의 수 및 총전열온도차가 주어지면 상기의 지배방정식의 해를 구할 수 있는데. 본연구에서는 Gauss-Seidel의 연속치환법을 이용하였다. 이와 같이 지배방적식의 해를 구하면 효용관의 면적, 압축펌프의 용량, 각효용관 입출구의 조건 등이 계산된다. 다중효용관 기계식 증기 재압축 증발장치의 최적화를 위하여는 효용관의 전열면적당 가격과 압축펌프의 용량당 가격 그리고 펌프를 운전하는데 필요한 전력의 요금 등의 자료가 요구된다. 총전열온도차에 따른 운전비와 시설비의 합이 최소가 되는 점이 최적 총전열온도차가 되는데 이 점을 구할 때에는 수치적으로 안정한 이분법을 이용하였다. Borland C++를 이용하여 프로그램하였으며 윈도우즈 환경에서 수행되게 하였다. 사용자 쉽게 이용할 수 있게 하기 위하여 각종 필요한 데이터를 입력할 수 있는 Edit box가 화면에 나타나게 하였다. 또한 입력된 데이터를 저장하거나 불려올 수 있는 메뉴, 입력된 데이타를 이용하여 효용관의 면적과 압축기의 용량을 계산하거나 효용관의 수가 주어졌을 때 총전열온도차를 최적화하는 것을 선택할 수 있는 메뉴 그리고 계산 결과를 파일로 혹은 프린트로 출력할 것을 선택할 수 있는 메뉴가 있다. 사용자는 해당되는 데이타를 입력한후 마우스로 원하는 작업의 메뉴를 선택하면 된다.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.7 no.4
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• pp.257-266
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• 2002

To estimate the nitrogen budget and assess the purification function of a tidal flat ecosystem, a field survey was carried out at Hajeon tidal flat in Gomso Bay, the southern part of Byeonsan Peninsula, Chollabuk-do, Korea. A study area of 3.0$\times$4.5 ㎢ was established on the tidal flat and the concentrations of chlorophyll-a, DIN, DON, and TN were measured in the water column during the period of April 17-18, 1999: From the budget analysis, the loss rate of Chl-a was estimated to be -0.05 mg Chl/㎡/hr, which is approximately 7% of that at Issiki tidal flat in Aichi Prefecture, Japan. The lower loss rate of Chl-a in the study area was attributable to the lower standing crop of phytoplankton, the lower temperature that may reduce metabolic rates of biotic components and the lower biomass of macrobenthos in the study area. Over the 13.5 ㎢ of study area, Hajeon tidal flat removed 8.36$\times$10$\^$2/ kg N/day of TN, 5.36$\times$10$\^$3/ kg N/day of PON and 1.62$\times$10$\^$2/ kg N/day of phytoplankton-related PON, showing that the tidal flats may play an important role in removing nitrogen in coastal waters. The removal rate of PON, compared to the removal cost of the existing waste water treatment facilities, indicates that the economic value of the purification function of Hajeon tidal flat (13.5㎢) may be more than that of two large facilities.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.8
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• pp.462-469
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• 2017

Eutrophication and shortage of phosphate ore raise the necessity of phosphate removal and recovery from wastewater treatment plants. Especially, a sludge treatment system containing highly concentrated phosphate should be targeted for phosphate removal and recovery. This study thus aimed to evaluate the capability of the struvite crystallization process for phosphate removal and recovery from a sludge treatment system of a wastewater treatment plant. Analysis on phosphate concentrations and masses in the sludge treatment system revealed that digested sludge and centrate have phosphate concentrations and masses, high enough to adopt the struvite crystallization process. Chemical equilibrium modeling indicated that the struvite crystallization reaction substantially occurred with pH higher than 8 and $Mg^{2+}$ concentration 1.2 times higher than its theoretical requirement. A series of batch tests with digested sludge and centrate indicated that the phosphate removal reaction by struvite crystallization followed a first-order kinetics and reached over 80% removal efficiency at equilibrium. Aeration in the batch tests was found to purge $CO_2$ in sludge or centrate and increase pH up to 8.7, without adding NaOH. Thus, we concluded that the struvite crystallization process could be an efficient and economical process for phosphate removal and recovery from a wastewater treatment plant.

• Journal of the Korean Society of Marine Environment & Safety
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• v.13 no.2 s.29
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• pp.111-118
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• 2007

Simple box budgets models are useful tools to understand the phenomena of natural system and to provide an insight into the complex processes including physical, chemical and biological processes occurring in natural system. Budgets of fresh water, salt and nutrients were estimated in order to clarify the characteristics of seasonal material cycle in the Masan Bay. Outflow volume of freshwater into system was approximately $307.4\times10^3\sim1,210\times10^3\;m^3/day$. Inflow masses of DIP and DIN were approximately $410.8\sim795.7\;kg/day$ and $4081.4\sim6525.3\;kg/day$, respectively. DIN is expected to accumulate in the system. The removal of nutrients from bottom sediments will contribute to the reduction of 21.0% of COD concentration in the system.