• KSBB Journal
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• v.14 no.3
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• pp.358-364
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• 1999

The effect of hydrogen peroxide on pretreatment of oakwood was investigated. Reaction temperature was $170^{\circ}C$ and reaction solutions used in pretreatment were aqueous ammonia, sulfuric acid and pure water. When 10% ammonia solution was used, the extents of delignification and hemicellulose recovery were 55% and 26%, respectively. These values were significantly higher as delinigfication and lower as hemicellulose recovery than those of acid hydrolysis. To overcome this problem, hydrogen peroxide was added into ammonia solution stream to increase hemicellulose recovery. But delignification and hemicellulose recovery were not increased as much as hydrogen peroxide loading was increased. And as hydrogen peroxide loading was increased, the decomposition of sugars solubilized from hemicellulose and cellulose were increased. So there were significant differences between the total amount in solid residue and liquid hydrolyzate, and the total amount in the original biomass. It was found that hydrogen peroxide added was reacted with substrate packed mostly in the front part of reactor. In order to increase hemicellulose recovery, it was necessary to treat with acidic solution than with alkali solution. Effect of hydrogen peroxide was higher in water than acid solution.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2009.06a
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• pp.291-291
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• 2009

한국원자력연구원의 파이로 실험 시설인 ACPF (ACP Facility)에는 공학규모 전해환원 반응기가 설치되어 공정 대용량화를 위한 연구가 수행되고 있다 본 연구에서는 전해환원 공정의 Scale-up을 위해 기존 반응기를 개선하여 전해환원 실험을 수행한 결과를 담고 있다. 장치의 대형화 빛 원격운전성 향상을 위해 기존의 전해환원 반응기의 상부 플랜지는 보다 간단하게 정리되었으며 염 이송에 의한 고온 조건 노출 시간을 줄임과 동시에 염 재사용을 목적으로 상부 플랜지는 이중으로 설계되었다. 따라서, 반응 종료후 전극이 설치된 상부 플랜지를 들어 올림으로서 반응기를 불활성 분위기로 유지하는 동시에 전해환원 금속전환체를 회수 할 수 있도록 반응기가 제작되었다. 또한, 새로운 반응기는 용융염 내의 강제 유동을 위해 아르곤 버블링이 가능하도록 설계 제작되었다. 새로 제작 설치된 전해환원 반응기를 사용하여 산화물 분말을 혼합하여 준비한 모의 사용후핵연료를 사용하여 전해환원 실험을 수행하였다. 그 결과, 산화물이 충진된 음극의 전영역에서 고루 96% 이상의 높은 금속전환율을 얻었으며 시간에 따라 선택된 FP들의 용융염 내 거동을 측정하였다. 실리더 형태의 음극에서 Cs, Sr 등의 원소들이 용융염으로 시간에 따라 용출되는 것을 확인하였으며 동시에 반응기 재질인 Fe 등도 일부 용융염에서 검출되었다. 아르곤 버블링에 의한 강제 유동은 전압 및 전류 거동에는 큰 영향을 미치지 못하였으나 염의 휘발량을 증가시켜 영조성올 변화시키는 것으로 측정되었다. ACPF의 전해환원 실험결과를 바탕으로 반응기를 상부 기체상과 하부 액체상으로 나누어 전산모사를 수행하였다 상부 기체상은 유입되는 아르곤 기체와 발생되는 산소기체의 흐름을 모사하는 결과를 얻었으며 온도 및 산소의 분압을 계산하였다. 하부 액체상에서는 전기장을 모사하여 전류 밀도 등을 3차원으로 모사하였다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.6
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• pp.21-29
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• 2014

This paper deals with the bonding characteristic of grouted joint connections of monopile support structures for offshore wind power facilities. For the integration of pile connection of wind power supporting structure, fiber reinforced high performance cementeous grout was developed and the ultimate compressive strength of it is 125MPa and the direct tensile strength is 7.5 MPa at 7 days. To assess the bond strength of grout filled in pile connection, small scaled direct bond tests under axially loaded was performed and analyzed according the existing guidelines. The fiber volume fraction (0%, 0.5% and 0.9%), aspect ratio of fiber (60 and 80) and the ratio of height to spacing of shear key (0.013 and 0.056) were adopted as the experimental variables. From the test results, the maximum bond strength among the all specimens was 30.8MPa and the bond strength of grouted connection was affected by the ratio of height to spacing of shear key than the fiber volume fraction.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.1
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• pp.233-241
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• 2005

The paper is presented experimental study results on bond stress between profiled steel and concrete in Profiled SPC(Profiled Steel Plate Concrete) rectangular steel tubes through an experimental program in which 13 pull-out specimens were tested. Advantages and class of composite members and current problems of construction work are noted, past research of PSSC is described. An experimental study is described and evaluated. The bond capacity is interrelated with slip at the steel concrete interface. The factors influencing the mechanism of bond stress transfer were the cross section shape, length/diameter, diameter/thickness and environmental parameters (temperature, moisture). The results of experimental program indicated that the force transfer could be characterized into two regions The first region was governed by bond with no relative slip between the profiled steel and concrete. The second region occurs after the chemical debonding. Bond stress transfer in this region was governed by frictional resistance between profiled steel and concrete and cross section shapes. The important factors influencing the magnitude of frictional resistance are the profiled steel shapes, length/diameter and environmental parameters. (temperature, moisture)

• Geotechnical Engineering
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• v.14 no.1
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• pp.5-14
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• 1998

In refuse landfill, long-term settlement is considerably dependent upon the biological decomposition of refuse which is distinguished from typical soil behavior. Two equations are combined in order to model long-term settlement behavior of refuse landfill caused by mechanical secondary compression and secondary compression caused by the decomposition of biolegradable refuse. It is suggested that mechanical secondary compression is linear with respcet to the logarithm of time. In order to estimate the settlement that occurs due. to the decomposition of biodegradable refuse, a mathematical model is used which theoretically conoiders the decomposition process related to the solubilization stage of biodegradable refuse solid. This model is based on hydrolysis process and expressed as first order kinetics. The proposed model is applied to Lysimeter compression data of an old refuse. This paper intends to propose the simplest mathematical model which effectively represents settlement caused by the solubilization stage of biodegradable refuse solid on decomposition process.

• Journal of the Korean Geophysical Society
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• v.2 no.3
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• pp.201-208
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• 1999

A high-resolution seismic profile acquired across the middle part of the Pungam Basin, one of the Cretaceous sedimentary basins in Korea, has been interpreted to delineate subsurface geological structures. Boundary faults, intrusive bodies, and unconformity surfaces are identified on the seismic section. Basin fills are divided into five depositional units (Units I, II, III, IV, and V in descending order). The normal faults were formed by transtentional movement along a sinistral strike-slip fault zone. Unconsolidated sediments, a weathered layer, and sedimentary layers overly the Precambrian gneiss. The granite body intruded at the southeastern part contacts the adjacent sedimentary rocks by a near-vertical fault. Granitic intrusions caused tectonic fractures and normal faults of various sizes. An andesitic intrusive body indicates post-depositional magmatic intrusions. Continuous strike-slip movements have deformed basin-filling sediments (Units I and II).

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.228-228
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• 2018

강변여과는 지하수 인공함양 방식 중 유도함양(induced recharge) 또는 간접함양 방식에 속한다. 이는 하천 및 강변 부근에 집수시설을 설치한 후, 미고결층 대수층(unconsolidated aquifer)의 자연 오염 저감능을 이용하여 지표수를 간접 취수하는 방식으로 수질이 불량한 지표수가 대수층을 관류하면서 희석, 화학적 이온 교환 및 반응, 흡착, 생물막(biofilm; 미생물에 의한 자연저감), 여과 등을 통하여 수질이 개선된다. 강변여과수내의 용존 농도가 높은 철과 망간은 수처리 비용증가, 용수관정 및 시설물의 수명단축을 초래한다. 따라서 강변여과 지역의 미고결 대수층에서 효과적인 철과 망간 동시 제거(vyredox)를 위해 에어서징(air surging)과 블록 서징(block surging)을 실시하기 위해서 실내 물탱크 모델(water tank model)에서 에어서징에 따른 공기 순환 우물시스템을 관찰하였으며, 이를 바탕으로 현장시험(Test bed)에 적용하였다. 미고결 대층수층에서의 철 망간은 음용수 기준치(각각 0.3 mg/L)를 초과하고 있으며, 강변여과 취수 개발 및 이용을 제한하는 요인이 되고 있다. 본 연구에서 사용된 에어서징과 블록서지 기술은 자갈층 및 미고결 대수층에 충진된 슬라임 및 폐색(clogging)을 제거함과 동시에 관정 주변의 대수층의 투수성 개선과 산화환경으로 치환되며, 대수층에 잔존하는 철/망간의 산화물들을 관정내로 빼낼 수 있는 방법이다. 따라서 서징에 따른 폐색 제거효율을 검토한 결과에서 철 망간 이온농도 저감효과와 관정 주변의 수리전도도(hydraulic conductivity) 및 저류계수(coefficient of storage)가 증가한 것으로 나타났다. 이와 같이 강변여과에 의한 폐색은 미고결층내 공기주입 및 블록서지를 통하여 철/망간 이온농도 저감 및 수리특성 개선 효과에 유용한 것으로 평가된다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.36-44
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• 2019

The purpose of this study is to evaluate the structural performance of press-formed type asymmetric column to beam connections of steel-PC composite module frames. Most of the column sections of the joints making up the modular frame use a closed square steel section. The column-beam connection using the closed column section has difficulty in reducing the workability and securing the fire resistance. In order to overcome this disadvantage, concrete is filled in the asymmetrical open type cross section of the steel plate by press forming. A total of four specimens were fabricated to investigate the structural performance of press formed type asymmetric column to beam connections. The experimental results show that the structural performance and behavior of the asymmetric columns are different depending on whether the asymmetric column cross section is composited or the column width thickness ratio. The structural performance of the press formed type asymmetric column to beam connection was evaluated by comparing the experimental results with the theoretical formulas.

• Journal of the Korea Institute of Building Construction
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• v.19 no.4
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• pp.299-306
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• 2019

In general, repair mortar is used to rehabilitate underground communities, but difficulties are encountered in the execution of long-term construction due to spatial co-operatives. In this study, the engineering properties of repair mortar according to the curing condition and accelerator type were reviewed. The results showed that the aluminate, alkali-free and calcium-aluminate precipitates in the water curing conditions showed higher compressive strength at the beginning of age than mortar specimens under air curing conditions, and increased. Especially in CA and AF test specimen with cement mineral quick setting, a large amount of ettringite products were observed compared with AL, thus reducing the pore volume and increasing the strength of the compound by micro-filling effect were found.

• Journal of Korean Society on Water Environment
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• v.27 no.2
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• pp.167-177
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• 2011

Billions of barrels of briny produced water are generated in the United States every year during oil and gas production. The first step toward recovering or reusing this water is to remove the hazardous organics dissolved in the briny produced water. Biological degradation of hazardous volatile compound could be possible regardless of salinity if they were extracted from briny water. In the current work, the effectiveness of a vapor phase biofilter to degrade the gas-phase contaminants (benzene, toluene, ethylbenzene and xylenes, BTEX) extracted from briny produced water was evaluated. The performance of biofilter system responded well to short periods when the BTEX feed to the biofilter was discontinued. To challenge the system further, the biofilter was subjected to periodic spikes in inlet BTEX concentration as would be expected when it is coupled to a Surfactant-Modified Zeolite (SMZ) bed. Results of these experiments indicate that although the BTEX removal efficiency declined under these conditions, it stabilized at 75% overall removal even when the biofilter was provided with BTEX-contaminated air only 8 hours out of every 24 hours. Benzene removal was found to be the most sensitive to time varying loading conditions. A passive, granular activated carbon bed was effective at attenuating and normalizing the peak BTEX loadings during SMZ regeneration over a range of VOC loads. Field testing of a SMZ bed coupled with an activated carbon buffering/biofilter column verified that this system could be used to remove and ultimately biodegrade the dissolved BTEX constituents in briny produced water.