• Journal of the Mineralogical Society of Korea
• /
• v.31 no.3
• /
• pp.173-182
• /
• 2018

The precipitation and phase transformation processes of iron minerals in acid mine drainage have a great influence on the behavior of trace elements in drainage. However, it is not easy to accurately trace these processes in natural environments, and therefore, most studies have carried out in the laboratory to obtain the information on the precipitation and transformation of those minerals. In this study, the precipitation of minerals and the changes of trace elements in drainage water were investigated at different pH values in actual acid mine drainage collected from the Dalsung mine. The amount of some precipitated minerals was not enough for the mineral identification. However, from the minerals identified, amorphous minerals were formed first, and then goethite was precipitated probably from schwertmannite. When the pH of the sample was high (10), amorphous phases of minerals were still observed at even high pH (pH 10). With increasing time, the pH values decreased by precipitation and transformation of minerals. All the elements showed low concentrations at high pH (8, 10), which might be due to the precipitation of minerals at high pH and the effect of surface charge, and the concentrations of elements gradually increased with time. In the case of sulfur, it also increased in water due to the transformation of schwertmannite to goethite.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.3 no.1
• /
• pp.65-70
• /
• 1970

This report is a part of the studies of the lower part of the Naktong River. The temperature and quality of the river water were investigated from May 1967 to June 1968. Except for Hadan which is a point located at the mouth of the river and much Influenced by sea water the average water temperature is generally below $10^{\circ}C$ up to the end of March, 10 to $20^{\circ}C$ from the beginning of April to the 1st-2nd ten days of May, and thereafter becomes above $20^{\circ}C$ which is adequate for the growth of warm-water fishes. The water again becomes below $20^{\circ}C$ at the beginning of October and becomes below $10^{\circ}C$ in December The difference of water temperature between at 7.00 a.m. and 4.00 p.m. is considerably great at Hadan, the mouth of the river, where the water is relatively stagnant. It shows an average monthly difference of 2.6 to $6.8^{\circ}C$ with a total average difference of $4.6^{\circ}C$. At the Kupo and Samrangjin stations the difference is very small For the basic data In the management of rivers, the water temperature should be measured twice a day at its highest and lowest temperatures, and the long term fluctuation of temperature should be investigated.

• Korean Chemical Engineering Research
• /
• v.50 no.3
• /
• pp.499-504
• /
• 2012

Characteristics of overall heat transfer were investigated in a three-phase slurry bubble column with relatively low surface tension media, which has been frequently encountered in the fields of industry. The heat transfer phenomena was examined in the system which was composed of a coaxial vertical heater and a proper of bubble column. The heat transfer coefficient was estimated from the measured mean value of temperature difference between the heater surface and the column proper at the steady state condition. Effects of gas velocity ($U_G$), solid fraction in the slurry phase ($C_S$) and surface tension (${\sigma}_L$) of continuous liquid media on the overall heat transfer coefficient (h) in the bubble column were determined. The mean value of temperature difference was estimated from the data of temperature difference fluctuations with a variation of time. The amplitude and mean value of temperature difference fluctuations with respect to the elasped time appeared to decrease with decreasing the surface tension of liquid phase. The overall heat transfer coefficient between the immersed heated and the bubble column increased with an increase in the gas velocity or solid fraction in the slurry phase, but it decreased with an increase in the surface tension of continuous liquid media. The overall heat coefficient in the slurry bubble column with relatively low surface tension media was well correlated in term of operating variables and dimensionless groups within this experimental conditions.

• Journal of the Korea Institute of Building Construction
• /
• v.20 no.5
• /
• pp.399-407
• /
• 2020

The aim of the research is to provide the boundary conditions for segregation of normal strength grade and high fluidity concrete mixture (so called mid-fluidity concrete) with rheology parameters. Since the normal strength grade concrete mixture has a relatively high water-to-cement ratio and no SCMs, it is easy to be segregated when superplasticizer is added. Hence, to achieve the mid-fluidity concrete of normal strength grade and high fluidity, preventing segregation of the mixture is inevitable. In this research, using two superplasticizers with different solid concentrations, the flow behaviors and rheological behaviors were assessed by increasing fluidity until the segregation happened. According to the experiment in this research, an unusual behavior in rheology parameters was observed when the concrete mixture started to be segregated. From this results and report, it is expected to contribute on the definition of segregation with rheological test methods.

• Water for future
• /
• v.14 no.4
• /
• pp.13-18
• /
• 1981

The rainfall pattern analysis on time distribution characteristics of rainfall rates in important in determination of design flow for hydraulic structures, particularly in urban area drainage network system design. The historical data from about 400 storm samples during 31 years in Seoul have been used to investigate the time distribution of 5-minute rainfall in the warm season. Time distribution relations have been deveolped for heavy stroms over 20mm in total rainfall and represented by relation percentage of total storm rainfall to percentage of total storm time and grouping the data according to the quartile in which rainfall was heaviest. And also time distribution presented in probability terms to provide quantitative information on inter-strom variability. The resulted time distribution relations are applicable to construction of rainfall hyetograph of design storm for determination of design flow hydrograph and identification of rainfall pattern at given watershed area. They can be used in conjuction with informations on spatstorm models for hydrologic applications. It was found that second-quartile storms occurred most frequently and fourth-quartile storms most infrequently. The time distribution characteristics resulted in this study have been presented in graphic forms such as time distribution curves with probability in cumulative percent of storm-time and precipitation, and selected histograms for first, second, third, and fourth quartile stroms.

• Magazine of the Korea Concrete Institute
• /
• v.8 no.5
• /
• pp.111-122
• /
• 1996

The effects of external restraint on the thermal stresses i n mass concrete are investigated through a series of parametric study. Two major factors affecting the degree of external restraint such as the ratio of length to height of the placed structure (L/H) and the elastic modulus of base structure ($E_r$) are employed as the parameters in a condition which a placing height H is 1.0m. Various conditions of I,/H and E, are analysed by a FEM program and the relationship between these two parameters is examined. The shape of stress distribution due to the external restraint is shown as linearity on the height direction of the section, and is influenced by L/H, $E_r$, and strength development of placed concrete. The external restraint can be devided by two part. One is an axial restraint and the other is a flexural restraint. When the level of external restraint is low, the structure behavior is mainly governed by flexural restraint, otherwise it is dependent on axial restraint. Comparing the calculated stress by the method of the ACI 207 committee with a finite element analysis, the fbrmer overestimates the external restraint stress when the degree of external restraint is weak, and underestimates when it is strong.

• Journal of Biomedical Engineering Research
• /
• v.18 no.3
• /
• pp.243-251
• /
• 1997

In this paper, we have reported two interesting flow effects arising in the TRFGE sequence using water flow phantom. First, we have shown that the TRFGE sequence is indeed not affected by "in-flow" effect from the unsaturated spins flowing into the imaging slice. Second, the enhancement of "in-plane flow" signal in the readout gradient direction was observed when the TRFGE sequence was used without flow compensation. These two results have many interesting applications in MR imaging other than fMRI. Results obtained were also compared with the results obtained by the conventional gradient echo(CGE) imaging. Experiments were performed at 4.7T MRI/S animal system (Biospec, BRUKER, Switzerland). A cylindrical phantom was made using acryl and a vinyl tube was inserted at the center(Fig. 1). The whole cylinder was filled with water doped with $MnCl_2$ and the center tube was filled with saline which flows in parallel to the main magnetic field along the tube. Tailored RF pulse was designed to have quadratic ($z^2$) phase distribution in slice direction(z). Imaging parameters were TR/TE = 55~85/10msec, flip angle = $30^{\circ}$, slice thickness = 2mm, matrix size = 256${\times}$256, and FOV= 10cm. In-flow effect : Axial images were obtained with and without flow using the CGE and TRFGE sequences, respectively. The flow direction was perpendicular to the image slice. In-plane flow : Sagittal images were obtained with and without flow using the TRGE sequence. The readout gradient was applied in parallel to the flow direction. We have observed that the "in-flow" effect did not affect the TRFGE image, while "in-plane flow" running along the readout gradient direction enhanced the signal in the TRFGE sequence when flow compensation gradient scheme was not used.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.32 no.6
• /
• pp.928-934
• /
• 2008

The objective of this study is to investigate the dyeing properties of safflower yellow dye on silk for the standardization of dyeing process and color reproducibility. Yellow colorants were water-extracted from safflower petals, concentrated, and freeze-dried to obtain colorants powder. The effects of dye concentration, dyeing temperature, and pH of dye bath were studied in terms of dye uptake and shade. Fastness to dry cleaning and light was evaluated. Dye uptake increased with raising temperature and brighter and more vivid yellow shade was obtained when dyed at $30^{\circ}C$. As colorants concentration increased, dye uptake increased progressively and the shade got darker and deeper. Maximum color strength was obtained at pH 3.5. It was speculated that the adsorption of colorants seemed to occur mainly by hydrogen bonding and physical force at pH 5.5 and by ionic bonding as well as hydrogen bonding below isoelectric point(pH 3.8-4.0). The results of reproducibility test showed acceptable color difference in the range of $1.11{\sim}2.01$. Washing fastness was fairly good as 4/5 rating, while light fastness was 2/3 rating.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.1
• /
• pp.216-222
• /
• 2020

A comparative analysis of farm incomes was performed from the new composition system of crops, such as feed crops, including soybeans, Italian ryegrass, soybean-potatoes, and soybean-barley planted in rice fields. Through this analysis, the suggested implications were derived, and the technological solutions were determined. The profitability of the composition of soybean-Italian ryegrass showed that the soybeans yield was 325kg/10a, and the sale price was ￦3,962/kg, leading to a gross revenue of ￦1,288,000/10a. The yield of Italian ryegrass was 1,584kg/10a with a sale price of ￦125/kg, showing a gross revenue of ￦198,000/10a. The net income of soybeans was ￦284,000/10a, which means a net income rate of 22.1%, whereas the net income of Italian ryegrass was -￦30,000/10a. The composition of soybeans-potatoes and soybeans-barley showed a gross revenue of ￦930,000/10a and ￦375,000/10a, respectively. The crop composition types have been developed for the Income Type, Production Type of Forage, Improvement Type of Food Self-Sufficiency, and Corresponding Type to Climate Change. On the other hand, regional types have not been developed sufficiently. In addition, various selections of alternative crops and the establishment of crop composition congruent to the specific regions should be developed systematically in terms of the production technology. Therefore, it is necessary to develop the technological establishment of the crop composition through continuous related studies with the mid-to-long term objectives of land utilization and grain self-sufficiency rates.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2000.02a
• /
• pp.123-123
• /
• 2000

선폭이 초미세화됨에 따라 게이트 전극에서의 공핍 현상 및 불순물 확산의 물제를 갖는 poly-Si 게이트를 대체할 전극 물질로 텅스텐(W)이 많이 연구되어 왔다. 반도체 소자의 배선물질로 일찍부터 사용되어온 텅스텐은 내화성 금속의 일종으로 용융점이 높고, 저항이 낮다. 그러나, 일반적으로 사용되고 있는 CVD에 의한 텅스텐의 증착은 반응가스(WF6)로부터 오는 불소(F)의 게이트 산화막내로의 확산으로 인해 MOS 소자가 크게 열화될수 있다. 본 연구에서는 W/TiN 이중 게이트 전극 구조를 갖는 MOS 캐패시터를 제작하여 전기적 특성을 살펴보았다. P-Type (100) Si위에 RTP를 이용, 85$0^{\circ}C$에서 110 의 열산화막을 성장 및 POA를 수행한 후, 반응성 스퍼터링법에 의해 상온, 6mTorr, N2/Ar=1/6 sccm, 100W 조건에서 TiN 박막을 150, 300, 500 의 3그룹으로 증착하였다. 그 위에 LPCVD 방법으로 35$0^{\circ}C$, 0.7Torr, WF6/SiH4/H2=5/5~10/500sccm 조건에서 2000~3000 의 텅스텐을 증착하였다. Photolithography 공정 및 습식 에칭을 통해 200$\mu\textrm{m}$$\times$200$\mu\textrm{m}$ 크기의 W/TiN 복층 게이트 MOSC를 제작하였다. W/TiN 복측 게이트 소자와 비교분석하기 위해 같은 조건의 산화막을 이용한 알루미늄(Al) 게이트, 텅스텐 게이트 MOSC를 제작하였다. 35$0^{\circ}C$에서 증착된 텅스텐 박막은 10~11$\Omega$/ 의 면저항을 가졌고 미소한 W(110) peak값을 나타내는 것으로 보아 비정질 상태에 가까웠다. TiN 박막의 경우 120~130$\Omega$/ 의 면저항을 가졌고 TiN (200)의 peak 값이 크게 나타난 반면, TiN(111) peak가 미소하게 나타났다. TiN 박막의 두께와 WF/SiH4의 가스비를 변화시켜가며 제작된 MOS 캐패시터를 HF 및 QS C-V, I-V 그리고 FNT를 통한 전자주입 방법을 이용하여 TiN 박막의 불소에 대한 확산 방지막 역할을 살펴 보았다. W/TiN 게이트 MOS 소자는 모두 순수 텅스텐 게이트보다 우수하였고, Al 게이트와 유사한 전기적 특성을 보여주었다. W/TiN 게이트 MOS 소자는 모두 순수 텅스텐 게이트보다 우수하였고, Al 게이트와 유사한 전기적 특성을 보여주었다. TiN 박막이 300 , 500 이고 WF6/SiH4의 가스비가 5:10인 경우 소자 특성이 우수하였으나, 5:5의 경우에는 FNT 전자주입 특성이 열화되기 시작하였다. 그리고, TiN박막의 두께가 150 으로 얇아질 경우에는 WF6/SiH4의 가스비가 5:10인 경우에서도 소자 특성이 열화되기 시작하였다. W/TiN 복층 게이트 MOS 캐패시터를 제작하여 전기적인 특성 분석결과, 순수 텅스텐 게이트 소자의 큰 저전계 누설 전류 특성을 해결할 수 있었으며, 불소확산에 영향을 주는 조건이 WF6/SiH4의 가스비에 크게 의존됨을 알 수 있었다. TiN 박막의 증착 공정이 최적화 될 경우, 0.1$\mu\textrm{m}$이하의 초미세소자용 게이트 전극으로서 텅스텐의 사용이 가능할 것으로 보여진다.