• Title/Summary/Keyword: 물성 향상

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저가 준결정질 붕소 분말의 밀링 및 탄소 도핑 처리에 따른 $MgB_2$ 초전도 임계전류밀도의 향상

  • Jeon, Byeong-Hyeok;Kim, Chan-Jung
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.32.1-32.1
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    • 2011
  • 39 K의 임계온도를 갖는 $MgB_2$ 초전도체를 이용한 전력에너지와 MRI 의료 기기로의 응용 가능성이 높아지고 있다. $MgB_2$ 초전도체 제조에 있어서 마그네슘과 반응성이 좋은 비정질의 붕소 원료 분말 가격이 비싼 반면 상대적으로 경제적인 결정질 분말의 기계적 밀링 공정을 이용하여 비정질화와 나노 입자로의 크기 감소 효과를 얻을 수 있다. 또한 탄소를 이용한 붕소 치환으로부터 고 자기장하에서 초전도 임계 성질을 향상시키고자 유, 무기물 형태의 여러 가지 탄소 소스를 개발하는 연구가 진행되어 왔다. 본 연구에서는 저가의 95~97% 순도, 약 1 ${\mu}m$ 이하 크기를 갖는 준결정상의 붕소 분말을 이용하여 기계적 밀링에 따른 붕소 분말의 비정질화 및 입자 나노화, $MgB_2$ 반응성 향상, $MgB_2$ 결정립 크기 감소 및 결정립계 피닝 증가에 의한 초전도 임계 물성 향상에 대하여 알아보았다. 또한 여러 시간 동안 밀링된 각 붕소 분말에 액체 글리세린을 이용한 탄소 도핑 전처리를 통하여 밀링 시간의 최적화를 알아보았고 이로부터 제조된 $MgB_2$ 초전도 벌크의 경우 적절한 임계온도 감소, 격자 왜곡 결함과 높은 결정립계 밀도 등에 의한 플럭스 피닝 향상으로 $MgB_2$ 초전도체의 임계전류밀도 및 비가역자기장이 증가함을 알 수 있었다. 즉, 경제성 있는 저급의 준결정상을 갖는 붕소 원료 분말의 입자 비정질 나노화 및 탄소 도핑 전처리를 통하여 $MgB_2$ 초전도 임계 물성을 향상시킬 수 있었다.

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Study on the Storage Stability of Horse Fat in Jeju (제주산 말지방(Horse Fat)의 저장 안정성 향상에 관한 연구)

  • Kim, Mi Seon;Yoon, Kyung-Sup
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.46 no.1
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    • pp.31-42
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    • 2020
  • Horse fat is known to be an effective ingredient in Asia, and the horse fat itself, which is mixed with other ingredients at the additive level, is often sold as a finished product. In this case, physical properties of the horse fat raw material are important. Many horse fats produced in Korea (Jeju) have low temperature stability, so if not stored at low temperatures, segregation may occur. In the case of Japanese horse fat, it is partially hydrogenated or is used the solid phase as the horse fat by separating the liquid phase and the solid phase that is harder and more stable than the horse fat of Jeju. In this study, the physical properties were tested to improve the temperature stability even without the partial hydrogenation process of Jeju horse fat. Various oil gelling agents were used in the study. Results confirmed that the physical properties of the hydroxystearic acid added Jeju horse fat were improved. In addition, stability evaluations at temperatures of 25 ℃, 40 ℃, 45 ℃ and flow behavior evaluations at temperatures of 25 ℃, 30 ℃, 40 ℃ were performed for Jeju horse fat with hydroxystearic acid, 100% Jeju horse fat, and 100% Japanese horse fat. Results showed that the Jeju horse fat improved in flow behavior by adding hydroxystearic acid similar to that of Japanese horse fat. In addition, when the crystal state was observed under a microscope, the thermal stability was improved by decreasing the size of the needle-type crystals with the addition of hydroxystearic acid. Jeju horse fat containing hydroxystearic acid was found to have no physical problems even when stored at room temperature for a long time.

실리콘 유무기 하이브리드 코팅을 이용한 CNT 투명전도필름의 내구성 증진에 관한 연구

  • Ha, In-Ho;Sin, Gwon-U;Han, Jong-Hun;Seo, Mun-Seok;Kim, Seon-Min;Jo, Jin-U;Lee, Cheol-Seung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.414-414
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    • 2012
  • 차세대 플렉시블 디스플레이 소재로서, 탄소나노뷰브(CNT) 기반의 투명전도막은 기존의 ITO 박막보다 우수한 유연성을 갖기 때문에 많은 관심을 모으고 있다. 특히 낮은 저항과 투과도를 유지하면서 투명 전도막의 내구성을 향상시키는 연구는 상업화에 가장 필요한 연구 분야이다. 본 연구에서는 다층벽 탄소나노튜브(MWCNT)를 이용하여 제작된 투명 전도막의 내구성을 개선하기 위하여 오버 코팅을 통한 물성 개선을 연구하였다. 투명전도막은 PET기판 위에 스프레이 방식을 이용하여 균일하게 코팅하였다. 오버 코팅 물질로는 실리콘계 유무기하이브리드 투명하드 코팅을 적용하였다. 연구결과 오버 코팅층과 CNT 코팅층과의 젖음성이 물성 향상에 가장 많은 영향을 끼치는 것을 관찰하였고, 특히 젖음성이 증가할수록 투과도와 전기전도도가 향상되는 것을 확인하였다. 또한 고온 고습 환경에서 240시간 이상 내구성 테스트 결과, 저항률 변화가 1.1 이하인 것을 확인하였다.

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A Study on Fire Resistance of Abaca/Vinyl-ester Composites (마닐라 삼/비닐에스터 복합재료의 내화성 연구)

  • Lee, Dong-Woo;Park, Byung-Jin;Song, Jung-Il
    • Composites Research
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    • v.30 no.1
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    • pp.59-64
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    • 2017
  • Eco-convivial composites with improved properties are essential to present polymer scenario and can be made easily by replacing partially/completely renewable materials either matrix or reinforcement along with few % of additives. In these investigations, Abaca fabric have been used as reinforcement for manufacturing of Vinyl ester composites through VARTM technique and study the effect of alkali surface treatment of abaca fabric and flame retardant additives i.e., ammonium polyphosphate (APP) with halloysite nano-clay (HNT) on mechanical and flame retardant properties. The results concluded that, surface treatment deceased the hydrophilic nature of fabric and enhanced the interfacial bonding with hydrophobic matrix and eventually increased mechanical properties slightly of developed composites. Similarly, the flame retardancy of the composites improved significantly and increases the burning time by varying the wt% of filler concentration.

Study on Improving Properties of Tile Cement Mortar by Mixing of Additives (Additives의 혼합에 의한 Tile Cement Mortar 물성향상 연구)

  • Lee, Moo-Jin;Shin, Young-Jo
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.486-490
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    • 1999
  • In this study, to improve the required properties of tile cement mortar such as excellent water retention capacity (WRC), workability, open time, sag resistance, and tile adhesive strength, tile cement mortars containing the several additives with different ratio were compared and analyzed. By adding small amount of synthesized starch to hydroxypropyl methylcellulose (HPMC) which is used for improving WRC, the decrease of moisture evacuation from mortar surface was observed and the workability of mortar was improved with long open time. Polyacrylamide (PAAm) and ethylencvinyl acetate (EVAc) were also added in order to increase the adhesion of tile. As a results, the saggings of mortar itself and tile were decreased and the adhesive strength of mortar between base and tile was enhanced. By adding melment, the workability was improved by increasing the fluidity of mortar. It is postulated that the properties of tile cement mortar was improved by adding 0.80~1.20% of HPMC, 0.10~0.15% of starch, 0.001~0.015% of PAAm, 0.05~0.10% of EVAc and 0.003~0.005% of melment to the cement mortar.

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Functionally Gradient Materials (FGMs) for Improved Thermo-mechanical Properties (열.기계적 특성 향상을 위한 경사기능 재료 (FGM))

  • 박성용;김진홍;김문철;박찬경
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.8-15
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    • 2004
  • The basic concept of functionally gradient materials (FGM) is to fabricate materials type having possibilities of applications in various fields by changing their intrinsic properties with continuous gradient. The present communication has reviewed the developments and applications of various FGMs designed for improved thermo-mechanical properties, in which the thermal protective and wear resistant materials are especially focused. Effects of thermo-mechanical properties and limits of FGMs designed for high temperature applications were mainly understood in terms of residual stress evolved from the design and fabrication. In addition, FGMs applied in structural parts were also introduced and discussed in terms of typical fabrication method for FGMs.

Properties of carbonated green construction materials by changes in processing conditions (공정조건 변화에 따른 탄산화 녹색건자재의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.3
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    • pp.152-160
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    • 2013
  • The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

A Study on the Fabrication and Mechanical Properties Evaluation of Natural Fiber Composites added Eco-friendly Materials (친환경 소재를 첨가한 천연섬유 복합재의 제조 및 기계적 물성 평가 연구)

  • Kim, Jae-Cheol;Lee, Dong-Woo;Prabhakar, M.N.;Song, Jung-Il
    • Composites Research
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    • v.33 no.4
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    • pp.213-219
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    • 2020
  • Recently, global facing environmental issues have been raised caused by plastic waste. Hence, increasing the demand for interest in environmentally friendly materials. In this row, research on engineering composite materials also replacing the synthetic reinforcement by introducing natural fibers. However, focus on the strength and interfacial adhesion between matrix and reinforcement is very essential in natural fiber composite, which is insufficient in the literature. There are number of approaches for improving the mechanical strength of the composites, one of the common methods is to reinforce additive nanoparticles. The present investigation, bio-additives were synthesized utilizing bio-waste, cheap, bio-degradable sea-weed powder that could replace expensive nanomaterials and reinforced into the CFRP composite through Hand lay-up followed by a vacuum process. Mechanical properties were evaluated and analyzed through microanalysis. The results concluded that synthesized additives are effective for improving mechanical properties such as tensile, flexural, impact, and shear strength. Overall, the results confirmed that the fabricated composites have potential applications in the field of engineering applications.

Preparation and characterization of isosorbide based PET/polycarbonate blends (Isosorbide가 함유된 바이오 기반 PET와 polycarbonate 블렌드의 제조 및 특성 연구)

  • Park, Ji-Soo;Nam, Byeong-Uk;Park, Jun-Seo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.1216-1221
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    • 2014
  • Poly(ethylene-co-isosorbide terephthalate) (PEIT) is interest in polymer which has isosorbide monomer that is renewable resources such as corn. However, there is important drawback which is low mechnical properties as increasing isosorbide contents. In this study, polycarbonate used to make up for drawback of mechanical properties of PEIT. In addition, PEIT used to improve the tensile elongation of polycarbonate because PEIT has good sheet proccessability. The effect of polycarbonate on morphology, thermal and mechanical properties were investigated using FE-SEM, DMA, TGA, UTM, and notched izod impact strength tester. As a result of this study, PEIT/PC blends were in compatible system and polycarbonate can act as an improvement of thermal stability and mechanical properties in the blends.

Preparation and Properties of EPDM/Zinc Methacrylate Hybrid Composites (에틸렌 프로필렌 디엔 고무/메타크릴산아연 하이브리드 복합체의 제조와 물성에 관한 연구)

  • Chang, Young-Wook;Won, Jong-Hoon;Joo, Hyun-Seok
    • Elastomers and Composites
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    • v.40 no.1
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    • pp.59-65
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    • 2005
  • Zinc methacrylate(ZMA) was incorporated into ethylene-propylene diene rubber(EPDM) by direct mixing of the metal salt with the rubber or was in-situ prepared in the rubber matrix through neutralization reaction of zinc oxide(ZnO) and methacrylic acid(MAA). Tensile and tear tests showed that ZMA had a great reinforcing effect for the EPDM. It was also found that ZMA reinforced EPDM vulcanizates can retain their mechanical properties under thermo-oxidative aging. Moreover the incorporation of ZMA induces a substantial improvement in the adhesive strength of the EPDM onto aluminum substrate. The reinforcing effect and an enhancement in adhesion was greatly manifested when the ZMA is in-situ formed with an excess amount of ZnO. The extraordinary improvement in the properties is supposed to be related with the formation of ionic crosslink as well as the degree of dispersion or ZMA domain in the rubber matrix.