• Title/Summary/Keyword: 물성변화

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Coupled T-H-M Processes Calculations in KENTEX Facility Used for Validation Test of a HLW Disposal System (고준위 방사성 폐기물 처분 시스템 실증 실험용 KENTEX 장치에서의 열-수리-역학 연동현상 해석)

  • Park Jeong-Hwa;Lee Jae-Owan;Kwon Sang-Ki;Cho Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.117-131
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    • 2006
  • A coupled T-H-M(Thermo-Hydro-Mechanical) analysis was carried out for KENTEX (KAERI Engineering-scale T-H-M Experiment for Engineered Barrier System), which is a facility for validating the coupled T-H-M behavior in the engineered barrier system of the Korean reference HLW(high-level waste) disposal system. The changes of temperature, water saturation, and stress were estimated based on the coupled T-H-M analysis, and the influence of the types of mechanical constitutive material laws was investigated by using elastic model, poroelastic model, and poroelastic-plastic model. The analysis was done using ABAQUS, which is a commercial finite element code for general purposes. From the analysis, it was observed that the temperature in the bentonite increased sharply for a couple of days after heating the heater and then slowly increased to a constant value. The temperatures at all locations were nearly at a steady state after about 37.5 days. In the steady state, the temperature was maintained at $90^{\circ}C$ at the interface between the heater and the bentonite and at about $70^{\circ}C$ at the interface between the bentonite and the confining cylinder. The variation of the water saturation with time in bentonite was almost same independent of the material laws used in the coupled T-H-M processes. By comparing the saturation change of T-H-M and that of H-M(Hydro-Mechanical) processes using elastic and poroelastic material mod31 respectively, it was found that the degree of saturation near the heater from T-H-M calculation was higher than that from the coupled H-M calculation mainly because of the thermal flux, which seemed to speed up the saturation. The stresses in three cases with different material laws were increased with time. By comparing the stress change in H-M calculation using poroelasetic and poroelasetic-plastic model, it was possible to conclude that the influence of saturation on the stress change is higher than the influence of temperature. It is, therefore, recommended to use a material law, which can model the elastic-plastic behavior of buffer, since the coupled T-H-M processes in buffer is affected by the variation of void ratio, thermal expansion, as well as swelling pressure.

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Morphology and Mechanical Properties of Recycled PVC Blends (III) - Morphologies and Mechanical Properties of Recycled PVC/PE Blends with Different Kinds of Compatibilizers and Mixing Conditions (폐폴리(염화 비닐)계 고분자 블렌드의 구조 및 물성 연구(III) -상용화제의 종류 및 혼합 조건에 따른 폐폴리(염화 비닐)/폴리에틸렌 고분자 블렌드의 형태학 및 물성)

  • 유영재;박재찬;원종찬;최길영;이재흥
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.468-477
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    • 2004
  • The polymer blends of waste poly(vinyl chloride) (RPVC) and waste polyethylene (RPE) were prepared by melt mixing. Various ethylene-vinyl acetate copolymers (EVA) and ethylene-methacrylic acid Na salt copolymer (ionomer) were used as compatibilizer. Their morphologies and mechanical properties were evaluated as a funtion of mixing sequence and time. EVA with high vinyl acetate contents showed a rapid increment of tensile properties when small amount was added. Tensile properties of the blends were gradually increased with the addition of ionomer. Morphologies of RPVC/RPE blends were analyzed by scanning electron microscopy. FT-IR data showed that EVA was a good compatibilizer in RPVC/RPE blend compared to ionomer. Mechanical properties of the blends were highly enhanced when RPVC and compatibilizer were mixed and first RPE was added later.

Change of Physical Properties of Binder Extracted from after Artificial Aging of Asphalt Concretes (아스팔트 콘크리트의 노화 후 추출한 바인더의 물리적 특성 변화)

  • Kim, Kwang-Woo;Doh, Young-Soo;Kim, Sung-Woon
    • International Journal of Highway Engineering
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    • v.4 no.4 s.14
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    • pp.53-66
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    • 2002
  • Asphalt binder characteristics in asphalt mixture are changed due to aging. However. depending upon aggregate and binder used, asphalt mixture dose not show the same level of stiffness and brittleness under the same ageing level. The factors affecting Physical Properties change of the asphalt binder within aged asphalt concrete are not well known and there is limited study which is dealing with this topic This study dealt with evaluation of physical properties of asphalt binder recovered from the mixtures after short-term and long-term aging. Two asphalts. two aggregates. two gradations and four polymers were used to make 32 mixture combinations. The mixtures were prepared and aged artificially in a forced draft oven. The measured physical properties included absolute viscosity, kinematic viscosity and penetration. Statistical analyses were carried out to find out the factor(s) having a significant effect on change of physical property of asphalt binder due to asphalt mixture aging. The results of study shown that aggregate, gradation and polymer had a significant effect on change of physical properties of asphalt binder.

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유도결합플라즈마를 이용한 실리콘 나노입자 박막 물성변화 연구

  • O, Gyeong-Seok;Kim, Ga-Hyeon;Kim, Dong-Seok;Lee, Heon;Lee, Jeong-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.423.2-423.2
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    • 2014
  • 비정질 실리콘 박막 태양전지는 1970년대 중반 개발된 이후 현재까지 지속적으로 연구 개발이 이루어져 왔으며, 대면적의 용이성 및 재료 사용의 효율성 등 산업적 측면에서 많은 장점을 보이고 있다. 하지만, 재료 특유의 무질서(disorder)로 인한 Voc의 한계 및 광 열화 현상 등의 문제점이 극복해야 할 과제로 남아있다. 이를 개선하기 위한 시도 중 하나로 나노입자를 포함한 실리콘 박막 제작을 통해 재료의 무질서도를 낮추고 전기광학적 물성을 개선하는 방법이 제안되고 있다. 본 연구에서는 유도결합 플라즈마(ICP, Inductively coupled plasma)를 사용하여 제작한 실리콘 나노입자 박막으로 비정질 실리콘 박막의 한계를 극복하고자 한다. 실리콘 나노입자를 사용하여 조밀한 박막을 제작하는데 중요한 변수로는 유도결합 플라즈마 반응기 상, 하부의 압력차 및 이로 인한 제트분사의 속력, 그리고 나노 입자의 크기 등이 중요하게 작용한다. 합성된 입자의 크기와 물성의 변화는 유입되는 반응 가스의 양, 공정압력과 파워에 의존한다. 실리콘 나노입자 박막을 다양한 플라즈마 조건에 따라 제작한 후 XRD, Raman, SEM, TEM을 이용하여 물성 변화를 관찰하였으며, 이를 통해 박막태양전지로의 응용 가능성을 제시하고자 한다.

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The Study on Properties of NEPE System Propellant to Size of RDX (RDX 입도에 따른 NEPE계 추진제 특성 연구)

  • Jang, Myungwook;Kim, Taekyu;Han, Haeji;Yun, Jaeho;Son, Hyunil
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.972-977
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    • 2017
  • The propellant tile and crack which account for the greatest proportion of solid rockets are profoundly affected by viscosity and mechanical properties of solid propellant. In this paper solid propellant with nitrate ester polyester(NEPE) system has been researched for the viscosity, mechanical properties and burning properties with size and mixing ratio of RDX. the viscosity of propellant was changed significantly depending on the size of RDX and mixing ratio, and mechanical properties of NEPE system propellant were also varied. Considering both lower viscosity and stable mechanical properties, the optimum size and mixing ratio of RDX can be identified as the main factors to the NEPE system propellant.

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The Research about Strength Properties of Recycled High Impact Polystyrene (재활용 고강도 폴리스틸렌(HIPS)의 강도 특성에 관한 연구)

  • Kim, Jong-Soon;Kang, Tae-Ho;Lee, Yong-Yeon;Kim, Young-Soo;Kim, In-Kwan
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.05a
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    • pp.113-118
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    • 2005
  • Recycle methodology was researched on the HIPS(High Impact Poly Styrene) materials which are used in modern industry widely, For the various mixing ratio between virgin pellets of HIPS and recycled ones, tensile strength and shrinkage ratio were analyzed with injection molding experiments and numerical simulations. In addition, the deviations of dimensional accuracy were observed in accordance with various molding conditions. Molding conditions such as mold and melt temperature were changed by 3 steps. Mixing ratio between virgin pellets of HIPS and recycled ones were under controlled with 15%, 30% and 45%.

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Evaluation of Mechanical and Interfacial Properties between Glass Fiber and Epoxy Resin after NaCl Solution and Aging Treatments (염수 노화처리 일수에 따른 유리섬유 에폭시간의 기계적 및 계면 물성 변화 평가)

  • Shin, Pyeong-Su;Wang, Zuo-Jia;Kwon, Dong-Jun;Choi, Jin-Yeong;Lee, Sang-Il;Park, Joung-Man
    • Composites Research
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    • v.28 no.1
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    • pp.22-27
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    • 2015
  • Although it is important to have high strength of each of fiber and matrix, interface between fiber and matrix is most important. If NaCl water penetrates the interface, that area will be weak. So experiment about increasing interfacial strength is in process. In this study, the change of properties by mechanical, interfacial and micromechanical tests was observed after NaCl and aging treatment. The changes in mechanical properties of glass fiber were investigated using single-fiber tensile test. Interfacial properties between glass fiber and epoxy resin were evaluated using nondestructive acoustic emission (AE) and micromechanical test applied to fatigue test. Through change of fatigue properties, relative interfacial properties were evaluate. In conclusion, glass fiber diameter decreased and the reduction of mechanical and interfacial was observed with NaCl solution and aging treatment.