• Korean Journal of Heritage: History & Science
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• v.55 no.2
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• pp.186-197
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• 2022

The Daejanggakgibi Stele of Silleuksa Temple in Yeoju is a stone stele from the Goryeo Dynasty that is inscribed with various stories about the construction of Daejanggak, a place where Buddhist scriptures were kept. This stele has been maintained for a long time in a state in which discoloration of the body has occurred, and the inscription has been partially damaged due to dozens of cracks. Using non-destructive analysis methods for stone artifacts, material investigation, portable X-ray fluorescence analysis, and ultrasonic velocity analysis for the stele were performed. It was confirmed that the stele body was composed of light gray crystalline limestone, and the base stone, support stone, and cover stone were medium-grained biotite granite. Portable X-ray fluorescence analysis confirmed that iron(Fe) was an original coloring element of the stele surface. From the distribution pattern of the coloration, it can be inferred that iron-containing materials flew down from between the stele body and the cover stone. Thereafter, living organisms or organic contaminants attached to it so that yellow and black contaminants were formed. Ultrasonic diagnosis revealed that the physical property of both the front and back surfaces ranged from fresh rocks(FR) to completely weathered rocks(CW), and the average weathering index was grade 3(intermediate). However, the point where cracks developed intensively was judged to be the completely weathered stage(CW), and some cracks located in the upper and lower parts of the stele bear potentially very high risk. It is necessary to monitor the movement of these cracks and establish reinforcement measures for conservation in the future.

• Journal of Conservation Science
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• v.6 no.1 s.7
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• pp.31-60
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• 1997

Stone-cultural-properties, distributed in Naju, Hwasun and a part of Jangheung, have been investigated and studied on the characteristics, rock weathering and phases in the geological and conservational points of view. The properities involve pagoda and twelve stupas, four stone-buddha, three stone monuments, two stone-lantern, four stone-Jangseung, one and flag-pole. The rocks used are mainly pebble-bearing tuffaceous rocks of the Cretaceous age which are widely distributed in the area. However, granites are also used in some properties. These rocks are strongly influenced by weathering and pervasive moss. The mottled rock surfaces in some properties are in colors due to pervasive moss different. Parts of some cultural properties are broken which results in structurally unstable. Cultural properties in the area are relatively well conserved at the earth consolidated by ramming and by iron fence. However some cultural properties are partly repaired by using other hinds of rock phases which results in different colors in weathered rock surface. For conservation, rock phases, weathered surface colors, and relationships with original parts must be scientifically considered in repairment forward.

• Journal of Conservation Science
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• v.25 no.3
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• pp.283-291
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• 2009

Methyl Bromide that was used as fumigation gas turned out to be the substance of destroying the ozone layer. For that reason, at the Montreal Protocol in 1987 the use of methyl bromide was forbidden starting 2005 in the advanced country. Also according to the 2007 Bali Protocolly methyl bromide is expected to be forbidden and therefore the purpose of this study is to find out the effects of substitution fumigation gas (Ethylene Oxide+HFC 134a, Methyl Iodide, Cyanogen and Argon) on the metal(silver, copper and iron), wood(oregon pine), pigment(yellow, red, blue, white and black), textile(hemp, ramie, jute, silk1 and silk2 / indigo, safflower and cork) and paper. After the fumigation test, ethylene oxide+HFC 134a did not have changes in the weight and color of the material itself before and after the experiment. On exterior alteration, color change occurred partly on paper and metal. Also, in most materials color change extent was 0.5 to 1.5 on the average and showed scanty difference. The materials after the fumigation test with methyl iodide did not show weight changes after the test. However, color changes more than 1.0 was shown in most of the materials especially in dyed textile material. In blue pigment, the discoloration on the surface could be seen by naked eyes. Fumigation test with cyanogen gas did not show weight changes and discoloration is more than 1.5 before and after the test. The weight changes of test materials with the argon gas was decreased about 3 to 6%. It can be observed that discoloration on paper was generated. Color changes can be seen on jute dyed with safflower and cork for two weeks with argon gas and the extent was 6.3 and 6.0.

• Korean Journal of Heritage: History & Science
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• v.46 no.4
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• pp.90-107
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• 2013

The Stone Monument of Taejong King in Heonreung Royal Tomb, Seoul was originally erected in 1424 to pay a tribute to Bang Won Lee's achievement who was named Taejong, the Third King of Joseon Dynasty. The monument has been damaged by Japanese Invasion of Korea in 1592 so that another monument was newly made and erected together with the original monument in 1695. The original monument was made of medium-grained biotite granite for the turtle base and medium-grained milky white crystalline limestone for the stele body and the top stone. The turtle base of the original monument is destroyed beyond the original shape and inscription due to irregular shaped breaking and a set of longitudinal crack. Analyzing the deterioration degree by using nondestructive methods, the 88 percentage of the front area and 38 percentage of the back area of the monument are damaged, and the lower part of the stele body is dominantly deteriorated especially due to the combination of discoloration and physical deterioration. The new monument in 1695 is also made of granite and limestone. The weathering indices of the turtle base and stele body stones by the calculation from ultrasonic velocity are 0.10 and 0.74, respectively. This is because the original monument is presumed to be degraded by heat shock and physical attack during the Japanese war, and the long-term outdoor exposure accelerated the weathering of the monument afterward without protective shelter.

• Journal of Conservation Science
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• v.34 no.2
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• pp.69-76
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• 2018

Lead-based pigments (Lead White, Massicot, and Red Lead) are known to cause discoloration easily in indoor air environments. This study was conducted to investigate the effect of representative indoor air environment factors ($O_2$, $CO_2$) on lead-based pigments. As a result of the experiment, almost all of the specimens showed changes of more than ${\Delta}E=5.0$ in their values of chromaticity under $O_2$ (99%, RH 99%) and $CO_2$ (36,000 ppm, RH 99%) environments. Scanning electron microscopy also showed that the pigment particles lose sharpness of the edge. Furthermore, under the degradation, the intensities of the characteristic peaks in the X-ray diffraction patterns were decreased, and Lead White, Massicot, and Red Lead exposed to $CO_2$ (36,000 ppm, RH 99%) were shown to include the new material cerussite ($PbCO_3$). In particular, Plattnerite ($PbO_2$) was identified on Massicot, and for white lead, the characteristic peaks disappeared and those of Cerussite were identified. It was confirmed that chemical change with discoloration can occur when these lead-based pigments are exposed to a high-humidity $CO_2$ environment.

• Journal of Conservation Science
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• v.25 no.1
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• pp.25-38
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• 2009

The Gyeongju Seokbinggo (Treasure No. 66) is an ice-storing stone warehouse, consisting mainly of alkaligranite which shows milky white color and medium-grained textures with drusy cavities. As results of deterioration assessment, the deterioration rates were determined as crack (12.5%), disjoining (6.7%), breaking-out (25.1%), exfoliation (20.9%), efflorescence (6.5%), brown discoloration (9.8%), darkgray discoloration (2.0%) and biological discoloration (36.5%). Comprehensive physical deterioration rate and discoloration rate were calculated as 43.7% and 68.7%, respectively, that indicates the Seokbinggo has been severely weathered. Indoor relative humidity was above 90% except in winter season. Indoor microclimate was hardly fluctuating although indoor microclimate was dependent on the outdoor climate. The main cause of deterioration was high relative humidity and a long time of wetness due to penetration of rain, underground water and condensation. It was identified that the water brought out biological discoloration, dissolution of minerals, structural movement and efflorescence, and the dust from the ground soil in front of the entrance accelerated brown and dark gray discoloration on the stone surface.

• Journal of Conservation Science
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• v.38 no.2
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• pp.124-132
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• 2022

Through scientific analysis, this study identified the material characteristics of metal foil decorating the border line and knotting of the National Folklore Cultural Heritage 'Pouch for the Sutra Embroidered with a Sun and Moon Design'. Through Scanning Electron Microscope-Energy Dispersive Spectroscopy results, it was estimated that silver (Ag) and sulfur (S) were present in the metal foil, and silver leaf was also attached to the medium. S may discolor Ag from yellow to black depending on its concsentration and contact time. Yellow color could not be identified in metal foil at present. But there existed an example of the preparation of a gold-colored flat silver thread; therefore, further research is needed to estimate the original color. The lamella was reddish brown on the back. Aluminum, silicon, and iron were also detected and were the main components found in red soil. This is believed to be the red adhesive in traditional flat gold thread and is considered to be an adhesive-related component of the metal foil. From the gas chromatography mass spectrometry results, the adhesive component was confirmed to be animal glue.

• 보존과학연구
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• s.33
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• pp.57-67
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• 2012

The Uiseong Tapriri Five-Storied stone pagoda has occurred exfoliation, granular disintegration and discoloration by physical and chemical weathering factors with the major deterioration occurring due to efflorescence by salt. According to the results of SEM-EDS and X-ray diffraction analysis, salts consists of gypsum, taranakite. Artificial salt weathering tests were carried out using the same type of rocks as those in the stone pagoda. The test results showed that efflorescence occurred on the surface of the rock, and that exfoliation and granular disintegration occurred inside the rock due to salt crystallization.

• Korean Journal of Heritage: History & Science
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• v.43 no.3
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• pp.4-25
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• 2010

This study was carried out on scientific conservation treatment based on material characteristics, provenance interpretation, and deterioration diagnosis for seven-storied Jungwon Tappyeongri stone pagoda in Chungju. As a result, main rock of the pagoda is biotite granite with magnetite-series (average $5.86{\times}10^{-3}$ SI unit), containing partly basic xenolith, pegmatite veinlet and feldspar phenocryst. As a result of the provenance presumption of the host rock, a rock around the Songgang stream was identified the same origin. Therefore the rock is appropriate for materials of the pagoda restoration. The deterioration assessment suggested that the pagoda was seriously exfoliated (2.7 to 5.5%), discolored (39.8 to 58.9), and contaminated with repair materials (3.5 to 9.4%), and bioorganisms (19.3 to 24.4%). Accordingly, conservation treatment was carried out based on preliminary investigation for stable conservation of the pagoda. Overall processes were sequentially proceeded by restoration of the replacement stone, cleaning, joining and consolidation. This study sets up an integrated conservation system from preliminary investigation to conservation treatment of the pagoda. Also, the study will contribute for establishing the future-oriented customized conservation treatment.

• 한국문화재보존과학회:학술대회논문집
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• 2004.10a
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• pp.72-74
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• 2004

The color change of lead-containing pigments is one of the most serious diseases in watercolor, oil paintings and wall paintings. These pigments have a tendency to darken or brighten. It was proved that oxidation of lead containing pigments in the formation of brown-colored lead dioxide is a photochemical reaction under high humidity conditions. Therefore, we carried out some analogic experiments on the color change of three typical lead containing pigments ; $Pb_3O_4$, Pbo and $PbCo_3{\cdot}Pb(OH)_2$ at the conditions of illuminations under the high humidity ($2PbCo_3{\cdot}Pb(OH)_2$ R. H.). The reason for the chemical reactions are discussed and the results of these experiments are shown in some spectrograms, micrographs and X-ray micro-diffraction patterns. Important conclusions were drawn in our research. Due to the formation of brown $PbO_2$, red lead $(Pb_3O_4)$ and massicot (PbO) turned brown or dark when they were illuminated light under high humidity. We noticed that the brightening of red lead occurred d to admixture with chalk or lead white in egg yolk or linseed oil medium on exposure to light. Lead white used in oil paintings turned yellowish on dark.