• Title/Summary/Keyword: 무연탄

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Porosity and Electrical Resistivity of Formed Cokes Made from Anthracite and Phenolic resin (무연탄(無煙炭)과 페놀수지(樹脂)로부터 제조(製造)된 성형(成形)코크스의 기공율(氣孔率)과 전기저항율(電氣抵抗率))

  • Lee, Gye-Seung;Song, Young-Jun
    • Resources Recycling
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    • v.17 no.5
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    • pp.19-27
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    • 2008
  • In this study, the porosity and electrical resistivity of the formed coke produced by sintering the mixture of domestic anthracite and phenolic resin were mainly investigated, when the effect of the amount of binder, the hydration temperature and time, the hardening temperature and time, sintering temperature and time, the particle size of anthracite, the grade of anthracite, and the mixing ratio of phenolic resin on the physical properties of the coke were studied. As a result, It was found that the electrical resistivity and porosity of the formed coke are varied in the range of $0.3\sim1.2\Omega{\cdot}cm$ of $10\sim30%$, respectively, in accordance with the variation of factors.

A study on the removal of the water from the anthracite slurry by Oil Agglomeration Prosess(partI) (Oil Agglomeration Process에 의한 무연탄 슬러리의 탈수에 관한 연구(제1보))

  • 권이동;신강호;조동성
    • Resources Recycling
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    • v.2 no.2
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    • pp.39-44
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    • 1993
  • This study was carried out to remove the water from low grade anthracite slurry produced at Eoryong coal mine by the oil agglomeration process. 80% of Anthracite as a coal oil mixture (COM) was separated from water by the difference of specific gravity. Then, the amount of kerosene, diesel oil, and heavy oil forming COM was 10% of the amount of sample, respectively. The recovery rate of combustibles and ash content of agglomerated anthracite were affected largely by the amount of added oil, pulp density, particle size, mixing time, and impeller speed. The recovery rate of combustibles was increased to 95% and ash content was decrea-sed from 30% to 13.5% under the optimum conditions.

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The influence of factors on the strength of formed coke made with anthracite and phenolic resin (무연탄(無煙炭)과 페놀수지(樹脂)의 혼합(混合)소성에 의해 제조(製造)된 함형(咸形)코크스의 강도(强度))

  • Lee, Gye-Seung;Song, Young-Jun
    • Resources Recycling
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    • v.17 no.6
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    • pp.57-61
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    • 2008
  • The aim of this study is to produce the coke which can be used for the production of ferroalloy, by mixing phenolic resin and anthracite and sintering it. The influence of factors on the strength of coke were investigated. The results of this study are as follows: It is found that the anthracite coke of $100{\sim}150\;kgf/cm^2$ strength for ferroalloy can be made by a series of process as follows; Mixing homogeneously 6% liquefied phenolic resin and 6% water with $35{\sim}325$ mesh anthracite of low ash content. Making pellet by press the mixture in $10-50\;kgf/cm^2$ pressure. Dehydrating the pellet for 6 hrs at $50^{\circ}C$, and hardening it for 180 min at $200^{\circ}C$. Sinter the mixture for 6 hrs at $1,200^{\circ}C$.

A Study on Production of Air Pollutants and Combustion Efficiency of Anthracite-Bituminous Coal Blend Combustor Using Fluidized Bed (유동층을 이용한 유,무연탄 혼합 연소로에서 대기오염물질 생성과 연소효율 연구)

  • Cho, Sang-Won;Min, Byoung-Chul
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.517-523
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    • 1997
  • We have been studied that combustion efficiency and the production of air pollution of anthracite-bituminous coal blend in a fluidized bed coal combustor. Also, the reaching time of steady state condition have been studied. This experimental results are presented as follows. As the height of fluidized bed combustor becomes higher, the concentrations of $SO_2$ and NOx mainly increased. Also, as anthracite fraction increased, the emission of $SO_2$ concentration was increased but, the variation of $NO_X$ concentration was negligible according to anthracite fraction. When anthracite fraction ratio was increased, elutriation rate was increased and exit combustible content over feeding combustible content was increased. Regardless of anthracite fraction ratio the uncombustible weight percentage according to average diameter of elutriation particles were approximately high in the case of fine particles. Over bed temperature $850^{\circ}C$ and excess air 20%, the difference of combution at the velocity 0.3m/s, bed temperature $850^{\circ}C$, the excess air 20%.

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A Study of Chemical Properties and Fusibility of Korean Anthracite Coal Ash (국내 무연탄회의 화학조성 및 용융특성에 관한 연구)

  • Park, Cheol-Woo;Lee, See-Hoon;Shon, Eung-Kwon
    • Analytical Science and Technology
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    • v.5 no.4
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    • pp.433-441
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    • 1992
  • Chemical composition and fusibility of coal ash were measured for 23 Korean anthracite coals. The relationship between chemical properties and fusion temperature of coal ash was investigated. The slagging and fouling in firing the pulverized coal for boiler was assessed for the coal samples. It was found that most ashes contained more than 80% of $SiO_2$ and $Al_2O_3$ whereas less than 1% of $Na_2O$. And also fusion temperature of ashes occured relatively higher for Korean coals. Therefore it can be predictable that the slagging and fouling formation has a little problem in a pulverized coal firing system. A base/acid ratio did show a good correlation with fusion temperature for these coal ashes.

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Physical Properties of Activated Carbon with Coal Blend Ratios and Manufacturing Conditions (석탄배합비율과 제조공정조건에 따른 활성탄의 물성변화)

  • Kim, Sang Cheol;Park, Kyung Ai;Lee, Seung Bum;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.835-841
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    • 1998
  • This study was devoted to the manufacturing process of activated carbon(AC) using and anthracite and bituminous coals which were regarded as appropriate for AC manufacturing, and the physcial properties a AC prepared with coal blends were characterized by the ultimate and proximate analysis. Generally, as the fraction of antheracite in AC from anthracite and bituminous coal blends was increased, AC yield was increased whereas iodine value($I_2$) was decreased. Being not related to mixing ratio of coal blends, the apparent density of AC remained constant. Pore development and iodine value of AC based on coal blends(Fushun and Dandong, 75:25 wt. %) were examined, varing carbonization and steam activation conditions. These results showed that the average pore diameter of AC was below $20{\AA}$ in the activation temperature range of 850 to $900^{\circ}C$ and the iodine value was above $1000m^2/g$. When the adsorption capacity of manufactured AC was compared with commercial AC, it is found that the AC from coal blends was comparable to the commercial AC. Therefore, it was confirmed that the characteristics of manufactured AC were changed with manufacturing conditions and the ratios and types of coal blends.

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A Study of Co-Combustion Characteristics of North Korean Anthracite and Bituminous Coal in 2 MWe CFBC Power Plant (2 MWe 순환유동층 발전 플랜트에서 유연탄과 북한 무연탄 혼소시험 특성 연구)

  • Han, Keun-hee;Hyun, Ju-soo;Choi, Won-kil;Lee, Jong-seop
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.580-586
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    • 2009
  • In this study, co-combustion characteristics of Chinese bituminous coal and North Korean anthracite were investigated using a 2 MWe scale circulating fluidized bed power plant. At first, the combustion efficiency of bituminous coal of China and Australia as a function of excess air ratio and temperature were observed. The results showed that the combustion efficiency was influenced by particle size and volatile content of coal, the combustion efficiency of Chinese bituminous coal was over 99.5%. The unburned carbon particles from fly ash and bottom ash were a content 5~7% and 0.3%, respectively. The combustion efficiency with the mixture ratio 20% of bituminous coal and anthracite decreased over 5% because of the increase of entrained particles by a small average particle size of anthracite in the combustor. However, the outlet concentration of $SO_2$ and $NO_x$ was not changed remarkably. The concentrations of the typical air pollutants such as $NO_x$ and $SO_2$ were 200~250 ppm($O_2$ 6%), 100~320 ppm($O_2$ 6%) respectively. The outlet concentration of $NO_x$ was decreased to 30~65% with $NH_3$ supplying rate of 2~13 l/min in SCR process. The $SO_x$ removal efficiency was up to 70% by in-furnace desulfurization using limestone with Ca/S molar of approximately 6.5. With wet scrubbing using $Mg(OH)_2$ as absorbent, the $SO_x$ removal efficiency reached 100% under near pH 5.0 of scrubbing liquid.

Intrinsic Reactivity of NO and $N_2$O gas with Korean Anthracites (국내산 무연탄과 NO, $N_2$O 기체의 고유반응 특성)

  • 박영철
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.279-284
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    • 1999
  • Thermal analyses were conducted in a thermogravimetric analyzer by isothermal technique in order to characterize the Korean anthracites-nitrogen oxides reaction. The tested coal sample was Dogae anthracites and compared with SP-1 graphite. Carbon-NO and carbon-N$_2$O reactions were carried out with respect to isothermal reaction temperatures (550$^{\circ}C$-900$^{\circ}C$) and reactant gas partial pressures (5 kPa∼20 kPa). In NO reaction, measured reaction orders of NO concentration and activation energy were 0.45∼0.96 and 39∼l12 kJ/mol, respectively. In N$_2$O reaction, measured reaction orders of N$_2$O concentration and activation energy were 0.62∼0.87 and 190∼215.3 kJ/mol, respectively. Compared the Korean anthracites-nitrogen oxides reaction with the combustion reaction, the reaction rate in the oxidation below 700$^{\circ}C$ decreases in the order O$_2$>NO>N$_2$O. But above 700$^{\circ}C$, the reaction rate of N$_2$O is faster than that of NO.

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Derivation of Scarcity Index for Korean Coal Using Input Distance Function (투입물거리함수(投入物巨利函數)를 이용한 한국(韓國) 무연탄(無煙炭)의 희소성지표(稀少性指標) 산정(算定))

  • Lee, Myunghun
    • Environmental and Resource Economics Review
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    • v.13 no.1
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    • pp.33-47
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    • 2004
  • Even though the price of extracted but unprocessed coal has been available in Korea, the use of it as scarcity index would be inappropriate because of price subsidy. Following Halvorsen and Smith(1984), Kim and Lee(2002) derived estimates of the shadow price of unextracted coal by estimating the restricted cost function and differentiating with respect to the quantity of coal extracted. In Korea, however, due to the limited data the capital prices have been computed inconsistently case by case without relying on the robust formula like the Christensen-Jorgenson methodology used in US, which could result in biased estimators of the restricted cost function. In the paper the shadow prices of the resources in situ are obtained by measuring an input distance function defined by Shephard (1970), which requires only the data on the quantities of inputs and output. Empirical results for the Korean coal mining industry show that these shadow prices as a coal scarcity have increased fast by approximately three times in comparisons with those obtained by Kim and Lee.

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