• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.586-591
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• 1999

Mixed-firing of a bituminous and an anthracite coal carried out in a batch fluidized bed combustor(0.109 m-I.D., 0.9 m-height). Effect of particle size an mixing fraction of anthracite and bituminous coal combustion characteristics were studied. The temperature profiles and pressure fluctuation properties were measured to interpret the combustion characteristics in a batch fluidized bed combustor. The used domestic anthracite coal has heating value of 2010 kcal/kg and the imported high-calorific bituminous coal has heating value of 6520 kcal/kg. The combustion characteristics in a batch fluidized bed combustor could be interpreted by using pressure fluctuation properties and temperature increasing rates. It was found that the optimum anthracite mixing percentage could be predicted analyzing the combustion rate and fluidization characteristics, The optimum mixing fraction was about 30 %. The different burning region of fluidized bed combustor was measured by temperature increasing rates.

• Resources Recycling
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• v.13 no.2
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• pp.16-23
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• 2004

To increase the recycling rate of anthracite fly ash, the properties of anthracite fly ash were compared to that of bituminous fly ash. Especially, the high temperature properties of the fly ash are investigated by using thermal analysis, high temperature microscope and X-ray diffraction analysis for utilizing anthracite fly ash to prepare the calcinated bricks. The average ratio of $A1_2$$O_3$/$SiO_2$ for anthracite is 0.62 and the ratio for bituminous is 0.34. The content of $SiO_2$ in anthracite fly ash was higher than that of bituminous fly ash. The $A1_2$$O_3$ of anthracite fly ash reacted with the $A1_2$$O_3$ in the fly ash and formed new mullite crystal at over $1000^{\circ}C$, so anthracite fly ash showed high fire resistance. And, the fly ash mixtures having kaolin were prepared, and then extruded in vacuum to evaluate the extruding property of anthracite fly ash mixture. The extruding velocity was decrease with increasing the addition amount of fly ash in the mixture, and the maximum addition amount of fly ash that could be extruded was 60 wt%.

• Journal of Energy Engineering
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• v.5 no.2
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• pp.170-175
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• 1996

This study is to determined the activation energy from TGA experimental data for the bituminous and anthracite coals of three kinds which are being used in the domestic coal-fired power plants. TGA experimental data indicate that the weight loss temperature of bituminous coal is 200$^{\circ}C$ higher than that of anthracite coal. Activation energy of bituminous coal is in the range of 14∼20 Kcal/mole compared with 37∼55 Kcal/mole of anthracite coal. A reduction of particle size of coals results in the decrease of activation energy and activation energy has a good correlation with the weight loss percent of coal in the TGA experiment. Addition of CaCO$_3$ on anthracite coal caused to decrease the activation energy of 1∼23 Kcal/mole while activation energy of bituminous coal do not change significantly.

• Journal of Energy Engineering
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• v.17 no.3
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• pp.153-160
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• 2008

The combustion behaviors of the blends of Korean anthracite, bituminous coal and their blends were studied with a thermogravimetric analyzer. Concerning the burning profiles of the anthracite-bituminous coal blends in TGA, it has been observed the independent burning of two coals without any interaction between two coals. With the blends of 50% anthracite with 50% bituminous coal in weight basis, the combustion tests in a utility boiler have been carried out for the analysis of the combustion and operational characteristics by increasing the power output from 134 MW to 197 MW. The stable combustion has been observed in a boiler. With the increase of power output, the exhaust gas temperature was exceeded the design value of $430^{\circ}C$, so the combustion air was taken from atmosphere instead of the boiler penthouse.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.553-558
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• 2010

To solve the problems of the low combustion activity of Korean anthracite and the abundant loss of unburned carbon in fly ash, pellet coal was fabricated from coal fines and fly ash, and the mixed combustion of coarse coal with the pellet coal was examined in the circulating fluidized bed combustor of a 0.1 MW scale test unit. In the combustion of the raw coal only, the significant amount of coal fines was entrained, resulting in overheat at the top of the combustor. With the coarse coal that most fines were eliminated, however, the combustion temperature was maintained stable. The mixed combustion of coarse and raw coals was also feasible even though it often went unstable. The mixed combustion of the coarse coal with the pellet coal was as stable as the coarse coal combustion, showing a promise that the combustion of the Korean anthracite in commercial circulating fluidized bed boilers could be further enhanced.

• Plant Journal
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• v.11 no.3
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• pp.46-52
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• 2015

200MWe 순환유동층보일러인 A화력발전소는 정부정책에 의해 국내 무연탄만을 연료로 배정받아 운영되었다. 하지만 무연탄에 대한 민간수요 증가에 따른 정부의 정책변경에 따라 유 무연탄 혼탄을 2000년대 후반부터 시행하고 있다. 하지만 기동시 석탄 투입온도는 여전히 무연탄 전소시의 기준온도인 $600^{\circ}C$에 석탄을 투입하고 있는 실정이라 기동시간 지연의 한 원인으로 작용하고 있고 기동 중 소요되는 경유의 과다소비라는 고질적인 문제점을 안고 있다. 이에 본 연구에서는 A화력에서 사용되는 석탄에 대한 공업분석과 원소분석을 통하여 비교적 휘발분이 많고 반응성이 좋은 러시아산 유연탄(Suek) 연소에 따른 경유에서 석탄으로의 연료교체시 경제적인 시점을 예측하였다. 실험결과 러시아산 유연탄 (Suek) 연소시 투입가능온도는 연소전환율이 90%이상이 되는 연소최대온도($426^{\circ}C$)가 기술적, 경제적으로 가장 적합한 것으로 예상하였다.

• Journal of Climate Change Research
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• v.4 no.1
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• pp.27-39
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• 2013

In this study, the anthracite coal being used as fuel in Korea were classified into different types. These types include the domestically produced anthracite, imported anthracite used as raw material, and imported anthracite used as fuel. Each of the calorific values and greenhouse gas emission factors were calculated. The calculation of greenhouse gas emission factors resulted in the domestically produced anthracite as $111,477{\pm}4,508kg\;CO_2/TJ$, the imported anthracite used as raw material as $108,358{\pm}4,033kg\;CO_2/TJ$, and anthracite used as fuel was displayed as $103,927{\pm}8,367kg\;CO_2/TJ$. Additionally, the amount of greenhouse gas emission based on these calculated emission factors was displayed as $6,216,942ton\;CO_2$, which resulted as 12.7% lower than the green house gas emission amount which was calculated without distinguishing anthracite coal in details. Therefore, collecting activity data through a detailed classification of anthracites facilitate a more accurate calculation of greenhouse gas emission amount compared to collecting activity data through combination. Furthermore, since the anthracite coal used domestically possesses characteristics differing from the anthracite coal proposed by the IPCC, anthracite coal should be classified for each purpose and calculated for the improvement of the national greenhouse gas inventory.

• Clean Technology
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• v.23 no.4
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• pp.364-377
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• 2017

In this study, to improve the low surface area of domestic anthracite as raw materials of activated carbon, characteristics on chemical activation and VOCs adsorption of activated carbon according to mixing ratio of anthracite and lignite. For these, properties of raw materials, parameter characteristics of preparation processes for activated carbon, and VOCs adsorption characteristic of the prepared activated carbon are analyzed. The experimental results showed that, the domestic anthracite had disadvantages of high contents for ash and lead, arsenic, which were exceeded for the heavy metal limits, in the properties of raw materials. To improve these diadvantages, using the mixing ratio of anthracite and lignite, and the optimum conditions for pretreatment, activation, washing, and pellitization process, the activated carbon had a range of BET (Brunauer-Emmett-Teller) surface area of $1,154{\sim}1,420m^2g^{-1}$ with mesopore development and hydrophobic surface property. The carbons were satisfied with the quality standard for granular activated carbon, and had similar physicochemical properties with the commercial activated carbon. The minimum mixing condition for commercial VOCs activated carbon performance must have the caloric value of above $5,640kcal\;kg^{-1}$, and the carbon had higher adsorption capacity with order of xylene > toluene > benzene according to more higher molcular weight and hydrophobic property.

• Resources Recycling
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• v.17 no.4
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• pp.47-56
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• 2008

The aim of this study is to produce cokes which can be used for the production of ferroalloy, for this purpose, domestic anthracite mixed with plastic was sintered at various condition. The combustion and physical properties of anthracite and plastic, coal separation, and the influence of factors on the strength of coke were investigated. The results of this study are as follows: 1. The three kinds of anthracite from the Samcheok region contained 25 to 30% ash of $100{\mu}m$ over size, and have the caloric value of 5,205 cal/g(TaeAn), 4,893 cal/g(JangSung), 4,873cal/g(KyongDong). 2. The recommendable conditions for heavy-fluid separation of the Samcheok coal are to set the specific gravity of heavy fluid to 2.4 and control the size of coal to $35{\sim}140mesh$. 3. It is concluded that phenolic resin powder, liquefied phenolic resin, SAN, and melamine resin can be used as a binder for the anthracite cokes, from the thermal analysis of various plastics. Especially, the liquefied phenolic resin was considered as the most suitable binder as it would simplify the process.

• Plant Journal
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• v.14 no.3
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• pp.35-41
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• 2018

Considering the recent government policy toward North Korea and situation of power facilities in North Korea, it will be necessary to prepare for the consumption of the anthracite coal from Korea in coal-fired power plants. In this study, the anthracite co-fired tests in 500 MW thermal power plants were conducted with varying the main operation conditions, such as anthracite injection position in the boiler, coal fineness and combustion air flow, to investigate the effects on the generation of unburned carbon. It was confirmed that the generation of unburned carbon was remarkably reduced when the anthracite coal was injected into the boiler low burner with a relatively long residence time in the main combustion region, and that the increase of the coal fineness proportional to the combustion reaction surface area also reduces the generation of unburned carbon. An increase in the combustion air flow, which increase the combustion reactivity, also contributes to the reduction of unburned carbon. It is possible to maintain the unburned carbon generation below 5 % of the ash recycling quality by controlling the above operating conditions for the given mixing rate of anthracite, and the priority of changing the operating conditions within the test range is the highest for anthracite coal injection position.