• Title/Summary/Keyword: 무수전도

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A Study on the Propogation Velocity of Biological Action Potential (생체의 자극 전도속도에 관한 연구)

  • Che, Gyu-Shik;Kwon, Yong-Chan
    • Journal of Advanced Navigation Technology
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    • v.14 no.6
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    • pp.1002-1009
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    • 2010
  • I made the axon to the electrical transmission model and then constructed electrical equivalent model using Kirhhoff's current law and voltage law in this paper. I calculated various axon parameters in order to analyze the electrical potential hehavior versus minute distance chang of axon. The transmission velocity of unmyelinated nerve is proportional to square root of axon diameter, while that of myelinated nerve is directly proportional to its diameter. Because the transmission of myelin sheath is independent of voltage unlike unmyelinated sheath, the Hodgkin-Huxley model across the membrane is not so precise.

Preparation and characterization of proton exchange membranes in non-aqueous conduction (무수 전도성 양성자 교환막 제조 및 특성평가)

  • Park, Jin-Soo;Sekhon, S.S.;Baek, Ji-Suk;Yang, Tae-Hyun;Kim, Chang-Soo;Yim, Sung-Dae;Park, Gu-Gon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.282-285
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    • 2009
  • This study presents preparation and characterization of composite membranes based on ionic liquids. The ionic liquids act as water in sulfonated membranes. On the behalf of ionic conduction through ionic liquid inside the membranes, non-aqueous membranes showed Arrenhius dependence on temperature with no external humidification. It was implied that hopping mechanism of proton was dominant in the ionic liquid based membranes. In addition, small angle X-ray (SAXS) studies provided the information on morphology of ionic clusters formed by the interaction between sulfonic acid groups of the polymers and ionic liquids. The SAXS spectra showed matrix peaks, ionomer peaks and Prodo's law for Nafion based composite membranes and only matrix peaks for hydrocarbon based ones. However, ionic conductivity and atomic force microscopy (AFM) images showed the clear formation of ionic clusters of the hydrocarbon based composite membranes. It implies for ionic liquid based high temperature membranes that it is important to use sulfonated polymers as solid matrix of ionic liquid which can form clear ionic clusters in SAXS spectra.

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Filtered Vacuum Arc Source의 Plasma Duct-Bias 변화에 다른 막 물성 연구

  • Gang, Yong-Jin;Jang, Yeong-Jun;Kim, Jong-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.170.2-170.2
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    • 2016
  • DLC(Diamond like Carbon)는 Diamond와 유사한 물리화학적 특성을 보유한 막으로 고경도 및 우수한 내마모성, 화학적 안정성의 특성을 가지고 있다. DLC는 크게 카본의 막 형성 공정에서 카본 소스에 따라 수소가 포함된 DLC와 무수소DLC로 구분된다. Tetrahedral amorphous carbon (ta-C) 박막은 DLC 박막 중에서 가장 다이아몬드와 유사한 특성을 가지는 박막으로, a:C-H에 비해 높은 열적안정성, 경도(50~60 GPa) 및 내마모 특성이 우수하여, 현재 다양한 응용분야에 적용하고 있다. 본 연구에서는 무수소 DLC 형성을 위해 자장필터가 장착된 Filtered Vacuum Arc Source(FVAS)를 자체적으로 개발하여 연구를 진행하였다. FVAS 장비는 카본 이온 발생부와 Plasma Duct 부위, 전자석부위 구성되어 있으며, 본 연구에서는 Plasma Duct 부위의 Bias 제어를 통해 음극에서 기판으로 이동하는 카본이온의 에너지와 flux 변화를 통한 박막 증착 거동 및 물성 연구를 진행하였다. Plasma Duct Bias 변화는 각 0, 5, 10, 15, 20 V 조건으로 진행하였으며, 물성 평가는 경도(Hardness), 마찰계수, 응력(Stress), 전기전도 특성에 대한 분석을 진행하였다. 박막의 증착 거동에서는 Plasma Duct bias 변화에 따라10 V에서 가장 높은 증착 거동을 가지다 감소하는 경향을 확인 하였으며, 박막의 물성 특성 평가 시에도 이와 유사하게 특성의 차이를 관찰하였다. 이는 음극부위에서 형성된 카본이온이 기판에 도달 시에 Plasma Duct Bias 변화에 따라 이온의 Flux 및 에너지 변화로 인해 박막의 밀도 및 ta-C 막의 물성 변화로 예상되며, 이를 분석하기 위해 라만분석 및 기판 도달 에너지 분석을 진행하였다

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난연 및 전기전도성 폐PET/PE 복합 발포체의 제조 및 특성

  • 송종혁;강영구
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2001.11a
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    • pp.242-247
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    • 2001
  • Foam Plastics, cellular plastics, expanded plastics, plastic foam 등 여러 가지 이름으로 불리우고 있는 발포플라스틱은 plastic matrix 내에 무수한 cell이 open 형태 혹은 closed 형태로 존재하는 플라스틱 재료이며/sup 1)/ 원료플라스틱 보다 경량성, 열전도성, 충격흡수성 등 제반물성이 우수하여 포장재료, 보온재, 완충재 및 각종 구조재료로써 널리 사용되고 있으며 소재 plastic의 특성에 따라 PE, PP, PVC, PS, ABS 등 다양하게 개발되어 있다.(중략)

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Behaviors of Ionic Conductivity with Temperature for High-Temperature PEMFC Containing Room Temperature ionic Liquids Under Non-humidified Condition (상온 이온액을 이용한 고온 무수 PEMFC용 고정화 액막의 온도에 따른 이온전도도 거동)

  • Kim, Beom-Sik;Byun, Yong-Hoon;Park, You-In;Lee, Sang-Hak;Lee, Jung-Min;Koo, Kee-Kahb
    • Membrane Journal
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    • v.16 no.4
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    • pp.268-275
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    • 2006
  • Novel SILEMs were prepared by multi-stage phase separation process combined by the low temperature phase separation (LTPS) and the high temperature phase separation (HTPS) using room temperature ionic liquids (RTILs) which have a high ionic conductivity. PVDF and imidazolium series ionic liquids were used as membrane material and electrolyte, respectively. To study the ion conducting properties, the SILEMs were tested using LCR meter at temperature controlled from 30 to $130^{\circ}C$. Under humid conditions, with increasing temperature from 30 to $100^{\circ}C$, the ion conductivity of the cast $Nafion^{(R)}$ membrane increased linearly, but then started to decrease after $100^{\circ}C$. However, in the case of the SILEMs, with increasing operating temperature, the ion conductivity increased. Also, the ion conductivity behaviors of the SILEMs were almost same, regardless of humidity. The ion conductivity of the SILEMs was $2.7{\times}10^{-3}S/cm$ and increased almost linearly up to $2.2{\times}10^{-2}S/cm$ with increasing temperature to $130^{\circ}C$. The effects of an inorganic filler on the physical properties of the SILEMs were studied using the $SiO_2$. The addition of $SiO_2$ could improve the mechanical strength of the SILEMs, though the ionic conductivity was decreased slightly.

Flat Sheet Polybenzimidazole Membranes for Fuel Cell, Gas Separation and Organic Solvent Nanofiltration: A Review (평막형태의 폴리벤지다미졸 분리막의 연료전지, 기체분리막, 유기물분리용 나노여과막으로의 응용: 총설)

  • Anupam Das;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.6
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    • pp.279-304
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    • 2023
  • Polybenzimidazole (PBI) based membranes have evolved in literature as a popular membrane material for various applications in the past two decades because of their high temperature thermal durability, strong mechanical and tensile properties, high glass transition temperature (Tg), ion conduction ability at elevated temperature (up to 200℃), oxidative or chemical durability along with robust network like structural rigidity, which make PBI membranes suitable for various potential applications in chemically challenging environments. Ion conducting PBI based membranes have been extensively utilized in high temperature proton exchange membrane fuel cells (HT-PEMFC). In addition, PBI based membranes have been vastly utilized for the development of gas separation membranes and organic solvent nanofiltration (OSN) membranes for their unique characteristics. This review will cover the recent progress and application of various types of flat sheet PBI based membranes for HT-PEMFC, gas separation and OSN application.

Kinetic Study on Nucleophilic Substitution of 1-Anthracenesulfonyl Chloride with Anilines (1-염화안트라센 술포닐의 치환아닐린과의 친핵성치환반응의 속도론적 연구)

  • Kim Hyong Tae;Yoh Soo Dong
    • Journal of the Korean Chemical Society
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    • v.29 no.2
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    • pp.88-97
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    • 1985
  • 1-Anthracenesulfonyl chloride used as a substrate has been prepared from anthra-quinone, and its melting point ($124^{circ}C$) was confirmed to be considerably different from the literature value ($90^{circ}C$). Rates of nucleophilic substitution reactions of this substrate with some p-substituted anilines in dry acetone were determined by electroconductometric method, and their mechanism has been discussed. As a result, it has been found that these reactions proceed in parallel catalyzed by anilines together with noncatalyzed process, and that their catalytic activities are electrophilic. Judging from $Br{\phi}nsted\;{\beta}$ (0.77), Hammett ${\rho}$(-3.2), and activation parameters which were determined from the temperature dependence of noncatalyzed second order rate constants, it appears most appropriate that their mechanism should be discussed in terms of an associative $S_N2$ involving sulfonylammonium intermediate.

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Heat transfer on annular fins with one-dimensional radiative and convective heat exchange (원형휜에서 열전달 특성분석)

  • 이금배
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.6
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    • pp.1621-1628
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    • 1990
  • Numerical solutions are presented for the heat transfer from radiating and convecting fins. Consideration is given to thin, annular fins attached to a tube surface for which the temperature is constant. Fin to fin, fin to base, and fin to environment radiative interactions are considered. It is assumed that the radiating surface is diffuse-gray, the environment is black, and the surrounding fluid is transparent. The radiation terms are formulated by using Poljak's net-radiation methoad. The mathematical description of the simultaneously heat transport by conduction, convection, and radiation leads to a nonlinear integro-differential equation. This has been solved for a wide range of the pertinent physical parameters by using finite difference method and iteration method based on the Newton-Raphson technique. The temperature distributions, heat transfer rates, fin efficiencies, and fin effectivenesses are presented in dimensionless form. The results definitely indicate that the use of fins leads to a significant increase in heat transfer compared with the unfinned tube.

Study of the Electoral TV-Public Space: Paradox of the Mythical Structure Manipulated by the Technical Institutionalization (TV 선거 공론장 구조 연구: 기계적 제도화의 역설(Paradox))

  • Park, Tae-Soun
    • Korean journal of communication and information
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    • v.36
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    • pp.198-230
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    • 2006
  • The aim of the this study is to observer paradoxal phenomenon in media election. The media, especially Television, was traditionally a journalistic operation representing political events on the outside of political camp. But recently, it intervenes to 'the political camp' as the most important method for election campaign. A centripetal of electronic medias making the dominant political space offer an alternative plan which get over the modern crisis of representative democracy. Even though, to the production of the political symbol and the operation of symbol which constitute substantial system of political action, the human being subject is excluded and the technical system of communication make up a govern structure. So it makes the contradictory situation. TV broadcast for election campaigning show well this paradoxal situation. The institutionalization of electoral broadcasting oriented by the State strengthens an immensification, an economical and political efficiency and a transparency of electoral campaign. But the means which controls the mind of public is also strengthened. It relates the production and circulation of the political symbol and the symbolic image restricted by dominator. In conclusion, this study argues that the media election is institutionalized by the instrumental reason(procedural rationality of politics and technological rationality of broadcasting), therefore the candidate take a fragment roles for the production of transcendental political symbol and the voters accommodate to the symbolic images which are foreseen and they judge.

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Preparation of Ni-doped Gamma Alumina from Gibbsite and Its Characteristics (깁사이트로부터 니켈피착 감마알루미나의 제조 및 특성)

  • Lee, Hyun;Chung, In-Sung;Park, Hee-Chan
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1158-1164
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    • 1998
  • Aluminium sulfate solution was prepared by sulfuric acid treatment from gibbsite. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was precipitated from aluminium sulfate solution by adding it into ethylalcohol. From XRD analysis as-prepared $Al_2(SO_4)_3$ · $nH_2O$ was confirmed to have mixed-crystalization water(n=18, 16, 12, 6). The average water of crystalization calculated from thermogravimetry(TG) was 14.7. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was thermally decomposed and converted to $Al_2(SO_4)_3$ at $800^{\circ}C$, $\gamma-Al_2O_3$ at $900-1000^{\circ}C$, and $\alpha-Al_2O_3$ at $1200^{\circ}C$. Ni-doped $\gamma-Al_2O_3$, was synthesized from the slurry of as-prepared $\gamma-Al_2O_3$, with the ratio of [Ni]/[Al]=0.5. The reaction conditions of synthesis were determined as initial pH 9.0 and temperature $80^{\circ}C$ The basicity(pH) of slurry was controlled by using urea and $NH_4OH$ solution. Urea was also used for deposition-precipitation. For determining termination of reaction, the data acquisition was performed by oxidation reduction potential(ORP), conductivity and pH value in the process of reaction. Termination of the reaction was decided by observing the reaction steps and rapid decrease in conductivity. On the other hand, BET(Brunauer, Emmett and Teller) and thermal diffusity of Ni- doped $\gamma-Al_2O_3$, with various content of Ni were measured and compared. Thermal stability of Ni- doped $\gamma-Al_2O_3$ at $1250^{\circ}C$ was confirmed from BET and XRD analysis. The surface state of Ni-doped $\gamma-Al_2O_3$ was investigated by X-ray photoelectron spectroscopy(XPS). The binding energy at $Ni2P_{3/2}$ increased with increasing the formation of $NiAl_2O_4$ phase.

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