• Title/Summary/Keyword: 마스터 곡선

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Generation of calibration standard gases using capillary gas divider: uncertainty measurement and method validation (다중 모세관을 이용한 교정용 표준가스의 제조: 불확도와 유효성 평가)

  • Lee, Sangyun;Hwang, Eun-Jin;Jung, Hye-Ja;Lee, Kwang-Woo;Chun, Ki-Joon
    • Analytical Science and Technology
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    • v.19 no.5
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    • pp.369-375
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    • 2006
  • Calibration gas mixtures were prepared using dynamic volumetric method according to ISO 6145-5 and the uncertainty was evaluated. Ten identical capillaries with 0.25 mm in inner diameter and 50 cm in length were applied in this system. Dilution ratio of parent gas was determined by the number of capillaries that passes parent gas and that passes balance gas through. Capillaries were made of Teflon which had good chemical stability against adsorption of gaseous substances. Mechanical valves were introduced in this system in order to minimize the thermal effect of solenoid valves. Concentration of prepared gases were compared with master grade standard gases in cylinders made by RiGAS Co. and calibration of the instrument were completed using comparison method according to ISO 6143. Experimental results showed that the coefficient of variance of diluted oxygen standard gases showed less then 0.2% in most dilution range, that of diluted hydrogen sulfide standard gases showed less then 1.0%. Therefore, it is proven that the standard gases prepared by this system are appropriate to be used as a calibration standards in ambient monitoring, etc.

Predictive Equation of Dynamic Modulus for Hot Mix Asphalt with Granite Aggregates (화강암 골재를 이용한 아스팔트 혼합물의 동탄성 계수 예측방정식)

  • Lee, Kwan-Ho;Kim, Hyun-O;Jang, Min-Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3D
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    • pp.425-433
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    • 2006
  • The presented work provided a predictive equation for dynamic modulus of hot mix asphalt, which showed higher reliability and more simplicity. Lots of test result by UTM at laboratory has been used to develop the precise predictive equation. Evaluation of dynamic modulus for 13mm and 19mm surface course and 25mm of base course of hot mix asphalt with granite aggregate and two asphalt binders (AP-3 and AP-5) were carried out. Superpave Level 1 Mix Design with gyrator compactor was adopted to determine the optimum asphalt binder content (OAC) and the measured ranges of OAC were between 5.1% and 5.4% for surface HMA, and around 4.2% for base HMA. The dynamic modulus and phase angle were determined by testing on UTM, with 5 different testing temperature (-10, 5, 20, 40, & $55^{\circ}C$) and 5 different loading frequencies (0.05, 0.1, 1, 10, 25 Hz). Using the measured dynamic modulus and phase angle, the input parameters of Sigmoidal function equation to represent the master curve were determined and these will be adopted in FEM analysis for asphalt pavements. The effect of each parameter for equation has been compared. Due to the limitation of laboratory tests, the reliability of predictive equation for dynamic modulus is around 80%.

Dendrochronological Analysis of Abies koreana W. at Mt. Halla, Korea: Effects of Climate Change on the Growths (한라산 구상나무(Abies koreana W.)의 연륜연대학적 연구 - 기후변화에 따른 생장변동 분석 -)

  • Koo, Kyung-Ah;Park, Won-Kyu;Kong, Woo-Seok
    • The Korean Journal of Ecology
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    • v.24 no.5
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    • pp.281-288
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    • 2001
  • The relationships between the growths of Abies koreana W. and climatic factors were analyzed by the use of tree-ring analysis at the subalpine belt of Mt. Halla National Park. The four cores were extracted from each 21 trees at north-facing slope (1,900m a.s.1.). The site chronology was established on the periods from 1912 to 1999. The growth of A. koreana was very poor, in particular in the years of 1982, 1988 and 1996. Simple correlation was employed to analyze the relationship between the growth of A. koreana and climatic factors. The result of simple correlation indicates that the growth of A. koreana represent positive correlations both with the mean temperatures of April and previous November, and the precipitation of previous December and January. The presence of large number of frost-damaged scars in the individual trees of A. koreana implies that local freezing temperature conditions at Mt. Halla have occurred in 1964, 1965 and 1966. The correlations between the fir chronology SOI(Southern Oscillation Index) of previous January, February and November were significantly positive. The growth ratio of A. koreana demonstrates that this species is sensitive to seasonal variations. As the winter temperature rises, the growth ratio of A. koreana decreases, on the other hand, the increase of autumn temperature accelerates the growth ratio of A. koreana. The growth decline of A. koreana was observed from 51 cores out of the 54 cores, and the overall growth declines have initiated at 1978, 1982 and 1988. Distinct growth decline of A. koreana in the range of 70% is noticed at 34 cores out of the 51 cores. The decline of, A. koreana growth appears to be related to the winter temperature which has increased since mid-1970s.

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