• 열처리공학회지
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• 제13권3호
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• pp.177-182
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• 2000

The effects of betatizing and aging temperatures on the martensitic transformation characteristics in an Cu-13.4wt%Al-4.2wt%Ni single crystal have been studied. Microstructures show that the specimen betatized above $800^{\circ}C$ has only ${{\beta}_1}^{\prime}$ martensite while the specimen betatized of below $700^{\circ}C$ has two phases i.e., ${{\beta}_1}^{\prime}+{\gamma}_2$ When betatizing temperature increase from $600^{\circ}C$ upto $900^{\circ}C$, Ms and As temperatures decrease due to the dissolution of which ${\gamma}_2$ phase depletes Al content in the matrix thereafter makes the both Ms and As temperatures significantly increased. Ms and As temperatures of the specimen aged at $200^{\circ}C$ are relatively stable but those of the specimen aged at $300^{\circ}C$ are shifted rapidly with aging time, especially within the first 30min.

• 열처리공학회지
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• 제24권5호
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• pp.271-276
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• 2011

The effect of grain size on the deformation induced martensite transformation and mechanical properties in austenitic stainless steel with high amount of Mn was studied. a'-martensite was formed by deformation and deformation induced martensite was formed with surface relief. With increase of grain size, volume fraction of deformation induced martensite was increased. With the increase in degree of cold rolling, hardness, and tensile strength was rapidly increased with linear relationship, while, elongation was decreased rapidly and then decreased slowly. With increase of grain size, hardness and tensile strength was rapidly increased with linear relationship, while elongation was decreased rapidly. The hardness, tensile strengths, and elongation were more strongly influenced by deformation induced martensite than the grain size.

• 한국세라믹학회지
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• 제32권9호
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• pp.967-976
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• 1995

The possiblity of the existence of a spontaneous relaxor-normal ferroelectric transition was proposed and examined using 1~5 mol% PbZrO3-doped Pb(Ni1/3Nb2/3)O3-PbTiO3 (PNN-PT) systems having tetragonal symmetry at rom temperature. On cooling, the system with 60mol% Pb(Ni1/3Nb2/3)O3 underwent a spontaneous transition from a relaxor to a normal ferroelectric state. A microscopic examination demonstrates that the relaxornormal ferroelectric transition corresponds to a micro-macro domain switching accompanied with thermoelastic martensitic transformation. The long-range macrodomains below the transition temperature were characterized by twinlike 90$^{\circ}$macrodomains with tetragonal symmetry. The relaxor-normal ferroelectric transition was further correlated with the rhombohedral-tetragonal first-order structural transition.

• 한국해양공학회지
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• 제14권1호
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• pp.23-28
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• 2000

The fatigue crack growth behavior of the cold-rolled STS 304 steel developed for membrane material of LNG storage tank was examined experimentally at 293K, 153K and 111K. The fatigue crack growth rate(do/dN) tends to increase as the stress ratio (R) increases over the testing temperature when compared at the same stress intensity factor range($\Delta$K). The effect of R on do/dN is more explicit at low temperatures than at room temperature. The resistance of fatigue crack growth at low temperatures is higher compared with that at room temperature which is attributed to the extent of strain-induced martensitic transformation at the crack tip. The temperature dependence of fatigue crack growth resistance is gradually vanished with an increase in $\Delta$K which correlates with a decreasing fracture toughness with decreasing temperature. Fractographic examinations reveal that the differences of the fatigue crack growth characteristics between room and low temperature are mainly explained by the crack closure and the strengthening due to the martensitic transformation.

• 열처리공학회지
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• 제8권1호
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• pp.75-83
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• 1995

The purpose of this study is to investigate the effect of heat treatments on the martensite transformation and tensile deformation behavior in Ti-Ni-B alloys with various boron concentration. Three types of heat treatment are given to the specimens; i) solution treatment ii) aging iii) thermo-mechanical treatment. In solution treated specimens. R-phase transition which is related to abnormal increase of electrical resistance prior to martensitic transformation has been formed at a boron content of 0.2at % and the $M_s$ temperature has been decreased with the increasing of boron content. However. It has not been affected by aging, while that of thermo-mechanically treated specimens has been remarkably increased in the vicinity of recrystallization temperature. The thermo-mechanically treated specimen has showed a good thermal fatigue characteristics, shape memory effect and superelasticity in comparison with the solution treated specimen.

• 한국재료학회지
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• 제29권3호
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• pp.160-166
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• 2019

This study investigates the effect of thermo-mechanical treatment on the damping capacity of the Fe-20Mn-12Cr-3Ni-3Si alloy with deformation induced martensite transformation. Dislocation, ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ are formed, and the grain size is refined by deformation and thermo-mechanical treatment. With an increasing number cycles in the thermo-mechanical treatment, the volume fraction of ${\varepsilon}-martensite$ increases and then decreases, whereas dislocation and ${\alpha}^{\prime}-martensite$ increases, and the grain size is refined. In thermo-mechanical treated specimens with five cycles, more than 10 % of the volume fraction of ${\varepsilon}-martensite$ and less than 3 % of the volume fraction of ${\alpha}^{\prime}-martensite$ are attained. Damping capacity decreases by thermo-mechanical treatment and with an increasing number of cycles of thermo-mechanical treatment, and this result shows an opposite tendency for general metal with deformation induced martensite transformation. The damping capacity of the thermo-mechanical treated damping alloy with deformation induced martensite transformation greatly affect the formation of dislocation, grain refining and ${\alpha}^{\prime}-martensite$ and then ${\varepsilon}-martensite$ formation by thermo-mechanical treatment.

• 소성∙가공
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• 제32권4호
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• pp.191-198
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• 2023

We examined the martensitic transformation kinetics for metastable stainless steel during electrochemical polishing (EP) using different types of electrolytes. Martensite fraction measured with EBSD showed that the electrolyte with high relative permittivity exhibited comparably higher levels of martensitic transformation. The amount of charge build-up on the specimen surface during EP with different types of electrolytes was calculated using COMSOL multiphysics simulations to understand these phase transformation characteristics. The effect of charge build-up-induced stress was analyzed using previously published first-principles calculations. We discovered that the electrolyte with high relative permittivity accumulated a greater amount of charge build-up, resulting in a stronger driving force for stress-induced martensitic transformation.

• 열처리공학회지
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• 제37권3호
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• pp.103-113
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• 2024

Martensite volume fraction significantly affects the mechanical properties of alloy steels. Martensite start temperature (M_s), transformation temperature for martensite 50 vol.% (M₅₀), and transformation temperature for martensite 90 vol.% (M₉₀) are important transformation temperatures to control the martensite phase fraction. Several researchers proposed empirical equations and machine learning models to predict the Ms temperature. These numerical approaches can easily predict the Ms temperature without additional experiment and cost. However, to control martensite phase fraction more precisely, we need to reduce prediction error of the Ms model and propose prediction models for other martensite transformation temperatures (M₅₀, M₉₀). In the present study, machine learning model was applied to suggest the predictive model for the Ms, M50, M90 temperatures. To explain prediction mechanisms and suggest feature importance on martensite transformation temperature of machine learning models, the explainable artificial intelligence (XAI) is employed. Random forest regression (RFR) showed the best performance for predicting the Ms, M50, M90 temperatures using different machine learning models. The feature importance was proposed and the prediction mechanisms were discussed by XAI.

• 대한조선학회논문집
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• 제39권1호
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• pp.82-89
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• 2002

선상가열에 의한 판 변형 예측은 고유변형도법에 의해 효율적으로 예측할 수 있다. 종래의 용접에서의 고유변형도 결정 방법은 용접 실험을 통하여 온도분포와 강의 상변태 영역(Ac3)을 시편을 절단하여 계측하고 이를 고유변형도 영역으로 간주하는 것이었다. 선상가열의 현상은 용접과 유사하므로, 용접과 같은 조건 하에서 얻어진 결과를 그대로 선상가열 해석에 이용하여 왔으나 이 결과는 가열 패턴이나 판 두께에 제한을 가지고 있다. 또한 현장에서는 선상가열 후 수냉 처리하는데 그 과정에서 강이 원래의 상으로 돌아가지 않고 마르텐사이트가 되면서 전단 소성 변화를 일으킨다는 점에 착안하여, 본 연구에서는 종래에 시편의 온도계측과 상변태 영역을 직접 계측하는 파괴검사법을 FEM을 이용한 이론해석으로 대체하였다. 즉 임의의 적절한 열속 모델에 대한 온도 분포를 얻고, 조직변화에 따라 추가적으로 발생하는 소성 영역을 고려하기 위하여 공석 온도 영역까지 포함시켜 온도계측과 파괴실험 없이 순수한 이론만으로 고유변형도 영역을 결정하는 새로운 방법을 제안하였다. 이 방법으로 결정한 영역을 이용하여 판의 변형을 예측하고 실험 결과와 비교하여 잘 일치함으로써 본 논문에서 제안한 방법의 유효성을 입증하였다.

• 한국재료학회지
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• 제4권5호
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• pp.524-534
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• 1994

소량의 misch metal과 Zr을 함유한 CuZnAI형상기억 합금의 변태온도에 미치는 열사이클 및 기계적 성질 변화에 대하여 고찰하였다. 합금원소 첨가에 따라 결정립에 매우 미세화 되었으며 용체화 처리후 100~$350^{\circ}C$구간에서 경도값 변화를 조사하기 위하여 post quench aging과 step quench aging처리한 결과 $200^{\circ}C$와 $250^{\circ}C$에서 최고의 경도값을 나타냈다. $M_f$온도이하에서 인당시험한 결과 파단강도와 연실율은 결저립이 미세할수록 증가하는 경향을 보였다. 또한 파단강도는 as quenching처리한 경우보다 post quench aging처리한 경우에 보다더 증가하였다. $\beta$-상에서의 시효는 $M_s$온도를 강하시켰으며 마르텐사이트상에서의 시효는 $A_s$ 온도를 증가시켰다. post quench aging 에 따른 $A_s$의 변화는 $\beta$에서의 회복율에 기여하였으며 변태온도 ($A_s-M_s$)히스테리시스는 열사이클에 의하여 증가하는 경향을 보였다.