• Title/Summary/Keyword: 로즈 벤갈

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Sensitized Photoisomerization of Benzalpyrrolinones (벤잘피롤린온의 광증감적 이성질화 반응)

  • Park, Y-T.;D. A. Lightner
    • Journal of the Korean Chemical Society
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    • v.22 no.6
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    • pp.417-422
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    • 1978
  • Rather than undergo photooxygenation, the Z-configuration benzalpyrrolinones (Z-2, Z-4) photoisomerized to the E-configuration isomers under direct or sensitized irradiation. Rose bengal sensitized photochemical stereoisomerzation of benzalpyrrolinones (Z-2, Z-4 and E-2) with monochromatic light (at 557 nm, excitation of rose bengal only) showed that the triplet of benzalpyrrolinones was involved in the photoisomerization, since oxygen inhibited the photoisomerization.

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Preparation of Standard Phosphatidylcholine Hydroperoxide for Chemiluminescence-HPLC Assay (화학발광고속액체크로마토그래피법에 대한 표준물질인 포스파티딜콜린 하이드로퍼옥사이드의 조제)

  • Song, Jin Hyang;Choi, Hong Yeob;Park, Dong Ki
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.474-477
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    • 1998
  • A simple and rapid method for preparation of standard phosphatidylcholine hydroperoxide (PCOOH) in chemiluminescence-HPLC assay (CL-HPLC) was developed using the rose bengal dependent spectrofluorometric oxidation. The concentration of obtained PCOOH was determined by FOX (ferrous oxidation-xylenol orange) assay and then subjected to a CL-HPLC system.

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Quantum Yield of Photoinduced Electron Transfer Across Microemulsion Interfaces (마이크로 에멀젼 계면을 통과하는 광유발전자의 양자수득률)

  • Yong-Tae Park
    • Journal of the Korean Chemical Society
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    • v.27 no.3
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    • pp.213-217
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    • 1983
  • Devices that mimic the natural photosynthetic pathway are of considerable interest as fuel sources. Quantum yield of viologen radical formation in several water-in-oil microemulsion system were measured. The yield of hexadecylviologen radical formation in microemulsion system using EDTA as an electron donor, ruthenium bipyridinium complex as photosensitizer, and hexadecylviologen as an electron acceptor was 12%. When benzylnicotinamide was inserted in the interface of the microemulsion and azo compound was dissolved in oil face, the quantum yield of hydroazo compound was 0.16. Organic dye (Rose bengal) was used as photosensitizer for the photoinduced electron transfer reaction. In anionic microemulsion no electrontransfer was observed.

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A Study on the Optimum Composition of Rose Bengal Reagent using Phase Transfer Catalyst (상이동 촉매 기법(phase transfer catalyst)을 이용한 rose bengal 시약의 최적 조성에 관한 연구)

  • Oh, Soo-Jin;Cha, Won-Jin;Choi, Da-Woon;Hong, Sung-Wook
    • The Journal of the Korea Contents Association
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    • v.18 no.7
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    • pp.245-252
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    • 2018
  • The rose bengal reagent, based on the phase transfer catalysis technique, is a calcium-targeting reagent that forms an insoluble salt that does not dissolve in a neutral or basic solution. It is expected to be effective in developing a latent fingerprint in a wet sample. However, many previous studies did not observe the fluorescence of the developed fingerprints, nor were the proposed methods of producing the reagents the optimal develop conditions. The aim of this study was to investigate the optimum reagent composition of rose bengal by varying the concentration of rose bengal dye and phase transfer catalyst based on maximum emission fluorescence of rose bengal. As a result, it was confirmed that rose bengal and surfactant concentration were the most effective when 0.01M: 0.008M, respectively.