• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.31-35
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• 2003

High-Flowability Concrete has many advanced properties and been focused on their workability. Because of the difficulty in understanding of the quality of High-Flowablity Concrete just using slump properties, many studies have been carried out rheological properties influenced on concrete fluidity. In this paper, for the purpose of expecting some level of rheological properties, the change of rheological properties of High-Flowability Concrete with dosages and types of superplasticizer, and various addition amounts addictives were investigated.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.10a
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• pp.373-379
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• 2011

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.84.2-84
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• 2003

• Journal of the Korea Institute of Building Construction
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• v.16 no.6
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• pp.505-512
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• 2016

Even though high performance concrete was developed according to the trend of bigger and higher of reinforced concrete building, the rheological evaluations such as viscosity, yield stress are not enough to use as input data to accomplish the numerical analysis for the construction design. So there are many problems in the harden concrete such as poor compaction, rock pocket and crack, etc. in the field. In this study, consistency curves were measured by the viscometer as hydration reaction time passed. At the same time the slump flow test and Vicat setting test were carried out for comparing with the results of rheological properties. The fluidity of the W/B 30% decreased as the increase of replacement ratio of blast furnace slag. But in case of W/B 40%, the replacement ration did not significantly influenced to the slump flow value with the passage of hydration time. By the replacement of blast furnace slag to cement, initial setting was delayed and the time gap between initial and final setting became shorten. Through the regression analysis using Bingham model, there are a sudden changes of viscosity and yield stress around initial setting in case of low W/B 30%. The increase of workability by the change of free water in cement paste was offset by the coating effect of impermeable layer in case of W/B 40%.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.276-286
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• 2021

General high fluidity concrete is the area of high strength concrete with a high amount of cement to secure the required fluidity and workability. Since most of the concrete structures currently used have normal strength, there is a limit to the practical expansion and practicality of use. Thus it is necessary to develop normal strength-high fluidity concrete with low binders that can be used not only in general buildings but also in special buildings, and can greatly reduce construction time and save labor costs. This requires to develop and apply the polycarboxylate-based superplasticizer. In this study, PCE was prepared for each combination of starting materials(WR, HB, RT) and the rheological properties of cement paste were analyzed using ringflow cone and a rotary viscometer. As a result, when PCE with a combination of WR 80%, HB 6.5%, and RT 13.5% was applied, the yield stress can be minimized while securing the plastic viscosity at level of the normal strength. In addition, high fluidity due to the high dispersion effect was confirmed.

• Korean Journal of Food Science and Technology
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• v.39 no.5
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• pp.584-587
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• 2007

The effect of molar substitution (MS, 0.030-0.118) on the dynamic rheological properties of hydroxypropylated rice starch pastes (5%, w/w) was investigated by small-deformation oscillatory measurements during aging. The magnitudes of storage (G#) and loss (G") moduli measured at $4^{\circ}C$ before aging increased with an increase in MS in the range of 0.030-0.118, while those of tan ${\delta}$ (the ratio of G"/G#) decreased. The G# values of hydroxypropylated rice starches, as a function of aging time (10 hr) at $4^{\circ}C$, increased rapidly at the initial stage, and then reached a plateau region at shorter aging times. However, for the native starch, the plateau values were not observed for G# after a long aging time. Increasing the MS resulted in a decrease in plateau values. The rate constant (K) for structure development during aging was described by first-order kinetics. The K values of hydroxypropylated rice starches at 0.086 and 0.118 MS were much lower than the K value at 0.030 MS.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.1
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• pp.715-723
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• 2017

This study investigates the properties of a high-performance cementitious composite with partial substitution of stone dust for fine aggregate. The relationship between the properties and particle size distribution was analyzed using several analytical models. Experiments were carried out to examine the flowability, rheology, and strength of cement mortars with different stone-dust replacement ratios of 0-30 wt.%. The results showed improved flowability, lower rheological parameters (yield stress and plastic viscosity), and improved strength as the amount of stone dust increased. These results are closely related to the packing density of the solid particles in the mortar. The effect was therefore estimated by introducing an optimum particle size distribution (PSD) model for maximum packing density. The PSD with a higher amount of stone dust was closer to the optimum PSD, and the optimization was quantified using RMSE. The improvement in the PSD by the stone dust was proven to affect the flowability, strength, and plastic viscosity based on several relevant analytical models. The reduction in yield stress is related to the increase of the average particle diameter when using stone dust.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.480-484
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• 2012

Concrete, the mixture of cement, sand, gravel and water, is a suspension substance extensively used to construct building materials. When a concrete mortar is applied to the underwater construction, the rheology of concrete is of great importance to its flow performance, placement, anti-washout and consolidation. In this research, the anti-washout and rheological properties of concrete have been investigated with concrete admixtures prepared by adding anionic surfactants, cationic surfactants, and polymeric thickeners. The concrete mortar formulated by pseudo-polymeric systems with the electrostatic association of anionic and cationic surfactants, showed high viscosities and suitable anti-washout properties, but poor pumpabilities. The addition of poly methyl vinyl ether to the mixed surfactant system exhibits synergistic effects by improving the concrete mortar properties of the concrete mortar such as fluidity, visco-elastic property, self-leveling, and anti-washout.

• Polymer(Korea)
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• v.26 no.1
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• pp.88-97
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• 2002

The effect of aminosiloxane modifier on the chemorheological properties of ortho-cresol novolac epoxy/phenol novelac/triphnylphosphine resin system was investigated aat different isothermal curing temperatures. By adding the aminosiloxane to the resin system, not only conversion rate and conversion were increased but also glass transition temperature was promoted. Critical conversion and gelation time obtained at the crossover point between storage and loss moduli were reduced and thus the viscosity was increased by the aminosiloxane. $C_1$ and $C_2$ in the WLF equation calculated from the glass transition temperature as a function of conversion and measured viscosity were found to vary with the curing temperature. By applying the change of glass transition temperature with conversion, $C_1$ and $C_2$ to WLF equation, it was possible to predict accurately the viscosity change with isothermal curing reaction.

• Korean Journal of Food Science and Technology
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• v.34 no.5
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• pp.830-834
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• 2002

본 연구는 동적 전단진동(dynamic shear oscillation) 측정방법을 이용하여 농도가 젤라틴의 동적 레올로지 특성에 미치는 영향에 대하여 관찰하였다. $5^{\circ}C$에서의 젤라틴의 저장 탄성률(storage modulus, G#)과 손실 탄성률(loss modulus, G@)은 농도가 증가함에 따라 증가하는 경향을 보였다. 0.9%를 제외한 모든 농도(2.0-4.9%)에서 젤라틴의 G#은 G@보다 매우 높은 값을 나타냈으며, G#과 G@이 ${\omega}$ 의존성이 없는 true 겔과 같은 거동을 나타냈다. 젤라틴의 농도와 K#(G#에 대한 절편)와의 관계에서는 높은 결정계수$(R^2=0.99)$를 보여주면서 좋은 상관관계를 나타냈다. 여러 온도범위$(-5,\;0,\;5,\;10^{\circ}C)$에서 각 온도별로 측정된 K#값은 $-5^{\circ}C(59.5Pa)\;>\;0^{\circ}C(4.09Pa)\;>\;5^{\circ}C(1.41Pa)\;>\;10^{\circ}C(0.35Pa)$의 순으로 가장 낮은 온도에서 K#값이 가장 높은 것으로 나타났다. 또한 냉각과정에서 최종냉각온도인 $5^{\circ}C$에서 측정된 젤라틴의 최대 G#수치는 4.9%(2399Pa)>4.1%(1744Pa)>3.0%(1159Pa)>2.0%(519.3Pa)>0.9%(3.15Pa)의 순으로 높은 농도에서 높게 나타났다. Aging 10시간 동안 젤라틴 겔의 구조형성은 겉보기 first-order kinetics로부터 겉보기 구조형성 속도상수(K)를 결정함으로써 파악될 수 있다. 젤라틴의 농도가 증가함에 따라 K값은 증가하였으며, 농도와 K값과의 관계는 높은 결정계수$(R^2)$를 나타내면서 좋은 상관관계를 보여주었다(Fig. 7). 10시간 aging 후 G#은주파수$({\omega})$ 의존성이 없이 독립적인 것으로 나타났다. 따라서 이들 젤라틴 겔은 aging하는 동안에 탄성이 점점 강해지고 10시간 후에는 가교결합의 밀도가 증가하여 강한 탄성을 가진 고무질 망상구조(rubber network)를 형성했음을 알 수 있다.