• Title/Summary/Keyword: 레올로지 특성

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Effect of Dispersant Contents on the Dispersity of Conductive Carbon-black and Properties of Screen-printed Source-drain Electrodes for OTFTs (분산제 함량에 따른 전도성 카본블랙의 분산 특성 및 스크린 인쇄된 OTFTs용 소스-드레인 전극 물성)

  • Lee, Mi-Young;Bae, Kyung-Eun;Kim, Seong-Hyun;Lim, Sang-Chul;Nam, Su-Yong
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.397-406
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    • 2009
  • We have fabricated source-drain electrodes for OTFTs using a screen-printing technique with carbon-black pastes as conductive paste. And effects of dispersants contents (SOP 10-40%) on the dispersity of carbon-black pastes and characteristics of screen-printed source-drain electrodes for OTFTs using two types of dispersants (DB-2150, DB-9077) were investigated. As contents of both dispersants were increased the dispersity of carbon-black mill-bases was improved, whereas the carbon-black pastes exhibited different dispersion characteristics. For the case of DB-2150, the dispersity of the pastes was improved with increasing dispersant content and the storage modulus G' in their rheology characteristics were reduced. But, for the DB-9077, the storage modulus G' of pastes were increased with dispersant content due to the flocculated network structure formed by interactions among carbon-black powders and dispersants. But, since this flocculated network structure of the pastes using DB-9077 resulted in the conduction path of carbon-black structures, the conductivities of screen-printed electrodes and mobilities of the OTFTs with them were better than those using pastes with DB-2150.

Analysis of Rheological Properties of Cement Paste with Binder Type and Composition Ratio (결합재 타입 및 구성비 변화에 따른 시멘트 페이스트의 레올로지 특성 분석)

  • Jeon, Sung IL;Nam, Jeong Hee;Lee, Moon Sup;Nho, Jae Myun
    • International Journal of Highway Engineering
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    • v.19 no.5
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    • pp.77-88
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    • 2017
  • PURPOSES : It is necessary to clarify the rheological properties of cement paste as a basic research in the development of mechanistic concrete mix design. The rheological properties of cement paste with different binder types, mix propositions, and with/without high range water reducers have been analyzed. METHODS : In this study, ordinary Portland cement, fly-ash, blast furnace slag, silica fume, and limestone powder were used as binders. The range of water-binder ratio was 0.3-0.5, and a total of 30 different mixes have been tested. The slump flow test, V-funnel test, and Dynamic Shear Rheometer (DSR) test were performed to analyze the rheological properties of cement paste. RESULTS : As a result of the slump flow test, it was found that the composition ratio of the binder contents greatly affected the paste flow when the high range water reducers were added. The results of V-funnel test showed that when the water-binder ratio was decreased without high range water reducers, the binder composition ratio had a large effect on the passing time of the V-funnel tester, but with high range water reducers the impact of the binder composition ratio was decreased. The slump flow and V-funnel have a certain relationship with the rheological factors (yield stress and plastic viscosity), but the correlation was not significant. Finally, we proposed the M-value considering the density and specific surface area of the binder. The correlation between rheological factors and M-value were better demonstrated than experimental values, but there is still a limit to predict the rheological factor in general mix design. CONCLUSIONS :In this study, the rheological properties of cement paste were analyzed. The binder type, composition ratio of binder, and with/without high range water reducers have combined to provide the complex effects on the rheological properties of cement paste. The correlation between the proposed M-value and rheological factor was found to be better than experimental results, but needs to be improved in the future.

A Study on the Preparation of UPE Resins with Different Glycol Molar Ratios and Their Physical Properties : 3. Estimation of Viscoelastic and Critical Surface Tension of UPE Liquid Resins (글리콜 몰비가 다른 불포화 폴리에스테르 수지의 제조 및 물성에 관한 연구 : 3. UPE 액상 수지의 임계표면장력 및 점탄성 평가)

  • 이상효;안승국;이장우
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.589-598
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    • 2000
  • In this study, various unsaturated polyester (UPE) resins were prepared from the condensation polymerization of mixtures of saturated (isophthalic acid : IPA) and unsaturated (maleic anhydride : MA) dibasic acids with propylene glycol (PG), neopentyl glycol (NPG). The critical surface tension (Υ$_{c}$) for the surface characteristics of a solid were estimated by Zisman plot, and the structure-property relationship was investigated by measuring the rheology of resins. The values of Υ$_{c}$ for glass of solid were 30.5 mNㆍm$^{-1}$ for UPE resin liquids. As the content of NPG in a PG/NPG glycol mixture increased, both the contact angle and the surface tension of the UPE resin liquids were found to decrease. The dynamic viscoelasticities of UPE resins with different glycol molar ratios were also measured. Shear rate dependence of viscosity and angular frequency dependence of storage, and loss modulus tended to decrease with increasing NPG content.

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Performance Evaluation of Admixture for Durability Improvement of Shielding Materials Used Waste Glass as Fine Aggregate (폐유리를 잔골재로 사용한 차폐채움재의 내구성 개선을 위한 혼화재료의 성능평가)

  • Hwang, Byoung-Il;Kim, Hyo-Jung;Song, Yong-Soon;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.20-27
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    • 2019
  • Compared to the development and manufacturing technology of electronic goods, the development of waste glass recycling technology is relatively insufficient, leading to the acceleration of waste of resources and environmental pollution. Although waste glass recycling technology is being actively developed overseas, waste glass recycling technology is insufficient in Korea, leading to the illegal dumping or burial of waste glass. Waste glass has been confirmed to have pozzolan reaction potential when having hydration reaction with cement. Waste glass is also reported to be effective in reducing bleeding and inhibiting the development of hydration heat by improving the physical properties of concrete and the rheology properties of fresh concrete. Therefore, this paper analyzed the strength characteristics and the effect of alkalic-silica reaction on the expansion of shielding concrete that used waste glass as fine aggregate. Where, suitable admixture materials were used as a measure to suppress the expansion.

양성 고분자로 표면 사이징된 원지에 의한 도공층의 조기 구조화 및 도공지의 물성 개선

  • 이학래;전대구
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.62-62
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    • 2000
  • 도공지 제조 시 적절한 표면특성을 지닌 원지를 사용하는 것은 최종 도공지 품질향상은 물론 조업성 개선에도 필수적인 요소이다. 이러한 목적을 달성하기 위해 도공원지의 표면 사이징이 실시되고 있다. 도공원지의 표면 사이정 시 양성전분을 이용할 경우 서로 반대로 하전된 전분 과 섬유 사이에 발현되는 정전기적 인력에 의해서 표면 사이정 전분의 원지로의 전분 침투가 억제되어 도공원지의 불투명도, 광택도 인쇄적성 둥의 물성 향상을 꾀할 수 있다. 또 이러한 원지를 이용하여 도공을 할 경우 음전하를 띤 도공액 구성성분과 양전하를 띤 원지 표면의 정 전기적 작용에 의해 도공액의 부동화가 촉진될 수 있으므로 도공액의 표면 잔류성이 향상되 며, 도공층 공극 구조 개선에 따른 광학적인 성질의 개선도 기대할 수 있을 것으로 기대된다. 본 연구에서는 양성전분으로 표면 사이정 된 원지를 사용한 도공지와 기존의 산화전분을 이용하여 표면 사이정한 원지를 이용하여 제조된 도공지의 특성을 비교하였다. 또 양성전분에 의한 표면 사이징 효과를 보다 극대화하고 도공안료와 원지 표면과의 반응성을 증가시키기 위 해 양이온성 폴리머를 표면 사이정 시 첨가하여 표면 사이칭을 하는 방법을 평가하였다. 아울 러 양성전분과 도공안료와의 반응에 따라 도공층의 부동화가 촉진될 수 있다는 근거를 구명하 기 위해 레올로지적인 접근을 시도하였으며, 도공층의 공극 특성 관찰, 광산란 및 광홉수 계수 측정 등을 통해 양성전분으로 표면 사이정된 도공층의 구조적 특성을 분석하였다. 그 결과 산화전분에 비해 양성전분으로 표면 사이징한 원지의 경우 도공지의 불투명도가 높게 나타났다. 이는 양성전분으로 표면 사이정한 원지를 사용한 경우 도공층의 구조가 광 산란계수를 향상시킬 수 있도록 변화되었기 때문임을 확인하였다. 표면 사이징시 양이온성 폴리머를 첨가할 경우 불투명도 개선에 상당한 효과가 있었으며, 전분 대비 1% 이하의 첨 가량에서도 어느 정도의 개선이 가능하였다. 양성전분에 의한 도공액의 조기 부동화가 발현 된다는 것을 구명하기 위해서 도공액의 점탄성적 평가를 실시한 결과 산화전분에 비해 양성 전분 상에서 도공액의 storage modulus가 높고 critical strain point 역시 높은 값을 나타낸 다는 것을 확인하였다. 이는 양성전분과 도공액, 특히 클레이와의 정전기적 인력에 의한 반 응 결과로 생각된다. 양성전분을 이용한 도공원지의 표면 사이정 기술은 특히 평량이 낮은 도공지의 경우 수분 의 침투를 억제함으로써 도공공정에서의 지절을 감소시킬 뿐 아니라 불투명도 등 광학적 성질 을 개선시키고, 표면 커버리지를 향상시키는 효과를 나타낼 것으로 기대된다.

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Optimum Mix Proportions of In-fill Slurry for High Performance Steel Fiber Reinforced Cementitious Composite (초고성능 강섬유보강 시멘트 복합체의 충전슬러리 최적배합 도출)

  • Kim, Seung-Won;Park, Cheol-Woo;Kim, Seong-Wook;Cho, Hyun-Myung;Jeon, Sang-Pyo;Ju, Min-Kwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.196-201
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    • 2014
  • As political circumstances in oversea countries and Korea varies, the risk of vulnerability from unexpected extreme loading conditions, such as explosions or extreme impacts, also increased. In addition, construction companies in Korea recently have taken chances of overseas expansion to countries where their domestic situations are not in rest. Therefore, the resistance of construction materials for blast or impact loading become taking more consideration from engineering field. This study is a part of the research to develop a high performance fiber reinforced cementitious composite materials with high volume steel fibers and primary purpose of this study is to find an optimum mix proportions of in-fill slurry. In order to accomplish the tasks this study performed experimental investigations on the slurry for consistency, compressive strength, flowability, J-penetration, bleeding and rheology properties as well as mechanical properties, compressive and flexural strength, with respect to different mix proportions.

Quality Characteristics and Dough Rheological Properties of Pan Bread with Perilla Seed Powder (들깨분말을 첨가한 식빵의 레올로지 및 품질특성)

  • Ji, Joung-Lan;Jeong, Hyun-Chul
    • Culinary science and hospitality research
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    • v.19 no.3
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    • pp.142-155
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    • 2013
  • This study investigates perilla seed powder substituted for wheat flour in bread recipes with the amounts of 0%(control), 5%, 10%, 15%, and 20%. Perilla seed powder consists of 9.41% of moisture content, 9.14% of crude protein, 1.12% of crude fat, and 2.97% of crude ash. Sedimentation value and pelshenke value have decreased as the perilla content increased. The farinograph measurement result of the bread made with perilla seed powder showed that consistency, water absorption and tolerance index have increased as the perilla content increased. The amylograph measurement result of the bread made with perilla seed powder showed that T, P, H, F, P-H and F-H have decreased as the perilla content increased. Baking loss and specific loaf volume have decreased as the perilla content increased. The chromatic 'L' and 'b' values were reduced as more perilla was added to more pan bread, while the chromatic 'a' value increased. The texture measurement result showed that the hardness of bread have increased as the ingredient contents increased. Their cohesiveness, spinginess, and chewiness have decreased as the ingredient contents increased. Overall preference scores showed a high preference for the bread made with 15% perilla seed powder.

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Mix Design of High Performance Concrete Using Maximum Density Theory (최대 밀도 이론을 이용한 고성능콘크리트의 배합 설계)

  • Lee, Seung-Han;Jung, Yong-Wook
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.377-383
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    • 2007
  • In recent years the field application of high performance concrete has been increased to improve the quality and reliability of concrete structures. The mix design of the high performance concrete includes the 2 set-off mixture theory of mortar and coarse aggregate and that of paste and aggregate. The 2 set-off mixture theory of mortar and coarse aggregate has a problem of having to determine its value through repeated experiments in applying the rheological characteristics of mortar. The 2 set-off mixture theory of paste and aggregate has never been applied to high performance concrete since it doesn't take into account the relationship between optimum fine aggregate ratio and unit volume of powder nor does it consider the critical aggregate volume ratio. As the mixture theory of these high performance concretes, unlike that of general concrete, focuses on flowability and charge-ability, it does not consider intensity features in mix design also, the unit quantity of the materials used is determined by trial and error method in the same way as general concrete. This study is designed to reduce the frequency of trial and error by accurately calculating the optimum fine aggregate ratio, which makes it possible to minimize the aperture of aggregate in use by introducing the maximum density theory to the mix design of high performance concrete. Also, it is intended to propose a simple and reasonable mix design for high performance concrete meeting the requirements for both intensity and flowability. The mix design proposed in this study may reduce trial and error and conveniently produce high performance concrete which has self-chargeability by using more than the minimum unit volume of powder and optimum fine aggregate with minimum porosity.

Quality Characteristics and Dough Rheological Properties of Pan Bread with Waxy Barley Powder (찰보리 분말을 첨가한 식빵의 레올로지 및 품질특성)

  • Jeong, Hyun-Chul;Ji, Joung-Lan
    • Culinary science and hospitality research
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    • v.19 no.4
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    • pp.119-135
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    • 2013
  • This study investigates waxy barley powder substituted for wheat flour in bread recipes with the amounts of 0%(control), 5%, 10%, 15% and 20%. Waxy barley powder consisted of 8.33% of moisture content, 10.47% of crude protein, 1.63% of crude fat, and 2.97% of crude ash. Sedimentation value and pelshenke value have decreased as the waxy barley powder content increased. The farinograph measurement result of the bread made with waxy barley powder showed that consistency, water absorption, development time, stability and time breakdown have increased as the waxy barley powder content increased. The amylograph measurement result of the bread made with waxy barley powder showed that T have increased as the waxy barley powder content increased. Their P, H and P-H have decreased as the ingredient contents increased. Baking loss and specific loaf volume have decreased as the waxy barley powder content increased. The chromaticity measurement result of the bread made with waxy barley powder showed no significant difference as the waxy barley powder content increased. The texture measurement result showed that the hardness and gumminess of bread have increased as the waxy barley powder content increased. Their cohesiveness, springiness and chewiness have decreased as the ingredient contents increased. Overall preference scores showed a high acceptability for the bread made with 10% waxy barley powder.

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Rheological Properties of Antiphlamine-S® Lotion (안티푸라민-에스® 로션의 레올로지 특성 연구)

  • Kuk, Hoa-Youn;Song, Ki-Won
    • Journal of Pharmaceutical Investigation
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    • v.39 no.3
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    • pp.185-199
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    • 2009
  • Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.