• Title/Summary/Keyword: 라텍스

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Durability of Polymer-Modified Mortars Using Acrylic Latexes with Methyl Methacrylate (MMA계 아크릴 라텍스를 혼입한 폴리머시멘트 모르타르의 내구성)

  • Hyung Won-Gil;Kim Wan-Ki;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.411-418
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    • 2005
  • Polymer-modified mortar and concrete are prepared by mixing either a polymer or monomer in a dispersed, or liquid form with fresh cement mortar and concrete mixtures, and subsequently curing, and if necessary, the monomer contained in the mortar or concrete is polymerized in situ. Although polymers and monomers in any form such as latexes, water-soluble polymers, liquid resins, and monomers are used in cement composites such as mortar and concrete, it is very important that both cement hydration and polymer phase formation proceed well the yield a monolithic matrix phase with a network structure in which the hydrated cement phase and polymer phase interpenetrate. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete. The purpose of this study is to obtain the necessary basic data to develope appropriate latexes as cement modifiers, and to clarify the effects of the monomer ratios and amount of emulsifier on the properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate(MMA/BA) and methyl methacrylate-ethyl acrylate(MMA/EA) latexes. The results of this study are as follows, the water absorption, chloride ion penetration depth and carbonation depth of MMA/BA-modified mortar are lowest. However, they are greatly affected by the polymer-cement ratio rather than the bound MMA content and type of polymer.

The Effects of Silica Sol and Modified Latex on the Concrete Surface Protection Cement Mortar for Improvement of Durability of Concrete (콘크리트 내구성 향상을 위한 표면 보호용 시멘트 모르타르에서 실리카 및 개질 라텍스의 영향)

  • Kim, Yong-Hoon;Jeaong, Cheol-Soo;Song, Myong-Shin;Lee, Woong-Geol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.715-722
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    • 2019
  • The durability of concrete structures deteriorates due to the corrosion of rebars and concrete deterioration by harmful ions (CO32-, Cl-, SO42-) penetrating and diffusing from the outside into concrete. Therefore, the use of surface-protection finishing mortar is very important for preventing or delaying the deterioration of concrete. In this study, the possibility of the prevention of deterioration or delay of deterioration of concrete was investigated using natural latex modified with silica sol and calcium ions for cement mortar, which can be used to repair the mortar of deteriorated concrete or for finishing the mortar of concrete. As a result, fine calcium silicate hydrate was formed in the pores of the cement material due to the calcium ions and silica sol components contained in the modified latex component that reduce the pore distribution of the cement mortar, thereby reducing the penetration and diffusion of harmful ions (CO32-, Cl-, and SO42-). Furthermore, the latex component was found to be present in the pores of the cement to improve the alkali resistance and carbonation resistance.

Strengthen Effect of RC Beam Overlaid or Repaired by VES-LMC (초속경 라텍스개질콘크리트로 덧씌우기 및 보수된 철근콘크리트보의 보강효과)

  • Choi, Sung-Yong;Yun, Kyong-Ku;Choi, Seung-Sic
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.423-430
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    • 2008
  • VES-LMC (very-early strength latex-modified concrete) has been widely used as repair material for bridge deck overlay or rehabilitation, because the overlaid or repaired could be opened to the traffic after 3 hours of curing. Although the field performance of VES-LMC generally indicates that it has an excellent bonding to the substrate and shows a long term performance, little quantitative data or research results have been presented in the literature on structural studies. The purpose of this study was to investigate the flexural behavior, interfacial performance, crack propagation, and strengthen effect of RC beam overlaid or repaired by VES-LMC through the 4-point flexural loading test. Two different types of RC beam were fabricated for repair and rehabilitation types. The test result showed that the strengthen effect, in term of flexural stiffness, increases as the depth of repair or overlay increases. More than 40% of stiffness was improved when the depth of repair was up to steel position. However, there was a little difference between 80 mm and 120 mm repaired beam. This means the repair depth must be considered. The interfacial behavior data showed that the repaired or overlaid beams had a little relative displacement. This means that two materials behave comparatively acting together. However, there were two specimens which had large displacement at the interface, because of poor bond strength. This suggested that interface treatment is one of the most important jobs in composite beams.

Natural Rubber-Clay Nanocomposites by Latex Method : Morphology and Mechanical Properties (라텍스법에 의한 천연고무-클레이 나노 복합재료: 모폴로지와 기계적 물성)

  • Kim, W.H.;Kang, J.H.;Kang, B.S.;Cho, U.R.
    • Elastomers and Composites
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    • v.41 no.1
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    • pp.27-39
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    • 2006
  • In this study, modified DA-MMT filled NR/DA-MMT nanocomposites were manufactured by a latex method and a compounding method. Cure characteristics and mechanical properties of the Cloisite 15A, carbon black, Na-MMT filled NR compounds and the DA-MMT filled NR compound by a latex method were also evaluated. The filler content of all compounds was 10phr except the carbon black filled compound. Degree of intercalation and dispersion was characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM). According to the XRD diffraction pattern and TEM analysis, extensive intercalation and homogeneous dispersion of the clay were obtained after the two-roll milling. Although the layer distance was increased, some parts of DA-MMT showed the layer distance of Na-MMT after vulcanization. DA-MMT filled NR compounds showed the highest ODR torques, tensile strength, modulus, and tear energy. The NR/DA-MMT nanocomposite (by a latex method) compared with a NR/DA-MMT nanocomposite (by a compounding method) was found that the improvement of the mechanical properties was mainly due to the degree of dispersion of the clay.