• Title/Summary/Keyword: 디메틸 에테르

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Numerical Analysis for Booster Effect in DME HCCI Engine with Fuel Stratification (연료의 불균질성을 갖는 DME HCCI엔진에서 과급의 효과에 관한 수치해석)

  • Kwon, O-Seok;Lim, Ock-Taeck
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.3
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    • pp.19-25
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    • 2010
  • The purpose of this study is to gain a better understanding of the effects of fuel stratification on reducing the pressure-rise rate at high load in HCCI combustion. It was found that fuel stratification offers good potential to achieve a staged combustion event and reduced pressure-rise rates. The engine is fueled with Di-Methyl Ether (DME) which has unique 2-stage heat release. Numerical analysis is conducted with single and multi-zones model and detailed chemical reaction scheme is done by chemkin and senkin. Calculation result shows that proper fuel stratification prolongs combustion duration and reduce pressure rise rate. Besides IMEP, combustion efficiency and indicated thermal efficiency keep constant. However, too wide fuel stratification increases pressure rise rate and CO and NOx emissions in exhaust gas.

Performance and Emissions of a SI Engine Operated with LPG-DME Blended Fuel (LPG-DME 혼합연료를 사용하는 전기점화 기관의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Oh, Seung-Mook;Kang, Kern-Yong;Choi, Won-Hak;Cha, Kyoung-Ok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.2
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    • pp.175-182
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    • 2008
  • In this study, a spark ignition engine operated with LPG and DME blended fuel was studied experimentally. Performance and emissions characteristics of a LPG engine fuelled by LPG and DME blended fuel were examined. Results showed that stable engine operation was possible for a wide range of engine loads within 20% mass content of DME fuel. Also, engine output power within 10% mass content of DME fuel was comparable to pure LPG fuel operation. Exhaust emissions measurements showed that hydrocarbon and NOx were increased with the blended fuel at low engine speed. Engine output power was decreased and break specific fuel consumption (BSFC) was severely increased with the blended fuel since the energy content of DME was much lower than that of LPG. Considering the results of engine output power and exhaust emissions, the blended fuel within 20% mass content of DME could be used as an alternative fuel for LPG.

An Investigation on Spray Characteristics of Diesel - DME with Change of Injection Pressure (분사압력 변화에 따른 디젤-DME연료의 다단분사 특성에 관한연구)

  • Jeong, Y.H.;Yang, J.W.;Oh, C.H.;Lim, O.T.
    • Journal of ILASS-Korea
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    • v.18 no.4
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    • pp.188-195
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    • 2013
  • An investigation on spray characteristics of fuels which diesel and di-methyl ether (DME) with change of injection pressure used the multi-injection in constant volume combustion chamber (CVCC). Diesel was already used famous fuel which we could use. DME showed similar features with diesel like as cetane number, auto-ignition temperature. High cetane number of diesel and DME could make possible to compression ignition. DME showed different atomization from diesel due to evaporating pressures and boiling points. Experiments were carried out in CVCC equipped with Delphi solenoid 6-hole type injector and the spray characteristics of diesel and DME were tested the various pre and pilot injection. Terms of injections and a number of injections in multi-injection has been controlled. Experiments were performed in 2 types that 1500 rpm, 2000 rpm and under the condition of injection ranging from 100 bar to 500 bar. From the results of this experiment diesel showed longer spray penetration than DME. That result showed different of atomization speed DME and diesel. Result of high injection pressure condition showed similar spray characteristics diesel and DME. After this investigation, new conditions and experiments using laser light to go forward and add the fuels like as the biodiesel and diesel and DME blend.

Prediction of the Viable Operating Range of DME Heel Engine Using Thermal Stratification Based on Numerical Analysis (온도 성층화를 이용한 DME HCCI 엔진의 운전 영역 확장에 관한 수치해석 연구)

  • Jeong, Dong-Won;Kwon, O-Seok;Back, Young-Soon;Lim, Ock-Taeck
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.4
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    • pp.344-351
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    • 2009
  • A multi-zone model was used to predict the operating range of homogeneous charge compression ignition (HCCI) engine, the boundaries of the operating range were determined by knock (presented by ring intensity), misfire (presented by sensitivity of indicated mean effective pressure to the initial temperature). A HCCI engine fueled with Di-Methyl Ether (DME) was simulated under different initial temperature and equivalence ratios, and the operating range was well produced by the model. Furthermore, the model was applied to develop the operating range for thermal stratification in the preceding condition of initial temperature and equivalence ratios. The computations were conducted using Senkin application of the CHEMKINII kinetics rate code.

Development of High Pressure Membrane-Based Associated Gas Separation System for DME Synthesis (DME 합성을 위한 고압 유휴가스 분리용 Membrane 시스템 개발)

  • Kim, Hackeun;Bae, Myongwon;Lee, Sangjin;Ha, Seongyong;Lee, Chungseop;Mo, Yonggi
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.1
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    • pp.45-53
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    • 2015
  • The objective of this study is to develop a gas pro-treatment system for DME synthesis, wherein this system separates $CO_2$ from Flaring gas as Membrane, in order to save raw material ($CH_4$) cost of DME. In this study, hollow fiber membrane is developed, which is able to separate high-pressure gas, supported by polysulfone and coated with amorphous fluorinated polymer. Throughout the evaluation of the membrane's separation characteristics, the membrane is applied to this system. The membrane is designed by 2 stages for over 90% removal rate of $CO_2$ and over 90% recovery rate of $CH_4$. The bench scale of pro-treatment system is developed as $25Nm^3/hr$.

A Study on Various Application Technologies Using Coal Bed Methane (Coal Bed Methane을 사용한 다양한 응용 기술에 대한 고찰)

  • CHO, WONJUN;LEE, JESEOL;YU, HYEJIN;LEE, HYUN CHAN;JU, WOO SUNG;LIM, OCKTAEK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.1
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    • pp.130-137
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    • 2018
  • Now discusses the potential use and applications of coal bed methane (CBM) in various industries. One of the options for gas monetization is gas to power (GTP), sometimes called gas to wire (GTW). Electric power can be an intermediate product, such as in the case of mineral refining in which electricity is used to refine bauxite into aluminum; or it can be an end product that is distributed into a large utility power grid. For stranded gas, away from the regional markets, the integration of the ammonia and urea plants makes commercial sense. These new applications, if established, could lead to a surge in demand for methanol plants.

Effect of Nozzle Hole Number on Atomization Characteristics of DME Fuel Spray using High Pressure Injector (고압 인젝터의 노즐 홀 수가 DME 연료분무의 미립화 특성에 미치는 영향)

  • Lee, Jongtae;Lee, Sanghoon;Chon, Mun Soo
    • Journal of ILASS-Korea
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    • v.19 no.4
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    • pp.216-220
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    • 2014
  • This paper presents effect of nozzle hole number on atomization characteristic of DME fuel spray using three different type of injector having the hole number of 6, 7 and 8. For this study, PDPA(phase Doppler particle analyzer) experiment was performed in terms of $T_{ASOE}$ under various injection pressure. To compare general trend of atomization characteristic, the law data were ensemble averaged based on $T_{eng}$ of 0.2 ms. Results showed that the droplet diameter in terms of SMD(Sauter Mean Diameter) was reduced as increase in injection pressure. Increasing the number of hole lead to reduce in droplet diameter, but no significant reduction in diameter was observed between hole number of 7 and that of 8. In addition, increasing the number of hole resulted in decrease in droplet velocity which is considered as the effect of reduction in spray momentum due to decreasing of fuel quantity per each hole.

Direct Synthesis of Dimethyl Ether From Syngas in Slurry Phase Reactor (액상 슬러리 반응기에서 합성가스로부터 DME 직접 제조)

  • Hwang, Gap-Jin;Kim, Jung-Min;Lee, Sang-Ho;Park, Chu-Sik;Kim, Young-Ho;Kim, Jong-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.2
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    • pp.119-128
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    • 2004
  • DME(Dimethyl Ether) was directly produced from the synthesis gas using the slurry phase reactor. The catalyst for DME production prepared two types (A type; Cu:Zn:Al=57:33:10, B type; Cu:Zn:Al=40:45:15, molar ratio). It was evaluated for the effect of the reaction medium oil using the small size slurry phase reactor. DME production yield and the methanol selectivity decreased in the order: n-hexadecane oil> mineral oil> therminol oil. The long-term test of DME production was carried out using A and B type catalyst, and n-hexadecane oil and mineral oil, respectively. It was confirmed that the use of A type for the catalyst and n-hexadecane for the reaction medium oil was very useful for the viewpoint of the DME production form the synthesis gas.

Experiment of CO Cleaning Process in DME Autothermal Reformate Gas for PEMFC Application (고분자 전해질 연료전지 적용을 위한 DME 자열개질가스 내 CO제거 공정 특성 연구)

  • Choi, Seung-Hyeon;Bae, Joong-Myeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.4
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    • pp.474-480
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    • 2011
  • Hydrocarbon is required to be converted to pure hydrogen without carbon monooxide (CO) for polymer exchange membran fuel cell (PEMFC) applications. In this paper, CO cleaning processes as the downstream of Dimethyl ehter (DME) autothermal reforming process were performed in micro-reactors. Our study suggested two kinds of water gas shift (WGS) reaction process: High Temperature shift (HTS) - Low Temperature shift (LTS), Middle temperature shift (MTS). Firstly, using perovskite catalyst for MTS was decreased effieiciency since methanation. Using HTS-LTS the CO concentration was decreased about 2% ($N_2$ & $H_2O$ free) with the reaction temperature of $420^{\circ}C$ and $235^{\circ}C$ for HTS and LTS, respectively. As the final stage of CO cleaning process, preferential oxidation (PROX) was applied. The amount of additional oxygen need 2 times of stoichiometric at $65^{\circ}C$. The total conversion reforming efficiency of 75% was gained.

Effect of Water Addition on the Conversion of Dimethyl Ether to Light Olefins over SAPO-34 (SAPO-34 촉매상에서 디메틸에테르로부터 경질올레핀 제조 및 물의 첨가 효과)

  • Baek, Seung-Chan;Lee, Yun-Jo;Jun, Ki-Won
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.345-349
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    • 2006
  • Conversion of DME (dimethyl ether) or methanol to light olefins (ethylene, propylene, butenes) over SAPO-34 were systematically studied, where it was observed that DME was dehydrated to light olefins and partially converted to by-products such as CO and $CO_2$ at various reaction temperatures on the time-on-stream. SAPO-34 catalyst during the DTO (dimetyl ether-to-olefins) reaction was significantly deactivated compared with MTO (methanol-toolefins) reaction. By addition of water to the reaction feed, the yield to light olefins was not only increased, but the life time of the catalyst was also prolonged by the suppression of the coke formation by steam.