• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2010년도 추계학술대회 초록집
• /
• pp.107-107
• /
• 2010

Hydrogen is an alternative fuel for the future energy which can reduce pollutants and greenhouse gases. Synthesis gas have played an important role of synthesizing the valuable chemical compound, for example methanol, DME and GTL chemicals. Renewable biomass feedstocks can be potentially used for fuels and chemical production. Current thermal processing techniques such as fast pyrolysis, slow pyrolysis, and gasification tend to generate products with a large slate of compounds. Lignocellulose feedstocks such as forest residues are promising for the production of bio-oil and synthesis gas. Pyrolysis and gasification was investigated using thermogravimetric analyzer (TGA) and bubbling fluidized bed gasification reactor to utilize forest woody biomass. Most of the materials decomposed between $320^{\circ}C$ and $380^{\circ}C$ at heating rates of $5{\sim}20^{\circ}C/min$ in thermogravimetric analysis. Bubbling fluidized bed reactor were use to study gasification characteristics, and the effects of reaction temperature, residence time and feedstocks on gas yields and selectivities were investigated. With increasing temperature from $750^{\circ}C$ to $850^{\circ}C$, the yield of char decreased, whereas the yield of gas increased. The gaseous products consisted of mostly CO, CO2, H2 and a small fraction of C1-C4 hydrocarbons.

• 한국응용과학기술학회지
• /
• 제34권2호
• /
• pp.210-216
• /
• 2017

선박엔진에서 발생하는 NOx 및 SOx 제거용 스크러버 폐세정액에 포함되어 있는 저농도상의 질산 및 황산이온을 비료상 물질로 회수하고자 하였다. 본 연구에서는 네 가지 유기용매를 적용하여 선택적으로 추출하여 회수하는 방법을 시험하였다. 아세톤과 메틸알콜을 이용하여 추출한 질산암모늄과 디에틸에테르와 에틸알콜을 적용한 황산암모늄의 시료를 적외석흡수분광법(IR)을 이용하여 분석한 결과, 상용제품과 거의 동일한 구성성분으로 나타났다. 이때 폐수로부터의 회수율은 최대 89%와 80%까지 각각 얻을 수 있었다. 따라서 배기가스 스크러버에 잔존해있는 질산이온과 황산이온에 대한 회수는 사용하는 용매의 선택도 및 용해도가 핵심적인 요소인 것으로 판단된다.

• 한국수소및신에너지학회논문집
• /
• 제21권6호
• /
• pp.587-594
• /
• 2010

Hydrogen is an alternative fuel for the future energy which can reduce pollutants and greenhouse gases. Synthesis gas has played an important role of synthesizing the valuable chemical compounds, for example methanol, DME and GTL chemicals. Renewable biomass feedstocks can be potentially used for fuel and chemicals. Current thermal processing techniques such as fast pyrolysis, slow pyrolysis, and gasification tend to generate products with a large slate of compounds. Lignocellulose feedstocks such as forest residues are promising for the production of bio-oil and synthesis gas. Pyrolysis and gasification was investigated using thermogravimetric analyzer (TGA) and bubbling fluidized bed gasification reactor to utilize forest woody biomass. Most of the materials decomposed between $320^{\circ}C$ and $380^{\circ}C$ at heating rates of $5{\sim}20^{\circ}C$/min in thermogravimetric analysis. Bubbling fluidized bed reactor was used to study gasification characteristics, and the effects of reaction temperature, residence time and feedstocks on gas yields and selectivities were investigated. With increasing temperature from $750^{\circ}C$ to $850^{\circ}C$, the yield of char decreased, whereas the yield of gas increased. The gaseous products consisted of mostly CO, $CO_2$, $H_2$ and a small fraction of $C_1-C_4$ hydrocarbons.

• 대한기계학회논문집B
• /
• 제35권1호
• /
• pp.67-73
• /
• 2011

본 연구는 DME-바이오디젤 혼합연료의 분무 및 연소, 배기 특성을 바이오디젤과 비교한 실험적 연구이며 실험연료는 바이오디젤 (BD100)과 중량 기준으로 DME를 20% 혼합한 DME-바이오디젤 혼합연료 (B-DME20)이다. 거시적 분무 특성을 연구하기 위하여 분무 이미지로부터 분무도달거리, 분무각을 측정하였으며, 연소 및 배기 특성은 단기통 직접 분사식 압축착화 기관을 이용하여 분석하였다. 실험결과 바이오디젤과 DME-바이오디젤 혼합연료는 분사율에서는 큰 차이가 없었지만 혼합연료의 경우에 착화지연기간이 짧고 연소압력이 높았으며soot 배출물이 현저하게 줄어들었다.

• 공업화학
• /
• 제20권4호
• /
• pp.355-362
• /
• 2009

석유를 기반으로 한 연료는 가까운 미래에 고갈될 것이다. 디메틸에테르(Di-methyl Ether, DME)는 청정에너지이며 천연가스,석탄 및 바이오매스 등으로 생산이 가능하다.DME는 분자구조 내에 탄소-탄소 결합이 없는 함산소 연료로 연소시 그을음과 황산화물을 발생하지 않으며, 물리적 특성이 액화석유가스(Liquified Petroleum Gas, LPG)와 매우 유사하여 LPG 유통인프라를 그대로 활용할 수 있다. DME는 세탄값이 55~60 정도로 높아 디젤 자동차용 연료로도 활용이 가능하다.차세대 청정연료로 혹은 차세대 화학공업 원료물질로 전력생산,디젤 연료, 가정용 연료 및 연료전지 등에 사용이 가능하다.본 총설에서는DME의 특성, 표준화, 국내외의 기술개발현황, 대체연료로서의 활용에 대해 살펴보고자 한다.

• 한국자동차공학회논문집
• /
• 제20권3호
• /
• pp.45-51
• /
• 2012

This work was investigated 2-stage injection strategy on combustion and emissions in a direct injection compression-ignition engine fueled with DME. Single cylinder engine was equipped with common rail. Injection pressure was 700bar, dSOI between the main injection and the pilot injection was varied. Diesel was used as compared fuel of DME in all cases. The results was shown that maximum pressure was higher than all cases and its amount of DME and diesel was similar. Regardless the pilot injection, the main fuel injection timing was same. The heat release rate of the main injection for diesel was high while that of pilot injection for DME was high. The THC was very low regardless of the fuel type and injection strategy. In the single injection, NOx was increased to retard of main injection timing regardless of the fuel type. NOx emissions was decreased with the retardation of the main injection timing regardless of the fuel type in the case of 2-stage injection strategy.

• 한국자동차공학회논문집
• /
• 제20권3호
• /
• pp.88-97
• /
• 2012

To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, CO2 and THC (Total hydrocarbon), and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the experiment in which a MEL chases a city bus fuelled by diesel, DME and Bio-diesel. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the bus fuelled by diesel were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. However, most particles in the exhaust of the bus fuelled by DME were nano-particles (diameter: less than 50 nm). The bus fuelled by Bio-diesel shows less particle emissions compare to diesel bus due to the presence of the oxygen in the fuel.

• 한국자동차공학회논문집
• /
• 제20권6호
• /
• pp.107-116
• /
• 2012

In this study, the trucks(2.9-liter) have been developed to use DME as fuel, and performance test of the vehicle's DME engine, power, emissions, fuel economy and vehicle aspects was conducted. For experiments, the fuel system(common-rail injectors and high-pressure pump included) and the engine control logic was developed, and ECU mapping was performed. As a result, the rail pressure from 40MPa to approximately 65% increase compared to the base injector has been confirmed that. Also, the pump discharge flow is 15.5 kg/h when the fuel rail pressure is 400rpm(40MPa), and the pump discharge flow is 92.1 kg/h when the fuel rail pressure is 2,000rpm(40MPa). The maximum value of full-load torque capability is 25.5 kgfm(based on 2,000 rpm), and more than 90% compared to the level of the diesel engine were obtained. The DME vehicle was developed in this study, 120 km/h can drive to the stable, and calculated in accordance with the carbon-balance method of fuel consumptions is 5.7 km/L.

• 한국자동차공학회논문집
• /
• 제21권4호
• /
• pp.1-7
• /
• 2013

DME spray characteristics were investigated about varied ambient pressure and fuel injection pressure using the DME common rail fuel injection system when the nozzle holes diameter is varied. The common rail fuel injection system with DME cooling system was used since DME has properties of compressibility and vaporization in atmospheric temperature. The fuel injection quantity and spray characteristics were measured. The spray analysis parameters were spray shape, penetration length, and spray angle at six nozzle holes. Three types of injector were used, the nozzle holes diameter were 0.166 mm (Injector 1), 0.250 mm (Injector 2), and 0.250 mm with enlargement of orifice hole from 0.6 mm to 1.0 mm (Injector 3). The fuel injection pressure was varied by 5MPa from 35 to 70MPa when the ambient pressure was varied 0, 2.5, and 5MPa. When using Injector 3 in comparison to the others, the DME injection quantity was increased 1.69 ~ 2.02 times. Through this, it had the similar low heat value with diesel which was injected Injector 1. Among three types of injector, Injector 3 had the fastest development velocity of penetration length. In case of spray angle, Injector 2 had the largest spray angle. Through these results, only the way enlargement the nozzle holes diameter is not the solution of DME low heat value problem.

• 해양환경안전학회지
• /
• 제16권3호
• /
• pp.301-306
• /
• 2010

DME는 환경 친화적인 특성으로 인해 현재 전 세계적으로 주목을 받고 있다. 지금까지 DME는 매연을 적게 생산하는 청정 에너지라는 특성으로 인해 디젤 자동차의 주요 대체 에너지로서 연구되어 왔다. 이에 본 연구에서는 에틸렌 대향류 확산화염에 DME를 5%, 14% 및 30% 혼합했을 때, DME의 혼합 비율에 따른 매연의 수밀도 및 크기에 대한 영향을 조사하였다. 레이저 투과법 및 산란법을 이용해 수밀도 및 크기를 측정하였다. 그 결과 DME를 30% 혼합한 경우에는 매연이 감소한 반면, 5%와 14%의 혼합 비율에서는 매연이 증가하는 경향을 나타내었다. 이 결과는 DME가 매연 생성이 적은 청정 연료로 알려진 것과는 달리 에틸렌 확산화염 내에서는 DME의 혼합에 따라 매연 생성이 증가될 수 있다는 것을 의미한다.