• Journal of Korean Society of Environmental Engineers
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• v.33 no.8
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• pp.606-616
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• 2011

The objectives of this study were to evaluate the applicability of adsorption models for adsorption properties of adsorbents. For this study, adsorption experiment of $NO_3^-$ ion using anion exchange resin has been investigated under adsorption equilibrium and kinetic in bach process. Adsorption equilibrium experiment were carried out that two conditions is change of adsorbate concentration and change of adsorbent weight. Experiment results have been analyzed by adsorption isotherm models, energy models and kinetic models. Under the condition of change of adsorbate concentration was best described by Sips and Redlich-Perterson isotherm models. However case of change of adsorbent weight was described by Langmuir isotherm models. It seems reasonable to assume that isotherm model was dominated by multiple mechanism according to experiment condition.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.6
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• pp.1330-1338
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• 1989

본 연구에서는 직각밀폐용기의 수평경계면이 단열인 경우뿐만 아니라 등온 조건을 갖는 경우에 대해 실험적으로 연구하여 경계조건의 변화가 직각밀폐용기내 흐름 및 열전달에 미치는 영향, 특히 등온조건을 갖는 경우 수직 온도차에 따르는 안정온도 구배효과로 예상되는 흐름의 억제, 지연효과를 작종 물리적 변수들의 영향과 함께 세밀히 조사하였다.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.1
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• pp.207-213
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• 1990

Natural convection heat transfer in rectangular air enclosure was studied interferometrically and numerically for the use of adiabatic and constant temperature horizontal boundary conditions. In the isothermal horizontal boundary case with the temperature difference ratio, .DELTA. $T_{v/}$.DELTA. $T_{H}$ .simeq. 1 temperature distribution in the enclosure is strongly stratified and the average Nusselt Number is higher than that of adiabatic horizontal boundary case.ase.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.3
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• pp.10-16
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• 2020

Computational simulations of adsorption columns were carried out to investigate the removal characteristics of VOCs from a laundry shop. n-Decane was selected as the representative component among the VOCs emitted, and the activity of the adsorbents, such as activated carbon, was evaluated using commercial CFD code. The mathematical framework was composed of continuity and Navier-stokes equations, and the simulation was performed using the Matlab program. The adsorption isotherms of LDF, Freundlich, and Langmuir were evaluated, and the adsorption amount of the adsorption isotherms with the adsorption parameter was compared. The simulation was carried out using a particle porosity, dispersion coefficient, particle density, bed diameter, and bed length of 0.79, 42.4 ㎠/min, 485 g/L, 2.0 cm, and 2.5 cm, respectively. The effect of the gas velocity, dispersion coefficient, and voidage on the adsorption amount was compared in the Langmuir adsorption isotherm. The simulation was carried out in the velocity range of 50 to 200 cm/min, dispersion coefficient range of 100 to 400 ㎠/min, and particle porosity range of 0.66 to 0.79. The simulation results of activated carbon with benzene coincided with the Langmuir isotherm. Three types of adsorption isotherm were compared under similar conditions, and the simulation results showed the efficient adsorption condition for hydrocarbons.

• Transactions of the Korean Society of Mechanical Engineers
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• v.10 no.5
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• pp.798-805
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• 1986

단열 혹은 등온 경계조건 하의 수직평판과, 선열원으로부터 형성되는 열상승류 간의 열적 상호작용을 조사형ㅆ다. 경계층 방정식은 Patankar-Spalding의 유한차분법을 사용하여 계산하였다. 단열평판의 경우에 자유 열상승류로부터 벽 경계층으로 부터의 점진적인 발달 단계를 설명하였다. 등온평판의 경우에는 평판주위에 새롭게 형성되는 열경계층에서의 열전달현상을 자세히 고찰하였다.

• Journal of the Mineralogical Society of Korea
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• v.18 no.4 s.46
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• pp.289-299
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• 2005

Annealing experiments on albite powders, thin sections, and TEM specimens have been performed utilizing an optical microscope heating stage. Sample orientations were determined by optical microscope and XRD, and then confirmed by TEM diffraction patterns. Partial melting of samples occurred at $1030^{\circ}C$-l2 hr for powder, but at $1060^{\circ}C$-12 hr for TEM specimen. It is difficult to get TEM images of albite microstructures above this temperature due to thickening and the amorphous phase of the melted part. Correlative studies between optical microscopy and TEM indicated that the $1050^{\circ}C$-12 hr annealing in ambient condition was most adequate to observe tweed microstructures in albite through TEM. In situ TEM heating experiments for direct observation of tweed microstructures in albite may require annealing at slightly higher temperatures than $1050^{\circ}C$ considering the high vacuum condition inside TEM.

• Journal of the Korean Society of Clothing and Textiles
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• v.27 no.12
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• pp.1434-1440
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• 2003

개망초로부터 색소를 추출, 분말화하여 FT-IR 분석을 행하고, 모섬유에 대한 염색조건과 매염이 염착량(K/S값) 및 색상에 미치는 영향을 조사하였다. 또한 염색한 시료의 견뢰도를 측정하여 실용성을 확인하였다. 개망초 색소는 모섬유에 높은 친화력을 보였으며, Langmuir형의 등온흡착곡선을 보여 염착이 주로 이온결합에 의해 이루어지는 것으로 나타났다. 염착략이 pH 3.0에서 최대가 되었으나 강한 산성조건은 강도 저하를 비롯한 섬유에 손상을 주기 때문에 pH를 조절하지 않고 염색하였다. 피염물의 색상은 모두 Y 계열을 나타내었다. 철매염 처리한 경우를 제외하고 매염처리가 염착량 증진에 미치는 영향은 그다지 크지 않았으며, 매염제 종류를 달리하여 염색한 모섬유의 색상은 크롬과 주석으로 매염한 경우 YR 계열을 나타내고 그 밖의 매염제에 의해서는 Y 계열의 색상을 나타내어 큰 변화는 없었다. 매염처리하지 않은 시료의 견뢰도는 매우 양호하였으며 매염처리가 견뢰도 증진에 미치는 영향은 크지 않았다.

• 한국초전도학회:학술대회논문집
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• v.10
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• pp.241-247
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• 2000

77 K와 self-field에서 22 A 의 Ic 를 갖는 길이 120 m, 19-심 Bi-2223상 선재를 제조하여, 두 개의 double pancake 코일로 구성된 proto-type 고온초전도 자석을 설계, 제작하여 이 자석에서의 4.2 K와 77 K에서의 I-V 특성과 운전 특성을 평가한 결과, 이 자석은 77 K 등온조건에서는 9.5 A 의 Ic를, 77 K 헬륨가스 속에서는 8.3 A 의 Ic를 나타내었고, 4.2 K 등온조건에서는 93.7 A 의 Ic와 102 A 의 Iq를, 4.2K헬륨가스 속에서는 88.4A의 Ic 와 92.0 A 의 Iq를 나타내어, 이 자석은 4.2 K 와 77 K 의 등온조건에서 각각 0.58 T 와 0.06 T 의 자장을 발생하였는데, 이는 해석적 방법으로 계산한 결과와 잘 일치하였다. 그리고 이 자석이 전도냉각되어 4.2 K 에서 운전될 때의 안정성 특성평가로서, Ic 보다 약간 큰 전류인 89 A 를 인가한 결과, 전류인가 후 82.6초 후에 quench가 발생하였는데, 이 quench는 네 번째 pancake의 전류도입선부 연결부에서와 약간 늦지만 첫 번째 pancake의 전류도입선부 연결부에서 거의 동시에 개시되어 전체로 파급된 것으로 사료되었는데, Ic 가 낮은 첫번째 pancake에서 더 높은 전압 강하가 나타났다. 또한 장착된 heater를 통하여 77 K 에서 8.9 A 의 전류로 운전되고 있는 코일에 146 joule 의 열을 가했을 때 quench 가 일어났는데, 이때 quench 는 방위각 방향의 Bi-2223/Ag 선재를 따라서 보다 Kapton 절연층을 관통하는 선재의 반경방향으로 훨씬 빨리 전파하였다.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.4
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• pp.260-269
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• 2012

The aim of this study is to evaluate the applicability of adsorption models for understanding the thermodynamic properties of adsorption process. For this study, the adsorption isotherm data of $NO_3$-N ion onto a commercial anion exchange resin obtained at various experimental conditions, i.e. different initial concentrations of adsorbate, different dosages of adsorbent, and different temperatures, were used in calculating the thermodynamic parameters and the adsorption energy of adsorption process. The Gibbs free energy change (${\Delta}G^0$) of adsorption process could be calculated using the Langmuir constant $b_M$ as well as the Sips constant, even though the results were significantly dependant on the experimental conditions. The thermodynamic parameters such as standard enthalpy change (${\Delta}H^0$), standard entropy change (${\Delta}S^0$) and ${\Delta}G^0$ could be calculated by using the experimental data obtained at different temperatures, if the adsorption data well fitted to the Langmuir isotherm model and the plot of ln b versus 1/T gives a straight line. As an alternative, the empirical equilibrium constant(K) defined as $q_e/C_e$ could be used for evaluating the thermodynamic parameters instead of the Langmuir constant. The results from the applications of D-R model and Temkin model to evaluate the adsorption energy suggest that the D-R model is better than Temkin model for describing the experimental data, and the availability of Temkin model is highly limited by the experimental conditions. Although adsorption energies determined using D-R model show significantly different values depending on the experimental conditions, they were sufficient to show that the adsorption of $NO_3$-N onto anion exchange resin is an endothermic process and an ion-exchange process.

• The Journal of the Korea Contents Association
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• v.17 no.7
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• pp.538-545
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• 2017

Moisture evaporates, when concrete is exposed to fire, not only at concrete surface but also at inside the concrete to adjust the equilibrium and transfer properties of moisture. The equilibrium properties of moisture are described by means of water vapor sorption isotherms, which illustrate the hysteretical behavior of materials. In this paper, the prediction method of the moisture distribution inside the concrete members at fire is presented. Finite element method is employed to facilitate the moisture diffusion analysis for any position of member. And the moisture diffusivity model of high strength concrete by high temperature is proposed. To demonstrate the validity of this numerical procedure, the prediction by the proposed algorithm is compared with the test result of other researcher. The proposed algorithm shows a good agreement with the experimental results including the vaporization effect inside the concrete.