• Title/Summary/Keyword: 등구조 온도

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금속-유기 구조체 기반 비효소식 글루코오스 센서

  • Kim, Gi-Jun;Bae, Yun-Sang;Kim, Hyeon-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.92.2-92.2
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    • 2018
  • 빠르고 정확한 글루코오스 농도 측정은 의료, 식품, 환경 등 다양한 산업에서 매우 중요하다. 글루코오스 산화효소를 기반으로 하는 현재 글루코오스 센서는 높은 감도와 선택성을 갖지만 온도변화나 다른 화학물 등 환경에 취약하다는 단점이 있다. 따라서 최근 비효소식 글루코오스 센서에 대한 연구가 활발히 진행되고 있다. 금속-유기 구조체(MOFs)는 금속이온과 유기물 리간드로 구성된 결정성 다공체로, 큰 기공 크기와 비표면적, 안정성 등을 특징으로 갖는다. 대부분의 MOFs는 전기전도도가 낮지만 금속이온의 산화/환원, 리간드의 화학적 개질을 통해 전기화학분야에서도 다양하게 연구되고 있다. 본 연구에서는 글루코오스 농도 측정을 위한 전극촉매로 다양한 금속이온과 리간드로 이루어진 MOFs를 합성했다. 표면분석을 통해 MOFs의 전기화학적 처리 전후의 구조와 성질 변화를 관찰했고 전기화학적 분석을 통해 금속이온과 리간드의 종류가 감도, 선택성 등 글루코오스 검지 성능에 주는 영향을 분석했다. 그 결과 Ni, Co 기반의 MOFs가 글루코오스에 대해 높은 감도를 보였으며 이를 통해 MOFs의 글루코오스 센서로의 응용 가능성을 확인했다.

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Performance Based Evaluation of Concrete Material Properties from Climate Change Effect on Temperature and Humidity Curing Conditions (기후변화의 온도와 습도 양생조건에 따른 콘크리트 재료특성의 성능중심평가)

  • Kim, Tae-Kyun;Shin, Jae-Ho;Shin, Dong-Woo;Shim, Hyun-Bo;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.6
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    • pp.114-122
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    • 2014
  • Currently, global warming has become a serious problem arising from the usage of fossil fuels such as coal and petroleum. Moreover, due to the global warming, heat wave, heavy snow, heavy rain, super typhoon are frequently occurring all over the world. Due to these serious natural disasters, concrete structures and infrastructures are seriously damaged or collapsed. In order to handle these problems, climate change oriented construction technology and codes are necessary at this time. Therefore, in this study, the validity of the present concrete mixture proportions are evaluated considering temperature and humidity change. The specimens cured at various temperature and humidity conditions were tested to obtain their compressive and split tensile strengths at various curing ages. Moreover, performance based evaluation (PBE) method was used to analyze the satisfaction percentage of the concrete cured at various condition. From the probabilistic method of performance evaluation of concrete performance, feasibility and usability can be determined for future concrete mix design.

Properties of Fire Resistance in Tunnel Concrete According to the Changes of Heating Curve (온도가열곡선 변화에 따른 콘크리트의 내화특성)

  • Pei, Chang-Chun;Noh, Sang-Kyun;Lee, Chan-Young;Lee, Jong-Suk;Lee, Jang-Hwa;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.705-708
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    • 2008
  • To obtain tunnel concrete safety in case of fire, this study analyzed fire proof characteristics by fire proof method change, and the results are as follows. As a fire proof characteristics by RABT temperature heating curve, plain concrete experienced severe spalling by initial extremely high temperature. In view of fire proof method, in the cases of organic fiber mixing method and board method, spalling was prevented, and in the case of spray method, severe spalling of over 100mm depth occurred along with exposure of structural concrete including spray coat by heat stress, etc while metal lath, the stiffener, falls off. As for fire proof characteristics by RWS temperature heating curve, in case of organic fiber inclusion, concrete surface experienced fusion of within 5mm, while in the case of spray method, spray coat was severely spalled to a depth of over 100mm causing structural body concrete to expose its reinforcement, and also in the case of board method, board was fused by high temperature, causing structural body concrete be directly exposed to high temperature, which triggered overall fall-off phenomenon, so in such extraordinary high temperature heating condition, establishment of special fire proof measures is needed.

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Experimental Study on Temperature-Moisture Combined Measurement System for Slope Failure Monitoring (사면붕괴 모니터링에 사용되는 온도-함수비 복합계측시스템 개발에 관한 실험적 연구)

  • Nam, Jin-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.2
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    • pp.33-39
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    • 2015
  • Recently, the event of slope failure has been occurring frequently due to rapid climate changes and broad development of infrastructures, and the research for establishment of monitoring and prevention system has been an attentive issue. The major influence factors of slope failure mechanism can be considered moisture and temperature in soil, and the slope failure can be monitored and predicted through the trend of moisture-temperature change. Therefore, the combined sensing technology for the continuous measurement of moisture-temperature with different soil depths is needed for the slope monitoring system. The various independent sensors for each item (i.e. temperature and moisture respectively) have been developed, however, the research for development of combined sensing system has been hardly carried out. In this study, the high-fidelity sensor combing temperature-moisture measurement by using the minimized current consuming temperature circuit and the microwave emission moisture sensor is developed and applied on the slope failure monitoring system. The feasibility of developed monitoring system is verified by various experimental approaches such as standard performance test, mockup test and long-term field test. As a result, the developed temperature-moisture combined measurement system is verified to be measuring and monitoring the temperature and moisture in soil accurately.

Analysis of the Frequency for Cable of Cable-Stayed Bridges to Temperature Variation (온도변화에 따른 사장교 케이블 고유진동수 분석)

  • Lee, Hyun-Chol;Kim, Jin-Soo;Park, Kyoung-Ho;Lee, Jong-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.2
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    • pp.23-34
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    • 2021
  • Cable was targeted for cable, which is a main material of cable-stayed bridges that have high frequency of use at home and abroad and many future construction plans. First of all, experiments were conducted on temperature loads that were permanently used due to changes in temperature of cables and changes in air temperature, taking into account changes in normal fat. The dynamic characteristics of cables were compared and analyzed by applying various systems to change dynamic characteristics by applying temperature change of cables. Comparing and analyzing the dynamic characteristics of cables, the acceleration, frequency and tension of cables due to temperature rise tended to decrease, the degree of influence of displacement of cables was analyzed, and the results of the mode characteristics of cables were analyzed. In particular, the correlation of cable acceleration, natural frequency, and tension due to changes in cable temperature showed that the cable tension is highly sensitive to acceleration and natural frequency.

RF magnetron sputtering에 의해 제작된 $SnO_2$ 투명전극의 구조적 및 광학적 특성

  • Im, Jeong-U;Lee, Dong-Hun;Yu, Jae-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.205-205
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    • 2010
  • 투명 전극(transparent conducting oxide, TCO)은 높은 전기전도도 및 낮은 비저항 ($10^{-4}{\sim}10^{-3}\;{\Omega}cm$)과 가시광영역에서의 우수한 광투과도(> 80%) 특성을 가지며, 주로 디스플레이, 태양전지, 가스 센서 소자 등에 쓰인다. 투명전극으로 쓰이는 대표적인 물질로서는 ITO, ZnO, $SnO_2$ 등이 있으며, ITO는 전기적 특성이 우수하여 널리 사용되고 있으나 가격이 비싸고 화학적으로 불안정하고, ZnO는 ITO에 비해 가격이 저렴하지만 고온에서 불안정한 특성을 가지고 있다. 반면, $SnO_2$는 ITO와 ZnO에 비해 전기적 특성은 떨어지지만, 우수한 열적, 화학적 안정성 및 높은 내마모성을 가지고 제조단가가 저렴하여 TCO 재료로 많은 연구가 진행되고 있다. TCO 박막을 증착시키는 방법으로 CVD, ion plating, sputtering, spray pyrolysis 등이 있으며, 이 중 sputtering 방법은 균일한 입자로 균질의 박막을 입힐 수 있고 우수한 재현성과 낮은 온도에서도 증착이 가능하여 박막 제조 방법으로 널리 이용되고 있다. 본 연구에서는 $SnO_2$ 박막을 실리콘 (100) 및 글라스 (Eagle 2000) 기판 위에 RF magnetron sputtering 방법을 사용하여 제작하였다. 박막 증착을 위해 99.99%의 2 인치 un-doped $SnO_2$ 타겟을 사용하였고, 기판은 20 rpm 으로 회전시켜 균일한 박막이 형성될 수 있도록 하였으며, 초기 진공도는 $1{\times}10^{-6}\;Torr$가 되도록 하였다. 증착 변수로 기판-타겟간 거리, RF 파워, $O_2/(Ar+O_2)$ 비, 공정압력, 기판 온도 등을 각각 변화 시키며 $SnO_2$ 박막을 증착하였다. 증착된 박막의 구조적 및 광학적 특성을 분석하기위해 FE-SEM, AFM, XRD, UV/VIS spectrophotometer, Photoluminescence 등을 사용하였다.

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A study on the temperature inside clothing as fundamental data for development of the heat energy harvesting clothing (인체 전력에너지 수확의류 개발을 위한 의복내 온도 측정의 기초적 고찰)

  • Yang, Jin-Hee;Cho, Hyun-Seung;Park, Sun-Hyung;Lee, Joo-Hyeon
    • Science of Emotion and Sensibility
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    • v.16 no.1
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    • pp.125-132
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    • 2013
  • Recently, the consciousness of energy crisis is rapidly growing and sustainable eco-friendly energy sources are becoming issue. Therefore the portable electronic device requires new energy sources for providing continuous power supply and the power energy harvesting system of the human body that enables the power-harvesting research requests anytime, anywhere. One of the sources for energy harvesting is heat energy, which is the difference in temperature of the body and the surrounding environment. We tried to analyze the temperature difference between the environmental temperature and the temperature inside clothing according to the structure of the closed portion. And we examined the temperature difference between the environmental temperature and the temperature inside clothing according to the material of the clothing. The analysis showed that we have been able to get different results at parts of the body in the temperature inside clothing according to the structure of clothing. In upper torso of the chest and back, the temperature inside clothing of 'closed structure' was higher than the temperature inside clothing of 'opened structure'. In the section of arm and leg, it was reduced the difference of temperature inside clothing between 'closed structure' and 'opened structure'. It was particularly noticeable in the section of leg. The results of analysis of the difference between the environmental temperature and the temperature inside clothing according to the material of the clothing, in both cases of the two materials, 'closed structure' was higher than the 'opened structure' in the difference value between the environmental temperature and the temperature inside clothing. There was a difference according to the material in the section of leg. In this study, we outlined the basic guidelines for developing heat energy harvesting clothing by exploring the structure and material of clothing suitable for the heat energy harvesting.

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Experimental Study on Limiting Temperatures of Structural Beams made with Structural Steel According to Load Ratios (하중비에 따른 강재 보의 한계온도에 관한 실험적 연구)

  • Kwon, In-Kyu
    • Journal of Korean Society of Steel Construction
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    • v.22 no.6
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    • pp.581-588
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    • 2010
  • Recently the requirements of the buildings built with structural steel were increased in terms of structural stabilities and fire resistance at severe fire conditions. To meet the building regulations of fire resistance, a fire design is needed. This is of a prescriptive method and a performance engineering based method. Recently a simple calculation method as one of performance based engineering method is very popular because of its ease for an application in building built with structural steel. But, in Korea the performance based engineering method is not allowed yet. Thus it is needed to make a guideline for the performance based engineering method. The purpose of this study is to establish the limit temperature derived from structural beams made with both a H-section and a H-section filled with concrete at the web and derived the limit temperatures from beams made with H-sections and found out that the limit temperatures from two kinds of specimens depended on the applied loads and the specimens filled with the concrete represented 3 hour fire resistance in the range of 80%, 60%, and 50% of the maximum load.

A Study on Mechanical Characteristics and Behaviors of FRP Composite with Three Different types of Matrices under High Temperature (온도 및 매트릭스 특성 변화에 따른 섬유강화 복합재료의 역학적 특성 및 구조적 거동 변화)

  • Jung, Woo-Young;Jang, Jun-Ho;Back, Min-Ho
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.3
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    • pp.1-9
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    • 2008
  • Fiber Reinforced Polymer (FRP) composites are used extensively in aerospace, marine, automotive, infrastructure, chemical processing and sporting good applications. A concern with using FRP composites in some engineering structures is their high flammability and poor fire resistance In this research, material properties of FRP composites at increasingly high temperatures was measured and verified. The obtained mechanical properties of FRP composites were performed according to ASTM D3039/D3039M and tested to a wide range of heat conditions with temperatures from Room-temp. to 300 for times up to 30 min. It is found that the mechanical properties of FRP composites dropped with increasing heat or temperature. The reduction to the properties was due mainly to thermal degradation and combustion of the polymer matrix.

Correlation of morphological changes of rice starch granules with rheological properties during heating In excess water (가열 조리시 쌀 전분 입자들의 형태학적 변화와 리올로지 특성과의 관계)

  • Lee, Young-Eun;Osman, Elizabeth M.
    • Applied Biological Chemistry
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    • v.34 no.4
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    • pp.379-385
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    • 1991
  • Morphological changes of starch granules from 12 different varieties of rice were examined by scanning electron microscopy during heating at 2.5% (w/v) concentration. Rice starch granules proceeded through a similar pattern of progressive morphological changes daring heating, regardless of variety. Rice starch granules began to swell radially in the initial stage of gelatinization and then undergo radial contraction and random tangential expansion to form complex structures in the latter stage of gelatinization temperature range. At higher temperatures, starch granules softened and melted into thin flat discs, and then stretched into thin filaments to form three-dimensional networks. These progressive morphological changes were reflected in the changes of swelling power, solubility and amylograph viscosity of starch. During the transition of melting or softening, swelling power, solubility and amylograph viscosity increased rapidly. The time of loss of granular structure of starch depended on gelatinization temperature range. The ratio of amylose to amylopectin was largely responsible fur the rate of melting or softening and the fineness of a three-dimensional filamentous network above the gelatinization temperature range. Therefore, both the gelatinization temperature range and amylose content of starch affect the rate of cooking, and amylose content of starch affects the final texture of cooked starch paste.

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