• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.942-945
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• 2001

Pulse electrochemical micromachining offers significant improvements in dimensional accuracy as compared with conventional electrochemical machining. One primary issue in pulse electrochemical micromachining is to identify and control machining depth as well as interelectrode gap size. This paper presents an identification method for the machining depth by in-process analysis of machining current and interelectrode gap size. The inter electrode gap characteristics, including pulse current, effective volumetric electrochemical equivalent and electrolyte conductivity variations, are analysed based on the model and experiments.

• Proceedings of the KIPE Conference
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• 2011.07a
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• pp.109-110
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• 2011

본 논문은 배터리 에너지 저장 시스템(Battery Energy Storage System, BESS)에 사용된 대용량 리튬이온 배터리의 등가 모델링을 제안하였다. 리튬 배터리의 전기화학적 특성을 고려한 임피던스 등가모델을 선정한 후 등가모델의 파라미터를 추출하였으며, 추출된 파라미터와 SOC(State-of Charge)와의 관계를 살펴보았다. 본 연구를 통하여 얻어진 파라미터를 이용하면 BESS 제어시 배터리 특성을 파악할 수 있으므로, 배터리의 최적제어 및 시스템의 신뢰성을 높일 수 있을 것으로 기대된다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.1
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• pp.83-90
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• 2017

The corrosion behavior of a rebar in concrete according to the amount of NaCl and $LiNO_2$ was observed by using Electrochemical Impedance Spectroscopy. The corrosion was accelerated in a short time by using dry/wet cycles method, which is one of the corrosion acceleration methods, and though the value of measured impedance, equivalent circuit can be introduced. It was confirmed that the passive film of a embedded rebar in concrete with NaCl was broken quickly, and when $0.6M\;LiNO_2$ was added, the velocity of ongoing corrosion was declined considerably compared to the amount of NaCl. However, when $1.2M\;LiNO_2$ was added, it was confirmed that the passive film was not broken and its performance remained, compared to the amount of NaCl.

• Journal of the Korean Society for Precision Engineering
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• v.19 no.4
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• pp.101-108
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• 2002

A specially-built EMM (Electrochemical Micro Machining) / PECM (Pulse Electrochemical Machining) cell, a electrode tool filled with non-conducting material, a electrolyte flow control system and a small & stable gap control unit are developed to achieve accurate dimensions of recesses. Two electrolytes, aqueous sodium nitrate and aqueous sodium chloridc arc applied in this study. The farmer electrolyte has better machine-ability than the latter one because of its appropriate changing to the transpassive state without pits on the surface of workpiece. It is easier to control the machining depth precisely by micrometer with pulse current than direct current. This paper also presents an identification method for the machining depth by in-process analysis of machining current and inter electrode gap size. The inter electrode gap characteristics, inc1uding pulse current, effective volumetric electrochemical equivalent and electrolyte conductivity variations, are analyzed based on the model and experiments.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.811-816
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• 1998

Rebar corrosion in cement mortar containing chloride ions was investigated by electrochemical AC impedance spectroscopy. Corrosion of mild steel bar was accelerated by an acceleration test equipment in short period. Impedance values obtained from AC-impedance method could be adapted to the proposed electrochemical equivalent circuit model and they were consistent with calculated values obtained by CNLS fitting method. The weight loss of rebar could be calculated by charge transfer resistance($R_2$) with time and it was close to real value.

• Journal of the Korean Electrochemical Society
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• v.8 no.4
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• pp.181-185
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• 2005

Lithium cobalt oxide thin film cathode, having thickness of $2.9{\mu}m$ with area of $4cm^2$, was deposited on platinum patterned alumina substrate by radio frequency magnetron sputtering. Li/Co molar ratio, which is an important factor for battery performance, was measured as a function of argon working pressure and applied R.F. power. Constant current charge and discharge performances were characterized with high rate discharge and cycling behavior. Using AC impedance analysis, internal resistance of the thin film battery was measured and simulated by proposed equivalent circuit model.