• Title/Summary/Keyword: 동형치환

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A Study on the Leaching and Recovery of Lithium by Reaction between Ferric Chloride Etching Solution and Waste Lithium Iron Phosphate Cathode Powder (폐리튬인산철 양극재 분말과 염화철 에칭액과의 반응에 의한 리튬의 침출 및 회수에 대한 연구)

  • Hee-Seon Kim;Dae-Weon Kim;Byung-Man Chae;Sang-Woo Lee
    • Resources Recycling
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    • v.32 no.3
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    • pp.9-17
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    • 2023
  • Efforts are currently underway to develop a method for efficiently recovering lithium from the cathode material of waste lithium iron phosphate batteries (LFP). The successful application of lithium battery recycling can address the regional ubiquity and price volatility of lithium resources, while also mitigating the environmental impact associated with both waste battery material and lithium production processes. The isomorphic substitution leaching process was used to recover lithium from spent lithium iron phosphate batteries. Lithium was leached by the isomorphic substitution of Fe2+ in LFP using a relatively inexpensive ferric chloride etching solution as a leaching agent. In the study, the leaching rate of lithium was compared using the ferric chloride etching solution at various multiples of the LFP molar ratio: 0.7, 1.0, 1.3, and 1.6 times. The highest lithium leaching rate was shown at about 98% when using 1.3 times the LFP molar ratio. Subsequently, to eliminate Fe, the leachate was treated with NaOH. The Fe-free solution was then used to synthesize lithium carbonate, and the harvested powder was characterized and validated. The surface shape and crystal phase were analyzed using SEM and XRD analysis, and impurities and purity were confirmed using ICP analysis.

A Characterization of Isomorphism Problem of Combinatorial objects and the Historical Note (조합대상의 동형사상 문제의 특성화와 역사적 고찰)

  • Park, Hong-Goo
    • Journal for History of Mathematics
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    • v.19 no.1
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    • pp.33-42
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    • 2006
  • In this paper, we study the theoretical and historical backgrounds with respect to isomorphism problem of combinatorial objects which is one of major problems in the theory of Combinatorics. And also, we introduce a partial result for isomorphism problem of Cayley objects over a finite field.

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Preparation of 1.1-nm Tobermorite from Starting Zeolite Mineral (Zeolite광물을 출발물질로 한 1.1-nm Tobermorite의 제조)

  • Yim, Going
    • Journal of the Korean Ceramic Society
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    • v.36 no.3
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    • pp.274-283
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    • 1999
  • 1.1-nm tobermorite의 수열합성에 SiO2원으로 zeolite광물을 출발물질로하여 소석회와 Ca(Si+Al)의 몰비 0.8~1.0로 150$^{\circ}$~23$0^{\circ}C$,8~48시간 동ㅇㄴ 포화증기압하에서 수열반응을 시킨 결과, 반응초기단계에서 tobermorite가 생성되었고, 고결정성 1.1-nm tobermorite의 최적합성조건은 0.8몰, 23$0^{\circ}C$, 48시간이었다. 출발물질중 Al의 존재로 tobermorite는 Ca/(Si+Al)몰비 0.8이 1.0보다 결정화가 급속히 이루어지고 있으나 Al를 함유치 않은 석영의 경우에는 Ca/Si 몰비 1.0이 0.8에서 보다 결정화가 빠르게 진행되었다 1.1-nm tobermorite는 $700^{\circ}C$에서 일주일간 가열처리하여도 저면간격이 변화하지 않는 열적거동이 이상형임을 보여주었다. 특히 출발물질중 Al의 존재는 1.1-nm tobermorite의 결정화와 안정화를 촉진시켜주며 Al이온이 tobermorite구조중의 Si이온과 동형치환을 한다.

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Genesis and development of Schur rings, as a bridge of group and algebraic graph theory (Schur환론의 발생과 발전, 군론과 그래프론에서의 역할)

  • Choi Eun-Mi
    • Journal for History of Mathematics
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    • v.19 no.2
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    • pp.125-140
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    • 2006
  • In 1933, I. Schur introduced a Schur ring in connection with permutation group and regular subgroup. After then, it was studied mostly for purely group theoretical purposes. In 1970s, Klin and Poschel initiated its usage in the investigation of graphs, especially for Cayley and circulant graphs. Nowadays it is known that Schur ring is one of the best way to enumerate Cayley graphs. In this paper we study the origin of Schur ring back to 1933 and keep trace its evolution to graph theory and combinatorics.

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Robotic Surgery in the Orthopedic Field (정형외과 영역에서 로봇수술)

  • Lee, Woo-Suk;Jung, Woo-Suk
    • Journal of the Korean Orthopaedic Association
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    • v.53 no.6
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    • pp.459-465
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    • 2018
  • Of the many factors that affect the clinical outcomes of orthopedic surgery, the surgical procedure is the most important. Robotics have been developed to perform the surgical procedures more accurately and consistently. Robotic surgical procedures in the orthopedic field were developed 20 years ago. Some designs of surgical robots have disappeared due to practical problems and complications, and an another design of surgical robots is emerging. To date, the use of robot surgery in arthroplasty is still controversial in terms of the clinical outcomes, practicality, and cost-effectiveness, even though it has been reported to be effective in the alignment and positioning of components in the field of artificial joints. Early robotic surgery was based mainly on active robot surgery according to the scheduled operation without the intervention of the operator. Recently the semi-active system of robotic surgery has been introduced. In a semi-active system, the robot constrains the surgeon to a haptic boundary defined by the computer based on the 3-dimensional imaging preoperative plan, and the operator can change the preoperative plan through real-time feedback during operation.

Effects of ADCYP1R1, FABP3, FABP4, MC4R, MYL2 Genotypes on Growth Traits in F2 Population Between Landrace and Jeju Native Black Pig (제주재래흑돼지와 Landrace의 F2 집단에서 ADCYP1R1, FABP3, MC4R, MYL2 유전자형이 성장형질에 미치는 효과)

  • Han, Sang-Hyun;Shin, Kwang-Yun;Lee, Sung-Soo;Ko, Moon-Suck;Jeong, Dong-Kee;Jeon, Jin-Tae;Cho, In-Cheol
    • Journal of Animal Science and Technology
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    • v.50 no.5
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    • pp.621-632
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    • 2008
  • Genetic polymorphisms was investigated at five single nucleotide polymorphisms(SNP) sites in four porcine genes(ADCYAP1R1, FABP3, MC4R, and MYL2) and analyzed their statistical association with growth traits in F2 reciprocal-crossbred population between Landrace and Jeju native black pig(JNP). All populations, JNP, Landrace and their F2 were polymorphic for all five SNP loci tested, however, the homozygote T/T of FABP3 g.-158T>C and the homozygote G/G of ADCYAP1R1 intron 2 337A>G were not found in JNP and Landrace, respectively. The genotypes of ADCYAP1R1 were significantly associated with body weights(BW) at 3 weeks and at 20 weeks(P<0.05), respectivley, those of FABP3 g.-135delT were associated with late average daily gain(LADG) (P<0.01), and those of FABP3 g.-158T>G were associated with body weights during late growth period such as, BW20 and LADG(P<0.01). Those of MC4R were also significantly associated with BW10 suggesting by the difference of early average daily gain(EADG) (P<0.05), and with LADG(P<0.01). The body length of F2 animals was affected by the genotypes of ADCYAP1R1, MC4R, and MYL2(P<0.05), respectively. Among these, MC4R A/A homozygotes showed over 3 cm longer in body length than those of other genotypes. As the useful basic information, these results suggested that SNP markers showing statistical association with growth traits and the results help to select the sires of JNP for improving the productivity in JNP-related crossbreeding system in pig industry and also to construct the molecular breeding system for breed improvement of JNP itself.

Genetic Characterization of Wolla Coat Color in Jeju Horses (제주마에서 월라 모색의 유전적 특성)

  • Kim, Nam-Young;Shin, Kwang-Ynu;Lee, Chong-Eon;Han, Sang-Hyun;Lee, Sung-Soo;Park, Yong-Sang;Ko, Moon-Suck;Hong, Hyun-Ju;Yang, Jae-Hyuk;Jang, Deok-Jee;Yang, Young-Hoon
    • Journal of Animal Science and Technology
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    • v.54 no.5
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    • pp.375-379
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    • 2012
  • This study was carried out to define the "Wolla" coat color using 376 Jeju registered horses (white patched 142, solid coat color 234). Three major factors related to the white patches i.e ECA3-inversion for Tobiano, EDNRB 2 bp nucleotide substitution for frame Overo, and the KIT intron 16 single nucleotide polymorphism (SNP) for Sabino types of coat color were analyzed. It was found that out of 142 Jeju horses with white patches that have the genotype for ECA3-inversion (To) 140 horses were +/To heterozygous and 2 horses were To/To homozygous all Jeju horses with white patches had ECA3-inversion allele. However, there was no frame Overo or Sabino allele type in EDNRB and KIT intron 16 SNP in Jeju horses with white patches. As for 234 Jeju horses with a solid coat color, there was no ECA3-inversion allele related to the white patches. Thus, it could be considered that Wolla coat color with white patches in Jeju horses might have come from the Tobiano line in the genetic classification by coat color.

Relationship Between MC1R and ASIP Genotypes and Basic Coat Colors in Jeju Horses (제주마의 기본모색과 MC1R과 ASIP 유전자형 조합의 상관관계)

  • Kim, Nam-Young;Han, Sang-Hyun;Lee, Sung-Soo;Lee, Chong-Eon;Park, Nam-Geon;Ko, Moon-Suck;Yang, Young-Hoon
    • Journal of Animal Science and Technology
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    • v.53 no.2
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    • pp.107-111
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    • 2011
  • This study was undertaken to reveal the relationship between genetic variations and the basic coat color classification system in Jeju horses. Genetic variations of the melanocortinreceptor 1 (MC1R) and agouti signaling protein (ASIP) genes were investigated using pyrosequencing technique. A nucleotide substitution mutation for MC1R g.901C>T and an ASIP 11-bp deletion mutation were screened. Black horses had MC1R $E^+$/- ($E^+/E^+$ or $E^+/E^e$) and ASIP $A^a/A^a$ genotypes. In contrast, chestnut horse genotypes were MC1R $E^e/E^e$ and ASIP -/-. Thus, black and bay horses have at least one dominant MC1R allele, $E^+$, whereas chestnut horses have homozygous recessive alleles $E^e/E^e$. This suggests that the MC1R genotypes determine chestnut or black/bay coat color, regardless of the genotype distribution of ASIP. In addition, the horses with MC1R $E^+$/- and a dominant ASIP $A^A$/- allele showed bay coat color, but not black, suggesting that the ASIP $A^A$ allele represses black coat color development in the hairs of the body, but not in the mane and all four legs. Pedigree analysis showed a consistent relationship between the genotype distribution of the MC1R and ASIP genes and basic coat color patterns, even in the $F_1$ progeny. The results of this study revealed the relationship between the coat color phenotype and genetic background and suggested that useful information may be provided for molecular breeding of Jeju horses.