• Geophysics and Geophysical Exploration
• /
• v.8 no.1
• /
• pp.1-6
• /
• 2005

Analogue physical modelling using granular materials (i.e., sandbox experiments) has been applied with great success to a number of geological problems at various scales. Such physical experiments can also be simulated numerically with the Discrete Element Method (DEM). In this study, we apply the DEM simulation to the collision between the Indian subcontinent and the Eurasian Plate, one of the most significant current tectonic processes in the Earth. DEM simulation has been applied to various kinds of dynamic modelling, not only in structural geology but also in soil mechanics, rock mechanics, and the like. As the target of the investigation is assumed to be an assembly of many tiny particles, DEM simulation makes it possible to treat an object with large and discontinuous deformations. However, in DEM simulations, we often encounter difficulties when we examine the validity of the input parameters, since little is known about the relationship between the input parameters for each particle and the properties of the whole assembly. Therefore, in our previous studies (Yamada et al.,2002a,2002b,2002c), we were obliged to tune the input parameters by trial and error. To overcome these difficulties, we introduce a numerical biaxial test with the DEM simulation. Using the results of this numerical test, we examine the validity of the input parameters used in the collision model. The resulting collision model is quite similar to the real deformation observed in eastern Asia, and compares well with GPS data and in-situ stress data in eastern Asia.

• Clean Technology
• /
• v.25 no.1
• /
• pp.56-62
• /
• 2019

The equilibrium, kinetic and thermodynamic parameters of adsorption of murexide by granular activated carbon were investigated. The experiment was carried out by batch experiment with the variables of the amount of the adsorbent, the initial concentration of the dye, the contact time and the temperature. The isothermal adsorption equilibrium was best applied to the Freundlich equation in the range of 293 ~ 313 K. From the separation factor (${\beta}$) of Freundlich equation, it was found that adsorption of murexide by granular activated carbon could be the appropriate treatment method. The adsorption energy (E) obtained from the Dubinin- Radushkevich equation shows that the adsorption process is a physical adsorption process. From the kinetic analysis of the adsorption process, pseudo second order model is more consistent than pseudo first order model. It was found that the adsorption process proceeded to a spontaneous process and an endothermic process through Gibbs free energy change ($-0.1096{\sim}-10.5348kJ\;mol^{-1}$) and enthalpy change ($+151.29kJ\;mol^{-1}$). In addition, since the Gibbs free energy change decreased with increasing temperature, adsorption reaction of murexide by granular activated carbon increased spontaneously with increasing temperature. The entropy change ($147.62J\;mol^{-1}\;K^{-1}$) represented the increasing of randomness at the solid-solution interface during the adsorption reaction of murexide by activated carbon.

• Journal of the Mineralogical Society of Korea
• /
• v.25 no.4
• /
• pp.271-282
• /
• 2012

We explore the effect of removal of organic ligand on the atomic configurations around oxygen in hydroxyl groups in amorphous silica gel (synthesized through hydrolysis of $SiCl_4$ in diethyl-ether) using high resolution $^{17}O$ solid state NMR spectroscopy. $^1H$ and $^{29}Si$ MAS NMR spectra for amorphous silica gel showed diverse hydrogen environments including water, hydroxyl groups (e.g., hydrogen bonded silanol, isolated silanol), and organic ligands (e.g., alkyl chain) that may interact with surface hydroxyls in the amorphous silica gel, for instance, forming silica-organic ligand complex (e.g., Si-$O{\cdots}R$). These physically and chemically adsorbed organic ligands were partly removed by ultrasonic cleaning under ethanol and distilled water for 1 hour. Whereas $^{17}O$ MAS NMR spectra with short pulse length ($0.175{\mu}s$) at 9.4 T and 14.1 T for as-synthesized amorphous silica gel showed the unresolved peak for Si-O-Si and Si-OH structures, the $^{17}O$ MAS NMR spectra with long pulse length ($2{\mu}s$) showed the additional peak at ~0 ppm. The peak at ~0 ppm may be due to Si-OH structure with very fast relaxation rate as coupled to liquid water molecules or organic ligands on the surface of amorphous silica gel. The observation of the peak at ~0 ppm in $^{17}O$ MAS NMR spectra for amorphous silica gel became more significant as the organic ligands were removed. These results indicate that the organic ligands on the surface of amorphous silica gel interact with oxygen atoms in Si-OH and provide the information about atomic structure of silanol and siloxane in amorphous silica gel. The current results could enhance the understanding of dehydration mechanism of diverse silicates, which is known as atomic scale origins of intermediate depth (approximately, 70~300 km) earthquakes in subduction zone.