• Economic and Environmental Geology
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• v.43 no.6
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• pp.589-601
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• 2010

Recently it has been frequently reported arsenic contamination of geologic origin in groundwater. The iron-impregnated ranular activated carbon (Fe-GAC) was developed for effective removal of arsenic from groundwater n the study. Fe-GACs were prepared by impregnating iron compounds into a supporting medium (GAC) with 0.05 M iron nitrate solution. The materials were used in arsenic adsorption isotherm tests to know the effect of iron impregnation time, batch kinetic tests to understand the influence of pH, and column tests to evaluate for the preliminary operation of water treatment system. The results showed that the minimum twelve hours of impregnation time were required for making the Fe-GAC with sufficient iron content for arsenic removal, confirmed by a high arsenic adsorption capacity evaluated in the isotherm tests. Most of the impregnated iron compounds were iron hydroxynitrate $Fe_4(OH)_{11}NO_3{\cdot}2H_2O$ but a mall quantity of hematite was also identified in X-ray diffraction(XRD) analysis. The batch isotherms of Fe-GAC for arsenic adsorption were well explained by Langmuir than Freundlich model and the iron contents of Fe-GAC have positive linear correlations on logarithmic plots with Freundlich distribution coefficients ($K_F$ and Langmuir maximum adsorption capacities ($Q_m$. The results of kinetic experiments suggested hat Fe-GAC had he excellent arsenic adsorption capacities regardless of all pH conditions except for pH 11 and could be used a promising adsorbents for groundwater arsenic removal considering the general groundwater pH range of 6-8. The pseudo-second order model, based on the assumption that the ate-limiting step might be chemisorption, provided the best correlation of the kinetic experimental data and explained the arsenic adsorption system f Fe-GAC. The column test was conducted to valuate the feasibility of Fe-GAC use and the operation parameters in arsenic groundwater treatment system. The parameters obtained from the column test were the retardation actor of 482.4 and the distribution coefficient of 581.1 L/mg which were similar values of 511.5-592.5 L/mg acquired from Freundlich batch isotherm model. The results of this study suggested that Fe-GAC could be used as promising adsorbent of arsenic removal in a small groundwater supply system with water treatment facility.

• Clean Technology
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• v.26 no.2
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• pp.122-130
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• 2020

The isotherm, kinetic, and thermodynamic parameters of reactive blue 4 adsorbed by activated carbon were investigated for activated carbon dose, pH, initial concentration, contact time, and temperature data. The adsorption of the RB 4 dye by activated carbon showed a concave shape in which the percentage of adsorption increased in both directions starting from pH 7. The isothermal adsorption data were applied to Langmuir, Freundlich, and Temkin isotherms. Both Freundlich and Langmuir isothermal adsorption models fit well. From determined Freundlich separation factor (1/n = 0.125 ~ 0.232) and Langmuir separation factor (R_L = 1.53 ~ 1.59), adsorption of RB 4 by activated carbon could be employed as an effective treatment method. The constant related to the adsorption heat (B_T = 2.147 ~ 2.562 J mol^-1) of Temkin showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo second order model with good agreement. The results of the intraparticle diffusion model showed that the inclination of the first straight line representing the surface diffusion was smaller than that of the second straight line representing the intraparticle pore diffusion. Therefore, it was confirmed that intraparticle pore diffusion is the rate-controlling step. The negative Gibbs free energy change (ΔG = -3.262 ~ -7.581 kJ mol^-1) and the positive enthalpy change (ΔH = 61.08 kJ mol^-1) indicated the spontaneous and endothermic nature of the adsorption process, proving this process to be spontaneous and endothermic.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.12
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• pp.1035-1047
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• 2015

Wind tunnel experiment and computational analysis have been carried out to evaluate the performance of propeller for scale electric-powered HALE UAV, named EAV-2H+. Performance curves are measured for three propellers and their adequacy for EAV-2H+ installation is examined through consideration of operating conditions. Decline in performance coefficients is observed in low rpm region. Also, the effect of transition tape on propeller performance is measured and analyzed. The computational performance analyses are carried out by using commercial CFD program. The thrust and power coefficient from computations show good agreement with experimental results. Performance coefficients are compared and the influence of measurement device which contributes to discrepancy of the results is examined. Transition SST model is confirmed to yield the tendency of performance decline in low rpm range, similar to experimental observation. The decrease in aerodynamic performance of blade element due to low Reynolds number is identified to cause the decline in propeller performance. Analyses for high altitude conditions confirms degradation in propeller performance.

• Journal of the Korean Society for Railway
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• v.10 no.5
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• pp.492-498
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• 2007

For the running safety assessment of Saemaul train passing through curves, an analysis model for multibody system has been developed. By using this model and ADAMS/Rail, sensitivity analyses depending on the variation of parameters related to the derailment coefficients have been conducted. At low speed, the derailment coefficient and the unload ratio of right wheel showed higher than left wheel, while those of left wheel showed higher than right wheel at high speed. According to decrease of curve radius, the derailment coefficient and the unload ratio were increased. When the length of transition curve was increased, the derailment coefficient was increased but there was no change on the unload ratio. According to the increase of cant, the derailment coefficient and the unload rate were increased.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.9 no.3
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• pp.49-55
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• 2010

In this paper, the stability of cracked cantilever T-beams subjected to subtangential follower force is investigated. Also, the effect of subtangential coefficient and crack on the natural frequency of T-beams is presented. Based on the Euler-Bernoulli beam theory, the equation of motion is derived by the energy expressions using extended Hamilton's Principle. The crack is assumed to be in the first mode of fracture and to be always opened during the vibrations. The values of critical follower force and the stability maps of cantilever T-beams are obtained according to the subtangential coefficient and crack severity. The results of this study will contribute to the safety testing and the stability estimation of cracked T-beams subjected to follower force.

• Proceedings of the KIEE Conference
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• 2006.07d
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• pp.1791-1792
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• 2006

이 논문에서는 저속 회전체의 불균일 질량측정을 위한 새로운 신호처리 방법을 제안하고 이를 이용한 자동차 타이어의 보정(balancing) 방법에 관해 설명한다. 타이어를 포함한 시스템의 동력학 모델을 기반으로 타이어의 불균일 질량에 의해 발생되는 진동과 이로 인해 로드셀에 작용하는 힘의 관계식을 유도하고, 센서의 측정계수(scale factor)를 포함한 매개변수를 실험 데이터로부터 계산한다. 또한, 기존 방법과 달리 불균일 질량의 크기와 위치를 정확하고 효율적으로 측정할 수 있는 방법을 소형 마이크로 프로세서를 이용하여 구현하고 실험을 통해 그 성능을 검증한다.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2001.05a
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• pp.404-407
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• 2001

In this paper, hydro-turbine system is modelled. Real input and output signals are acquired from the hydro-turbine system and the parameters of the model are estimated using input-output data, the model adjustment technique and a genetic algorithm(GA). To verify feasibility of the propose(1 model, computer simulations using GA have been carried out. The results show excellent characteristics of the proposed modeling and identification of the hydro-turbine system.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.315-319
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• 2000

400ppm의 pentachlorophenol(PCP) 오염토양을 5$m\ell$ scintillation vial의 multi reactor와 1L 크기의 one reactor를 써서 Hydrogen peroxide와 Hemoglobin 촉매반응에 의해 PCP 분해정도를 조사하였다. 대부분 초기에 반응이 빠르게 진행되므로 time scale을 8시간 이내와 한달여기간동안 살펴보았다. 8시간동안의 PCP 분해정도는 일차함수로 동력학 계수가 -0.0233으로 나타났고, 이때 제거효율은 60.8%이고 one reactor의 경우 30일동안 80%의 제거효율을 보였다. PCP 회수율은 multi reactor의 경우 96.5($\pm$6.7)이고 one reactor(fan scale)의 경우 90.1%였다.

• Clean Technology
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• v.20 no.3
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• pp.290-297
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• 2014

Batch adsorption studies were carried out for equilibrium, kinetics and thermodynamic parameters for adsorption of coomassi brilliant blue G (CBBG) using activated carbon with varying the operating variables like initial concentration, contact time and temperature. Equilibrium adsorption data were fitted into Langmuir, Freundlich and Dubinin-Radushkevich isotherms. From estimated separation factor of Langmuir and Freundlich, this process could be employed as effective treatment for removal of CBBG. Also from Dubinin-Radushkevich isotherm model, adsorption energy (E) indicated adsorption process is physical adsorption. From kinetic experiments, the adsorption reaction was found to confirm to the pseudo second order model with good correlation. Intraparticle diffusion was rate controlling step. Thermodynamic parameters like change of free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption. The change of enthalpy (406.12 kJ/mol) indicated endothermic nature of the adsorption process. The change of entropy (1.66 kJ/mol K) showed increasing disorder in process. The change of free energy found that the spontaneity of process increased with increasing adsorption temperature.

• Clean Technology
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• v.27 no.2
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• pp.182-189
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• 2021

The adsorption of disperse yellow 3 (DY 3) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetic and thermodynamic parameters by experimenting with initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH change experiment, the adsorption percent of DY 3 on activated carbon was highest in the acidic region, pH 3 due to electrostatic attraction between the surface of the activated carbon with positive charge and the anion (OH^-) of DY 3. The adsorption equilibrium data of DY 3 fit the Langmuir isothermal adsorption equation best, and it was found that activated carbon can effectively remove DY 3 from the calculated separation factor (R_L). The heat of adsorption-related constant (B) from the Temkin equation did not exceed 20 J mol^-1, indicating that it is a physical adsorption process. The pseudo second order kinetic model fits well within 10.72% of the error percent in the kinetic experiments. The plots for Weber and Morris intraparticle diffusion model were divided into two straight lines. The intraparticle diffusion rate was slow because the slope of the stage 2 (intraparticle diffusion) was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was rate controlling step. The free energy change of the DY 3 adsorption by activated carbon showed negative values at 298 ~ 318 K. As the temperature increased, the spontaneity increased. The enthalpy change of the adsorption reaction of DY 3 by activated carbon was 0.65 kJ mol^-1, which was an endothermic reaction, and the entropy change was 2.14 J mol^-1 K^-1.