• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.168-168
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• 2000

Yamada 등의 덩어리 증착에 관한 연구 이후 낮은 기판 온도에서 결정성이 뛰어난 금속박막성장(thin film growth)을 얻을 수 있는 방법으로 최근 덩어리 증착(cluster depositon) 방법에 관하여 많은 연구들이 진행되어 덩어리 충돌이 원자 충돌인 경우와 큰 차이를 보이는 결과를 얻었으며, 덩어리 증착시 기판 내부에 점결함(point defect)이 발생되지 않는다는 중요한 결과를 얻었다. 금속 덩어리를 사용한 금속박막성장은 높은 박막성장속도와 뛰어난 구조 재배열 효과를 얻을 수 있으며 기판의 격자 손상을 감소시키기 때문에 향후 나노미터 소자 개발에 응용성이 클 것으로 예상된다. 그러나 금속 덩어리와 금속 표면사이의 상호작용에서 발생되는 기본적인 역학(mechanism)은 분명하게 알려져 있지 않다. 지금까지 알루미늄 덩어리의 원자구조와 특성에 관한 연구는 수행되어졌지만 (4,5), 알루미늄 덩어리 증착에 관한 연구는 수행되지 않았다. 본 연구에서는 13~177개로 이루어진 큰 알루미늄 덩어리들의 증착에 관하여 Md(molecular dynamics) 방법을 사용하여 연구하였다. MD 시뮬레이션을 사용하여 덩어리 증착시 기판 표면과의 충돌 초기에 나타나는 덩어리 내부 원자들의 상관충돌효과(correlated collisions effect)에 의하여 덩어리 크기에 따른 증착현상과 여러 물리적 현상들을 관찰하였다. 덩어리 총 에너지가 증가할수록 기판의 최고 온도는 증가하며, 덩어리 크기가 클수록 상관충돌효과가 커지기 때문에 덩어리의 총 에너지에 다른 최고 증가 비율은 적어졌다. 시간에 따른 비정렬 원자수(disordered atom number) 비교를 통하여 덩어리가 클수록 구조 재배열이 더 잘 이루어진다는 것을 알 수 있었고, 원자당 에너지가 클수록 덩어리 원자들이 기판 내부로 더 깊이 들어갔고, 덩어리 크기가 클수록 상관충돌효과로 인하여 덩어리 원자들이 기판 내부로 더 깊이 들어가는 것을 알 수 있었고, 덩어리 크기가 클수록 상관충돌효과는 커지고 더욱 부드러운 증착이 이루어졌으며, 무엇보다도 덩어리 증착시 표면에서 구조 재배열이 잘 이루어지는 특징을 살펴볼 수 있었다. 이러한 알루미늄 덩어리를 생성하여 증착할 수 있을 경우, 뛰어난 재배열 효과를 이용하여 품질이 향상된 반도체 소자를 제조할 수 있을 것으로 사료된다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.1
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• pp.31-36
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• 2021

Recently, automobile air conditioning systems have applied an alternative refrigerant that can replace the high GWP refrigerant R134a due to the global warming problem. This study simulated the performance of an automobile climate control system with an internal heat exchanger and TXV. Refrigerant R1234yf was applied as the working fluid. Amesim, a commercial software program, was used to model the main components of the compressor, condenser, TXV, evaporator, and internal heat exchanger. As the outside temperature increased from 30℃ to 40℃, the cooling capacity of the system decreased by 3.1%, and the power consumption of the compressor increased by 17.1%. In addition, The performance characteristics of the refrigeration cycle were simulated by increasing the fin pitch of the condenser from 0.8 mm to 1.4 mm. When the fin pitch was larger than 1.0 mm, the condenser capacity decreased, and the system COP was lowered by 5.9%. When the fin pitch of the condenser was 0.8 mm, which was smaller than 1.0 mm, there was no significant change in the system performance. Hence, the optimal performance was observed at a fin pitch of 1.0 mm.

• Clean Technology
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• v.17 no.4
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• pp.346-352
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• 2011

The adsorption characteristics of propineb pesticide onto activated carbon has been investigated for the adsorption in aqueous solution with respect to initial concentration, contact time and temperature in batch experiment. The Langmuir and Freundlich adsorption models were applied to described the equilibrium isotherms and isotherm constants were also determined. The Freundlich model agrees with experimental data well. slope of isotherm line indicate that activated carbon could be employed as effective treatment for removal of propineb. The pseudo first order, pseudo second order kinetic models were use to describe the kinetic data and rate constants were evaluated. The adsorption process followed a pseudo second order model, and the adsorption rate constant($k_2$) decreased with increasing initial concentration of propineb. The activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The estimated values for change of free energy were -7.28, -8.27 and -11.66 kJ/mol over activated carbon at 298, 308 and 318 K, respectively. The results indicated toward a spontaneous process. The positive value for change of enthalpy, 54.46 kJ/mol, found that the adsorption of propineb on activated carbon is an endothermic process.

• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.565-573
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• 2021

Isotherms, kinetics and thermodynamic properties for adsorption of Brilliant Green(BG), Quinoline Yellow(QY) dyes by activated carbon were carried out using variables such as dose of adsorbent, pH, initial concentration, contact time, temperature and competitive. BG showed the highest adsorption rate of 92.4% at pH 11, and QY was adsorbed at 90.9% at pH 3. BG was in good agreement with the Freundlich isothermal model, and QY was well matched with Langmuir model. The separation coefficients of isotherm model indicated that these dyes could be effectively treated by activated carbon. Estimated adsorption energy by Temkin isotherm model indicated that the adsorption of BG and QY by activated carbon is a physical adsorption. The kinetic experimental results showed that the pseudo second order model had a better fit than the pseudo first order model with a smaller in the equilibrium adsorption amount. It was confirmed that surface diffusion was a rate controlling step by the intraparticle diffusion model. The activation energy and enthalpy change of the adsorption process indicated that the adsorption process was a relatively easy endothermic reaction. The entropy change indicated that the disorder of the adsorption system increased as the adsorption of BG and QY dyes to activated carbon proceeded. Gibbs free energy was found that the adsorption reaction became more spontaneous with increasing temperature. As a result of competitive adsorption of the mixed solution, it was found that QY was disturbed by BG and the adsorption reduced.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.1-10
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• 2023

Due to the development of the industrial revolution, regulations on exhaust emissions have been continuously strengthened to reduce the rapidly increasing greenhouse gas emissions. The use of environmentally friendly fuels is essential to meet these regulations. Hydrogen has been attracting attention as a future environmentally friendly fuel, but due to its material properties, it faces significant challenges in handling and storage. As an alternative, ammonia has been proposed. Ammonia can be easily liquefied at room temperature compared to hydrogen and has a high energy density. In order to examine the applicability of ammonia as an engine fuel, experiments were conducted to investigate the effects of changes in combustion control parameters in a direct injection ammonia combustion engine. The experiments were conducted by varying two variables: spark timing and excessive air ratio. Observations were made on combustion stability and the trends of exhaust emissions such as nitrogen oxides and unburned ammonia under the conditions of an engine speed of 1,500 rpm and medium to high loads (brake torque of 200 Nm). By optimizing the combustion control parameters, conditions for stable combustion even when using ammonia as the sole fuel were identified, and plans are underway to apply strategies for future expansion of the operating range.

• Journal of Energy Engineering
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• v.5 no.2
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• pp.160-169
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• 1996

Parametric studies are conducted for optimizing the integration design between gas turbine compressor and air separation unit (ASU) of integrated gasification combined cycle power plant. The present study adopts the ASU of double-distillation column process, from which integration conditions with compressor such as the heat exchanger condition between air and nitrogen, the amount and the pressure of extracted air are defined and mathematically formulated. The performance variations of the compressor integrated with ASU are analyzed by combining streamline curvature method and pressure loss models, and the predicted results are compared with the performance test results of actual compressors to verify the prediction accuracy. Using the present performance prediction method, the effects of pinch-point temperature difference (PTD) in the heat exchanger, the amount and the pressure of extracted air on compressor performances are quantitatively examined. As the extraction air amount or the PTD is increased, the pressure ratio and the power consumption of compressor are increased. The compressor efficiency deteriorates as the increase of the flow rate of air extracted at higher pressure level while improving at lower pressure air extraction. Furthermore, through the characteristic curve between generalized inlet condition and efficiency of compressor, optimal integration condition is presented to maximize the compressor efficiency.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.29 no.2
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• pp.230-237
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• 1996

The objective of the present study is to evaluate organic removal efficiencies, nitrogen removal efficiencies, kinetic constant, sludge production rates, oxygen requirements, and optimum treatment renditions for recycling water treatment of aquaculture by using a trickling filter process. When the loading rates were $0.500\~0.082kg\;COD/m^3/day$ and $0.271\~0.044kg\;NH_4^+-N/m^3/day$, SCOD and ammonia removal efficiencies were $74.5\~84.0\%$ and $43.7\~61.8\%$, respectively. The maximum removal rate of ammonia was 119.5 mg/L/day. Observed cell yield coefficient in the trickling filter reactor was 0.572 kg VSS/kg $BOD_{rem}$. When the hydraulic loading rate was $6.712\~40.341m^3/m^2/day$, oxygen uptake rate was $1.33\~7.22\;mg\;O_2/L/hr$.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.5-5
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• 2017

방제 작업은 병해충을 줄여 농산물의 품질과 생산량을 높이기 위한 필수 작업이다. 하지만 방제 작업은 고온 다습한 환경에서 작업하여 고된 작업 강도와 농민의 농약 중독 문제, 고령화 여성화로 인한 농가 일손 부족 문제로 농촌에서는 기피하고 있는 작업 중 하나이다. 이러한 점을 보완하기 위해 동력 살포기와 같은 기계를 이용하여 살포 작업을 실시하고 있으며, 스피드 스프레이어의 경우 2015년 기준 2,073 대가 농가에 공급되어졌다. 스피드 스프레이어를 사용하는 농가는 점차 증가하고 있으나, 현재 스피드 스프레이어의 살포 방식의 경우 농약을 다량 살포함으로써, 농약의 낭비, 환경오염의 문제점이 나타나고 있다. 이러한 점을 보완하기 위해 최근에는 방제 작업의 방식이 붐을 이용한 방제 작업으로 바뀌어가고 있는 추세이다. 붐 방제기의 경우 붐에 노즐을 배치하여 작물에 근접한 위치에서 농약을 정밀 살포하며, 스피드 스프레이어와 다르게 농약의 낭비를 줄일 수 있으며, 농약의 살포량을 제어하기 쉬운 장점이 있다. 본 연구에서는 기존의 트랙터 부착형 붐 방제기가 아닌 스피드 스프레이어를 개선한 붐식 스피드 스프레이어를 개발하기 위하여 현재 사용되고 있는 붐 방제기의 연구 동향 및 제품을 소개하고 개발에 필요한 기초 자료로 활용하고자 한다. 기존의 붐 방제기는 트랙터에 부착하는 형태로 개발되어졌으며 트랙터의 부착위치에 따라 전륜, 후륜형으로 나뉘고, 작물의 크기에 따라서 붐의 높이 및 붐의 각도를 조절하는 구조로 제작하여 사용되고 있다.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.589-597
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• 2010

Strengthening the regulation standard of biological nutrient in wastewater treatment plant(WWTP), the necessity of repair of WWTP which is operated in conventional activated sludge process to advanced nutrient removal treatment is increased. However, in full-scale wastewater treatment system, it is not easy to fine the optimized operational condition of the advanced nutrient removal treatment through experiment due to the complex response of various influent conditions and operational conditions. Therefore, in this study, an upgrading design of conventional activated sludge process to advanced nutrient removal process using the modeling and simulation method based on activated sludge model(ASMs) is executed. And a design optimization of advanced treatment process using the response surface method(RSM) is carried out for statistical and systematic approach. In addition, for the operational optimization of full-scale WWTP, a correct analysis about kinetic variables of wastewater treatment is necessary. In this study, through partial least square(PLS) analysis which is one of the multivariable statistical analysis methods, a correlation between the kinetic variables of wastewater treatment system is comprehended, and the most effective variables to the advanced treatment operation result is deducted. Through this study, the methodology for upgrading design and operational optimization of advanced treatment process is provided, and an efficient repair of WWTP to advanced treatment can be expected reducing the design time and costs.

• Korean Journal of Agricultural Science
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• v.11 no.2
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• pp.284-294
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• 1984

Effects of orifice diameter, operating angle and swirl chamber distance were examined to study a reasonable distribution pattern on the maximum available travel distance in the triple nozzle system. The results of the study were as follows; 1. Discharge rate was increased with increase of orifice diameter, and a quadratic line for the 1st nozzle and linear lines for the 2nd or the 3rd nozzle. 2. The operating angle of $15^{\circ}$ had showed the maximum available travel distance, and 17m in orifice diameter of 3.0mm and operating pressure of $24.5{\times}10^5pa$ ($25Kg/cm^2$). 3. Nozzle setting methods (reference Table 6.) for improvement of uniformity of deposit distribution were varied depending on the size of orifice diameter of the 1st nozzle, nevertheless coefficients of uniformity were improved about 6 percents. 4. Adjustment of the swirl chamber distance of the 2nd nozzle could improve the minimum area of about 6m from the triple nozzle.