• Title/Summary/Keyword: 동력증가량

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Adsorption Kinetic, Thermodynamic Parameter and Isosteric Heat for Adsorption of Crystal Violet by Activated Carbon (활성탄에 의한 Crystal Violet 흡착에 있어서 흡착동력학, 열역학 인자 및 등량흡착열)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.206-213
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    • 2017
  • The adsorption of crystal violet dyes from aqueous solution using the granular activated carbon was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, initial concentration, contact time and temperature. The adsorption characteristic of crystal violet followed Langmuir isotherm. Based on the estimated Langmuir separation factor ($R_L=0.02{\sim}0.106$), this process could be employed as an effective treatment (0 < $R_L$ < 1). The adsorption kinetics followed the pseudo second order model. The values of Gibbs free energy (-1.61~-11.66 kJ/mol) and positive enthalpy (147.209 kJ/mol) indicated that the adsorption process is a spontaneous and endothermic reaction. The isosteric heat of adsorption decreased with increasing of surface loading by the limited adsorbent-adsorbate interaction due to increased surface coverage.

Studies on Cure Kinetics and Rheological Properties of Difunctional Epoxy/Polysulfone Blend System (이관능성 에폭시/폴리썰폰 블렌드의 경화 동력학 및 유변학적 특성에 관한 연구)

  • 박수진;김현철;이재락
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.177-185
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    • 2001
  • In this work, the cure kinetics and rheological properties of difunctional epoxy(diglycidylether of bisphenol A, DGEBA)/polysulfone (PSF) blends were investigated using differential scanning calorimeter and rheometer. From the DSC results of the blends, the temperature of the exothermic peak and cure activation energy (E) using a half-width method were increased with increasing the PSF content to neat epoxy resin up to 30 wt%. However, a marginal decrease in the blend system was shown in E. The conversion ($\alpha$) and conversion rate (d$\alpha$/dt) were decreased as the content of PSF increases. Rheological properties of the blend system were investigated under isothermal condition using a rheometer. Cross-linking activation energy (E$_{c}$) was determined from the Arrhenius equation based on gel time and curing temperature. As a result, the E$_{c}$ showed a similar behavior with E which could be resulted from high viscosity of PSF and the phase separation between DGEBA and PSF.PSF.f PSF and the phase separation between DGEBA and PSF.PSF.

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THE DYNAMIC CHANGE OF ARTIFICIALLY DEMINERALIZED ENAMEL BY DEGREE OF SATURATION OF REMINERALIZATION SOLUTION AT pH 4.3 (pH 4.3에서 재광화 용액의 포화도에 따른 인공 탈회된 법랑질의 동력학적 변화)

  • Yi, Ji-Sook;Roh, Bung-Duk;Shin, Su-Jung;Lee, Yoon;Gong, Hyung-Kyu;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.34 no.1
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    • pp.20-29
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    • 2009
  • The purpose of this study is to observe and compare the dynamic change of artificially demineralized enamel by remineralization solutions of different degrees of saturation at pH 4.3. In this study, 30 enamel specimens were demineralized artificially by lactic acid buffered solution. Each of 10 specimens was immersed in pH 4.3 remineralization solution of three different degrees of saturation (0.22, 0.30, 0.35) for 10 days. After demineralization and remineralization, images were taken by a polarizing microscope (${\times}100$). The density of lesion were determined from images taken after demineralization and remineralization. During remineralization process, mineral deposition and mineral loss occurred at the same time. After remineralization, total mineral amount and width of surface lesion increased in all groups. The higher degree of saturation was, the more mineral deposition occurred in surface lesion and the amount of mineral deposition was not much in subsurface lesion. Total demineralized depth increased in all groups.

A study on energy efficiency improvement of waste-water treatment system by freeze concentration method (동결농축법을 이용한 폐수처리시스템의 에너지 효율 향상에 관한 연구)

  • Kim, Jung-Sik;Lim, Seung-Taek;Oh, Cheol
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.5
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    • pp.467-476
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    • 2013
  • Freeze concentration method has advantages of high thermodynamic efficiency, low energy consumption and purified water re-use. In this study, freeze concentration waste-water system which was designed as the small and medium sized capacity was analyzed about the rate of electric power consumption and the daily treatment capacity to suggest the direction of system development. At first, power consumption and operation time of the system with fresh water precooler or without it was calculated by computer modeling and analysis. Subsequently, the change of design treatment capacity was applied to the system with fresh water cooler. As a result, the rate of electric power consumption was higher as 0.6 Wh/kg but daily treatment capacity increased in quantity as 19 % in the system with fresh water precooler. As design treatment capacity increased, the rate of electric power consumption was lower and daily treatment capacity was larger in quantity.

Development of a Cutting Force Monitoring System for a CNC Lathe (CNC 선반에서의 절삭력 감지 시스템 개발)

  • Heo, Geon-Su;Lee, Gang-Gyu;Kim, Jae-Ok
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.1 s.94
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    • pp.219-225
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    • 1999
  • Monitoring of the cutting force signals in cutting process has been well emphasized in machine tool communities. Although the cutting force can be directly measured by a tool dynamometer, this method is not always feasible because of high cost and limitations in setup. In this paper an indirect cutting force monitoring system is developed so that the cutting force in turning process is estimated based on a AC spindle drive model. This monitoring system considers the cutting force as a disturbance input to the spindle drive and estimates the cutting force based on the inverse dynamic model. The inverse dynamic model represents the dynamic relation between the cutting force, the motor torque and the motor power. The proposed monitoring system is realized on a CNC lathe and its estimation performance is evaluated experimentally.

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Model-Based Monitoring of the Turning Force (모델에 근거한 선삭력 모니터링)

  • 허건수
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1999.10a
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    • pp.11-15
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    • 1999
  • Monitoring of the cutting force signals in cutting process has been well emphasized in machine tool communities. Although the cutting force can be directly measured by a tool dynamometer, this method is not always feasible because of high cost and limitations in setup. In this paper an indirect cutting force monitoring system is developed so that the cutting force in turning process is estimated based on a AC spindle drive model. This monitoring system considers the cutting force as a disturbance input to the spindle drive and estimates the cutting force based on the inverse dynamic model. The inverse dynamic model represents the dynamic relation between the cutting force, the motor torque and the motor power. The proposed monitoring system is realized on a CNC lathe and its estimation performance is evaluated experimentally.

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Characteristics of Hybrid Type Fabric Filter with Combining Centrifugal Force and Fabric Filtration (원심력과 여과집진이 접목된 하이브리드형 여과집진장치의 특성)

  • Kim, Sang-Do;Park, Hyun-Seol;Son, Jae-Ik;Park, Young-Ok;Kang, Yong
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.63-64
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    • 2003
  • 원심력집진기는 장치가 간단하지만 집진효율이 낮아 주로 여과포집진장치 및 전기집진장치의 전단에만 사용되는 단점을 가지고 있다. 여과포집진장치는 고효율의 집진성능을 가지고 있지만 유입되는 먼지의 농도를 감소시키기 위하여 전단에 원심력집진기를 설치하게 되므로 설치공간 및 동력비가 과다하게 소요되고 있으며, 높은 압력손실, 낮은 여과속도에 의한 장치면적 증가, 균일한 집진이 어려워 일부 여과포에 집중적인 부하가 걸리게 되는 단점 등을 가지고 있다. 전기집진장치의 경우 압력손실이 적고 대용량에 적용 가능하지만, 여과집진장치에 비해 집진효율이 낮고, 먼지의 종류 및 연료연소조건에 따라 집진효율이 크게 영향을 받는 단점을 가지고 있다. (중략)

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Analysis on the two-dimensional ablation phenomenon at nozzle throat with graphite (그라파이트 노즐목의 2차원 삭마현상 해석)

  • 윤덕진;강윤구
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.04a
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    • pp.35-35
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    • 1998
  • 고체 로켓 추진기관의 노즐을 개발하기 위해서는 주어진 체계 제한 조건내에서 기본적인 가스의 동력학, 내탄도에 의한 형상 설계, 재료 개발 및 적용 기술, 열전달 계산에 의한 열설계 및 해석 등이 종합적으로 적용되며 수많은 반복과정을 거쳐야 한다. 특히 최근에는 알루미늄 함유량을 증가시켜 연소가스의 온도가 300$0^{\circ}C$ 이상이 되는 고성능 추진제가 일반적으로 적용되고 있으므로 고온에 의한 열적문제가 심각하게 대두되고 있으며 이에 견디는 신뢰도가 높은 노즐 설계개발이 요구되고 있다. 노즐목을 노즐내에서 열부하가 가장 심한 곳으로 노즐목 확대에 의한 추력 손실을 최소화하기 위해 내삭마성이 강한 재료를 선정하여야 하며, 그래파이트는 이러한 조건을 만족시키는 소재의 하나로 많이 적용되고 있다.

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Development of chopper for rice-straw round bale (볏짚원형베일쵸퍼개발)

  • 유병기;오권영;최광재;이성현;이기현
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2002.02a
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    • pp.248-253
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    • 2002
  • 가. 대형 원형베일의 볏짚을 절단하여 축사의 사조나 TMR제조기에 공급하는 원형베일쵸퍼를 개발하였다. 나. 시작기의 적정작업속도는 PTO 500rpm 수준이었으며 이때 작업능율은 964kg/시간, 평균볏짚절단길이는 13.9 cm이었다. 다. 시작기의 소요동력은 PTO회전수가 300rpm에서 600rpm으로 높아짐에 따라 증가하였으며 PTO회전수 500rpm 일 때 축 토크는 38.4kgf·m 수준이었다. 라. 비육우 50두 규모에서 시작기는 관행(볏짚절단기)에 비하여 노력절감 92%, 작업비용 26.%절감으로 나타나 실용성이 있는 것으로 나타났다. 마. 볏짚의 허실율만을 고려한 손익분기급이량은 106톤/년으로 나타나 대규모의 전업 낙농 농가나 비육우 농가 또는 여러농가에서 공동 사용할 경우에 경제성이 있는 것으로 나타났다.

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추진기 캐비테이션 성능해석법

  • 이진태
    • Bulletin of the Society of Naval Architects of Korea
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    • v.31 no.4
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    • pp.10-13
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    • 1994
  • 최근 선박의 대형화, 고속화로 인하여 추진기의 부하가 증가되고 있으며, 특히 최근 등장한 1,000TEU급 콘테이너선의 경우 추진기가 흡수해야되는 축마력이 70,000HP 이상인 경우도 잇다. 커다란 축마력을 흡수하여 선박을 빠른 속도로 추진시켜야 되는 최근의 추진기는 작동 원리상 캐비테이션 발생을 피할 수 없으며 캐비테이션 발생량의 허용범위 및 캐비테이션 거동의 특성을 고려하여 추진기를 설계하여야 된다. 캐비테이션의 여유가 없이 추진기 설계가 수행되기 때문에 추진기 캐비테이션의 성능해석은 엄밀한 정밀도가 요구된다. 캐비테이션이란 일정한 온도에서 유체동력학 작용에 의해서 유체주위의 압력이 일정한 압력(예 : 증기압) 이하로 낮아질 때 물이 기화하여 수증기로 변하면서 빈 공간을 형성하는 현상을 말한다. 이렇게 발생된 캐비티는 주위 압력환경에 따라 생성, 성장, 수축, 붕괴의 과정을 거치게 된다. 특히 붕괴의 과정은 짧은 시간 내에 급격히 진행되기 때문에 진동 및 소음의 원인이 되고, 심할 경우 추진기 혹은 주위 물체 표면에 침식작용의 원인이 되기도 한다. 본 고에서는 캐비테이션의 물리적 특성 및 분류방법을 간단히 소개하고, 캐비테이션에 의한 선박추진기의 성능저하 특성 및 모형시험 기법을 이용한 캐비테이션 성능해석법을 소개하였다.

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