• Title/Summary/Keyword: 독성원소

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Comparison of Heavy Metal Contents in Women's Hair Collected from Residental and Factory Areas in Pusan (부산시 주거지역과 공업지역 여성모발에서 검출된 중금속 농도에 대한 비교 연구)

  • 민병윤;안희정;윤명희
    • Biomedical Science Letters
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    • v.3 no.1
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    • pp.37-42
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    • 1997
  • The concentrations in women's hair of essential and toxic elements such as Zn, Ni, Fe, Mn, Cu, Cr, Pb and Cd in residential and factory areas in Pusan were determined, and all the elements were detected from all the samples. It was apparent that employees working in factory areas in Pusan were exposed directly to the essential and toxic heavy matals. This is based on the fact that average concentrations of Ni, Fe, Mn, Cu, Cr, Pb, and Cd in hair samples from women aged 10 to 29 in factory area, who were considered to be main members among women employees, were much higher than those of residential areas. That is, the highest concentrations found in the hair samples taken from women 10 to 29 years old living in factory areas were 110 times higher in Cr (in the women in their 20's), 92 times higher in Pb (in the women in their teens) and 23 times higher in Cd (in the women in their 20's) than those living in residential areas. Furthermore, it was suggested that the heavy metals may be accumulated gradually in human bodies as humans get older, based on the fact that the concentrations of Cr, Pb, and Cd in women living in residential areas were higher in older age groups, although the average contents of these elements in residents from residential areas were similar with those of several foreign countries.

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Utilization of Waste Tires as Soil Reinforcement; (2) Environmental Effects (지반보강재로서 폐타이어의 활용; (2) 환경적 영향)

  • 윤여원;문창만;김건흥
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.119-128
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    • 2004
  • Environmental impact of waste tires as gound-reinforcing material is studied. Analysis for chemical compounds and toxic effect were performed on effluents from twelve lysimeters in which waste tires were mixed with sand and three initially different environmental solutions of acidic, neutral, and basic circulated through the mixture. The test results of effluents collected from the lysimeters provided that the contaminant concentrations were lower than those of Korean drinking water standards for all the selected and tested metal elements. While iron concentration increased slightly with the exposure period, other metal concentrations decreased with the number of circulation times. From the comparison with previous investigations, the contaminant concentration decreased with the increase of tire size, i.e. increases with the increase of the exposed surface of tire metals. From the toxicity tests, no deteriorative effect was observed and it could be concluded that waste tires are not biologically hostile materials.

Geochemistry, Secondary Contamination and Heavy Metal Behavior of Soils and Sediments in the Tohyun Mine Creek, Korea (토현광산 수계에 분포하는 토양과 퇴적물의 지구화학적 특성, 이차적 오염 및 중금속의 거동)

  • 이찬희;이현구;윤경무
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.39-53
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    • 2001
  • Environmental pollution of the Tohyun mine creek area was investigated on the basis of geology, mineralogy and geochemistry. In soils and sediments of the mine area, ${Al_2}{O_3}/{Na_2O}$ and ${K_2}O/{Na_2}O$ ratios are partly negative correlation against ${SiO_2}/{Al_2}{O_3}$, respectively. Geochemical characteristics of some trace and rare earth elements such as V/Ni, Ni/Co, La/Ce, Th/Yb, Th/U, La/Th, ${La_N}/{Yb_N}$, La/Sc and Sc/Th are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. These results suggest that sediments source of the host shale around the mine area could be originated by basic to intermediate igneous rocks. Mineral compositions of soil and sediment near the mine area were partly variable mineralogy, which are composed of quartz, mica, feldspar, chlorite, clay minerals and some pyrite. Soils and sediments with highly concentrated heavy minerals, gravity separated mineralogy, are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various kinds of hydroxide minerals on the polished sections. As normalized by bed rock composition, average enrichment indices of major elements in sediments, precipitates, farmland soils and paddy soils are 1.0, 1.7, 0.9 and 0.8, respectively. Maximum concentration of environmental toxic elements in the mine creek are detected with Ag = 186 ppm, As = 17,100 ppm, Bi = ]27 ppm, Cd = 77 ppm, Cu = 12,299 ppm, Pb = 8,897 ppm, Sb = 1,350 ppm, W = 599 ppm and Zn = 12,250 ppm, which are increasing with total FeO increasing, and extremely high concentrations of surface sediments and precipitates near the waste rock dump. These toxic elements (As, Bi, Cd, Cu, Pb, Sb, W and Zn) of the samples, normalizing by host rock concentration, revealed that average enrichment index is 106.0 for sediments, 279.6 for precipitates, 3.5 for farmland soils and 1.6 for paddy soils. However, on the basis of EPA values, enrichment indices of all the samples are 40.7, 121.4, 1.3 and 0.6, respectively.

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CZTS 박막 태양전지 후속 열처리에 관한 연구

  • Hwang, Dae-Gyu;Jeon, Dong-Hwan;Go, Byeong-Su;Kim, Dae-Hwan;Seong, Si-Jun;Gang, Jin-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.308.2-308.2
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    • 2013
  • Cu2ZnSnSe (CZTS)는 CuInSe2 (CIS) 중 희소 원소인 In을 Zn 및 Sn 으로 치환하여 만든 화합물 반도체이다. CZTS 의 특징은 그 구성원소가 지각 중에 풍부하게 존재하고, 모든 원소의 독성이 극히 낮다는 것이다. 이에 비해 CIS 중에 In과 Se 의 지각 함유량은 0.05 ppm 이하이다. 따라서 CZTS 는 값이 싼 범용 원소만으로 구성된 새로운 태양전지 재료가 된다. 본 연구에서는 다양한 Se 비율로 동시 증발법으로 증착된 CZTS 박막의 후속 열처리 효과에 관하여 발표하고자 한다. 증착된 CZTS 박막은 적정량의 Se 비율과 후속 열처리를 통해서 이차상이 없는 CZTS 결정성을 나타내는 XRD 결과를 보여주었으면, 3.6% 의 효율을 보여주었다.

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우리나라 패류의 계절에 따른 중금속 오염도 변화

  • 김정민;권훈정;김찬국;이창복
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.05a
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    • pp.86-86
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    • 2003
  • 국내에서 식용되고 있는 패류 내의 중금속 오염도를 검색하기 위하여 5, 6, 7, 8, 10, 12월 동안 12종, 70개의 시료를 수집하였다. 젖은 시료 약 3g에 질산과 과산화수소를 가하여 마이크로파 분해 장치로 습식분해하고 희석하여 ICP-MS, 원자흡광 광도계, 원자 형광 광도계로 분석 하였다. 분석 원소는 Hg, Pb, Cd, As를 포함하여 13종이며 계절에 따른 중금속 오염도의 변화양상을 보았다. (중략)

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보은제일탄광 수계에 분포하는 수질과 토양의 오염도 평가

  • 김기중;이찬희;이현구
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.223-225
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    • 2003
  • 충북 보은군 회남면 조곡리와 분저리 일대에는 옥천누층군의 변성퇴적암에 속하는 문주리층, 창리층, 황강리층 및 국사봉층이 분포한다. 특히 국사봉층에는 모암의 주향연장을 따라 3~6매의 저품위 탄층이 단속적으로 배태되어 있어, 이를 대상으로 개발되었던 한도탄광, 부국탄광, 삼성제일탄광 및 보은제일탄광이 있다. 각각의 탄광주변에는 탄층을 따라 노두의 여러 곳에 갱도와 지표 채굴적이 산재한다. 노두에서 관찰되는 탄층은 수직 20 m 내외에서 10~300 cm의 폭을 보이나 대부분 100 cm 미만이다. (중략)

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Determination of Bromine, Arsenic, Mercury, and Selenium in Plant by Neutron Activation Analysis (방사화분석법에 의한 식물 중의 Br, As, Hg, Se의 정량)

  • Chun, Sea-Yull
    • Korean Journal of Food Science and Technology
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    • v.3 no.3
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    • pp.144-149
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    • 1971
  • The sensitive technique of activation analysis is well suited for this study since the elements such as As, Br, and Se in tobaccoes are expected to be high concentration. As, Br, and Hg were determined by Bethge destruction method and subsequent neutron activation analysis. $^{77m}Se$ was also by non-destruction activation analysis. The quantities of the element determined in Korean tobaccoes are given as follows in ppm: As, 0.65 ppm. Hg, 0.74 ppm. Se, 1.18 ppm. Br, 7.1 ppm. From the date given it seems that Korean tobaccoes and foreign tobaccoes contained considerably high concentration of selenium and mercury.

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Human Risk Assessment of Toxic Heavy Metals Around Abandoned Metal Mine Sites (금속광산지역 독성 중금속원소들의 인체 위해성 평가)

  • 이진수;전효택
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.73-86
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    • 2004
  • In order to estimate the post-ingestion bioavailability of heavy metals and to assess the risk of adverse health effects on human exposure to toxic heavy metals, environmental geochemical surveys were undertaken around the Dogok Au-Ag-Cu and the Hwacheon Au-Ag-Pb-Zn mine sites. Human risk assessment of toxic heavy metals was performed with the results of the SBET(simple bioavailability extraction test) analysis for soil and chemical analytical data for crop plant and water. Arsenic and other heavy metals were highly elevated in tailings from the Dogok(218 As mg/kg, 90.2 Cd mg/kg, 3,053 Cu mg/kg, 9,473 Pb mg/kg, 14,500 Zn mg/kg) and the Hwacheon(72 As mg/kg, 12.4 Cd mg/kg. 578 Pb mg/kg, 1,304 Zn mg/kg) mines. These significant concentrations can impact on soils and waters around the tailing dumps. The quantities of As, Cd and Zn extracted from paddy soils in the Hwacheon mine using the SBET analysis were 55.4%, 20.8% and 26.4% bioavailability, respectively, and for farmland soils in the Dogok mine, 40.8%, 37.6% and 33.0% bioavailability, respectively. From the results of human risk assessment, HI(Hazard Index) value exceeded 1.0 for As in the Hwacheon mine and for Cd in the Dogok mine. Thus, toxic risks for As and Cd exist via exposure(ingestion) of contaminated soil, water and rice grain in these mine sites. The cancer risk for As by the consumption of rice and groundwater in the Hwacheon mine area was 8E-4 and 1E-4, respectively. This risk level exceeds the acceptable risk(1 in 100,000) for regulatory purpose. Therefore, regular ingestion of locally grown rice and ground-water by the local population can pose a potential health threat due to long-term arsenic exposure.

Evaluation of Korean Water Quality Standards and Suggestion of Additional Water Parameters (국내 농업용수 수질기준의 적정성 평가 및 추가수질항목 제안)

  • An, Youn-Joo;Lee, Woo-Mi;Yoon, Chun-Gyeong
    • Korean Journal of Ecology and Environment
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    • v.39 no.3 s.117
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    • pp.285-295
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    • 2006
  • Korean water quality standards for the protection of agricultural water uses were originally derived based on management of public water resource. They were not prepared to protect crop plants from contaminants, and therefore required water parameters in agricultural uses were excluded in current water quality standards. Korean water standards in river and lake have five levels, and level IV is correspondent to agricultural water uses. Currently, there is no Korean guidelines to protect crop plants from contaminants contained in agricultural water. In Canada, agricultural water guidelines are provided to protect crops from contaminants. In this study, agricultural water quality standards in Korea were compared with them in developed countries to evaluate the adequacy of Korean water quality standards for the protection of agricultural water uses. Additional water quality parameters in agricultural uses were also proposed. Suggested parameters include electric conductivity, sodium, chloride, boron, copper, iron, zinc, and microbiological quality, They are the required parameters to protect crop plants as well as human health. Current water quality standards in agricultural uses was not considered to be appropriate in terms of crop protection. Additional water parameters should be included in agricultural water quality standards.