• Title/Summary/Keyword: 도금로

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Acute Hydrogen Cyanide Poisoning in a Plating Worker and Workplace Measurement (도금 사업장 근로자에게 발생한 시안화수소 급성중독과 작업환경평가)

  • Ham, Seunghon;Choi, Won-Jun;Lee, Junhyung;Lim, Yong su;Kang, Jihyun;Kang, Seong-Kyu
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.29 no.3
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    • pp.336-342
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    • 2019
  • Introduction: An unexpected death was reported in a beginner immediately after starting the work at a plating factory. After the incident, air sampling was performed using a simulation of the situation as it had been at the time. Methods: To evaluate the airborne concentration of hydrogen cyanide, a total of six samples were collected: one personal sample, three area samples, and two background samples (office and outdoors). Hydrogen cyanide measurement was performed according to the standard sampling protocol recommended by the U.S. NIOSH (National Institute of Occupational Safety and Health). Results: The highest concentration of hydrogen cyanide was 0.938 ppm measured in a sample collected from the plating bath area with local exhaust ventilation. This value was approximately 20% of the ceiling occupational exposure limit. The personal sample showed a concentration of 0.135 ppm. Samples collected near the bath in which the incident occurred and a dehydrator showed hydrogen cyanide concentrations of 0.236 ppm and 0.101 ppm, respectively. Hydrogen cyanide was not detected in the background samples (office and outdoors). Conclusions: It is necessary to use proper ventilation systems and respirators in plating factories to prevent acute poisoning. Furthermore, it is important to educate and train new workers dealing with toxic substances.

A Real Time Temperature Monitoring System for Plating Process (도금공정 실시간 원격 온도 모니터링 시스템)

  • Jung, Sun-Wung;Choi, Tae-Lin;Yoo, Woosik;Kim, Byung Soo
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.38 no.4
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    • pp.72-79
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    • 2015
  • A number of plating companies have been exposed to the risk of fire due to unexpected temperature increasing of water in a plating bath. Since the companies are not able to forecast the unexpected temperature increasing of water and most of raw materials in the plating process have low ignition temperature, it is easy to be exposed to the risk of fire. Thus, the companies have to notice the changes immediately to prevent the risk of fire from plating process. Due to this reason, an agile and systematic temperature monitoring system is required for the plating companies. Unfortunately, in case of small size companies, it is hard to purchase a systematic solution and be offered consulting from one of the risk management consulting companies due to an expensive cost. In addition, most of the companies have insufficient research and development (R&D) experts to autonomously develop the risk management solution. In this article, we developed a real time remote temperature monitoring system which is easy to operate with a lower cost. The system is constructed by using Raspberry Pi single board computer and Android application to release an economic issue for the small sized plating manufacturing companies. The derived system is able to monitor the temperature continuously with tracking the temperature in the batch in a short time and transmit a push-alarm to a target-device located in a remoted area when the temperature exceeds a certain hazardous-temperature level. Therefore, the target small plating company achieves a risk management system with a small cost.

Technology of selective absorber coatings on solar collectors using black chromium+3 sulfate acid on substrates (흑색 황산3가크롬을 이용한 태양열 흡열판 선택흡수막 도금기술)

  • Ohm, Tae-In;Yeo, Woon-Tack;Kim, Dong-Chan
    • Journal of the Korean Solar Energy Society
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    • v.33 no.3
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    • pp.27-35
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    • 2013
  • One of the most important factors that have a large influence on performance of the solar water heater system is performance of the solar collector, more detailedly, coating technology on the surface of the solar collector, which can provide high solar absorptance and low emittance. The core of the coating technology is to coat solar selective surfaces. In this study, various performance experiments are carried out using $Cr_2(SO_4)_3{\cdot}15H_2O$ coating technology. Here, IGBT(Insulated Gate Bipolar Transistor) of 5000A-15V was used as the surface processing rectifier which can stably output power and also can control voltage and current. The plating solution mainly contains black chrome$^{+3}$ concentration, H-y Conductivity, N-u Complex, NF Additive and NC-2 Wetter. Before applying the black chrome coating on the copper plate, optimal conditions are provided by using various preprocessing methods such as removal of fat, activation, electrolytic polishing, nickel strike, copper sulfate plating and bright neckel plating, and then the automatic continuous coating experiment are performed according to plating time and cathode current density. In the experiment, after the removal of fat, chemical polishing, nickel strike and activation processes as the preprocessing methods, the black chrome coating was performed in a plate solution temperature of $28^{\circ}C$ and a cathode current density of $18A/cm^2$ for 90 seconds. The thickness of chrome and nickel on the coated plate is $0.389{\mu}m$, $159{\mu}m$ respectively. As a result of the coating experiment, it showed the most excellent performance having a high solar absorptance of 98% and a low emittance of $5{\pm}1%$ when the black chrome surface had a thickness of $0.398{\mu}m$.

He Generation Evaluation on Electrodeposited Ni After Neutron Exposure (중성자 조사에 따른 Ni도금피복재에서의 He발생량평가)

  • Hwang, Seong Sik;Kwon, Junhyun;Kim, Dong Jin;Kim, Sung Woo
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.308-314
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    • 2021
  • Neutron dose level at bottom head of a reactor pressure vessel (RPV) was calculated using reactor vessel neutron transport for a Korean nuclear power plant A. At 34 EFPY with a 40-year (2042) design life after plating repair, irradiation fast neutron effect was 6.6x1015 n/cm2. As helium(He) gas can be generated by Ni only at 1/106 level of 5 × 1021 n/cm2, He generation possibility in the Ni plating layer is very little during 40 years of operation (2042, 34 EFPY). Thermal neutrons can significantly affect the generation of He from Ni metal. At 10 years after a repair, He can be generated at a level of about 0.06 appm, a level that can add general welding repair without any consideration. After 40 years of repair, 9.8 appm of He may be generated. Although this is a rather high value, it is within the range of 0.1 to 10 appm when welding repair can be applied. Clad repair by Ni electroplating technology is expected to greatly improve the operation efficiency by improving the safety and shortening the maintenance period of the nuclear power plant.

Study on Oxygen Evolution Reaction of Ni-Zn-Fe Electrode for Alkaline Water Electrolysis (알칼라인 수전해용 Ni-Zn-Fe 전극의 산소 발생 반응 특성)

  • LEE, TAEKYUNG;KIM, JONGWON;BAE, KIKWANG;PARK, CHUSIK;KANG, KYOUNGSOO;KIM, YOUNGHO;JEONG, SEONGUK
    • Journal of Hydrogen and New Energy
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    • v.29 no.6
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    • pp.549-558
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    • 2018
  • The overall efficiency depend on the overpotential of the oxygen evolution reaction in alkaline water electrolysis. Therefore, it is necessary to research to reduce the oxygen evolution overpotential of electrodes. In this study, Ni-Zn-Fe electrodes were prepared by electroplating and the surface area was increased by Zn leaching process. Electroplating variables were studied to optimize the plating parameters(electroplating current density, pH value of electroplating solution, Ni/Fe content ratio). Ni-Zn-Fe electrode, which is electroplated in a modified Watts bath, showed 0.294 V of overpotential at $0.1A/cm^2$. That result is better than that of Ni and Ni-Zn plated electrodes. As the electroplating current density of the Ni-Zn-Fe electrode increased, the particle size tended to increase and the overpotential of oxygen evolution reaction decreased. As reducing pH of electroplating solution from 4 to 2, Fe content in electrode and activity of oxygen evolution reaction decreased.

A Study on Pd-based Electrode prepared by using Electroless Plating Method (무전해도금법을 이용한 Pd 기반 전극·제조에 관한 연구)

  • Hwang, In Hyuck;Lee, Dong Yoon;Kim, Sung Su
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1338-1347
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    • 2018
  • In this study, Ti-mesh based electrodes were fabricated for the application of anode to the electrolysis process for wastewater treatment using Pd electroless plating method. The removal performance of the prepared Pd / Ti-mesh electrode was evaluated as representative dye RO16, and the durability and performance were maximized by varying the electrode manufacturing conditions. As a result, it was confirmed that the coating condition had no significant effect on the performance, and that the heat treatment process greatly affected the performance and the durability was improved. In addition, we tried to maximize performance and durability by complexing Ir, Ru, and Ta. However, as the thickness of the layer increased due to the limitation of the coating method, the resistance increased and the performance decreased accordingly.

Producing of Bronze Artifacts Excavated from Gulsansa Temple Site in Gangneung: Technology and Provenance (강릉 굴산사지에서 출토된 청동기의 제작: 제작기술 및 원료산지)

  • Han, Woo Rim;Kim, So Jin;Lee, Eun Woo;Hwang, Jin Ju
    • Journal of Conservation Science
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    • v.35 no.3
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    • pp.187-196
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    • 2019
  • Bronzes excavated from a Gulsansa temple site in Gangneung were investigated in order to study the production of technology and provenance in this area. The bronze artifacts were discovered to consist of copper-tin or copper-tin-lead alloys using chemical analysis(EDS and EPMA). The excavated bronzes were manufactured using a casting or hammering process, and a bronze belt was gilded with gold foil. The provenance of 25 bronzes was studied using lead isotope analysis(TIMS and LA-MC-ICPMS). The results reveal the use of raw materials found near the excavated site. The object of this study was to investigate the manufacturing techniques and provenance in Gangneung without the need for a lot of data. Our results will contribute to the study of Gulsansa and bronze artifacts in Goryo(12-13th century).

Enhancement of Electrical Conductivity in Silver Nanowire Network for Transparent Conducting Electrode using Copper Electrodeposition (구리 전기도금 방법을 이용한 은 나노와이어 투명전극의 전기전도도 향상)

  • Ji, Hanna;Jang, Jiseong;Lee, Sangyeob;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.29 no.5
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    • pp.311-316
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    • 2019
  • Transparent conducting electrodes are essential components in various optoelectrical devices. Although indium tin oxide thin films have been widely used for transparent conducting electrodes, silver nanowire network is a promising alternative to indium tin oxide thin films owing to its lower processing cost and greater suitability for flexible device application. In order to widen the application of silver nanowire network, the electrical conductance has to be improved while maintaining high optical transparency. In this study, we report the enhancement of the electrical conductance of silver nanowire network transparent electrodes by copper electrodeposition on the silver nanowire networks. The electrodeposited copper lowered the sheet resistance of the silver nanowire networks from $21.9{\Omega}{\square}$ to $12.6{\Omega}{\square}$. We perform detailed X-ray diffraction analysis revealing the effect of the amount of electrodeposited copper-shell on the sheet resistance of the core-shell(silver/copper) nanowire network transparent electrodes. From the relationship between the cross-sectional area of the copper-shell and the sheet resistance of the transparent electrodes, we deduce the electrical resistivity of electrodeposited copper to be approximately 4.5 times that of copper bulk.

Analysis of Performance of Multi-functioned frictional force measuring instrument using adaptive smoothing (적응화 평활화법을 이용한 다기능 마찰력 측정기의 성능 분석)

  • Kim, Tae-Soo;Kim, Gwang-Su
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.2
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    • pp.113-119
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    • 2019
  • We have developed the multi-functioned friction measuring instrument for the previous research. In here, we improved the performance of friction measuring instrument by applying the adaptive smoothing method and analyzed the friction of plate and monitoring function of friction surface through scratch tests. We substituted lubricant steel plate to lubricant oil used for reducing the friction when fabricating steel plate because lubricant oil was regarded as one of the major causes for the environmental pollution. In particular, the functions of various plate such as galvannealed steel sheets were analyzed because friction coefficient could be changed depending on the type of organic/inorganic plate or state of coating layer. Therefore, we demonstrated that adaptive smoothing method could enhance the accuracy of measuring instrument which eliminate the noise. As a result of using the method, it showed the reduction rate 0.0417% for the friction coefficient 0.16.

Corrosion resistance at high temperature condition of Cr Films Formed on hot-dip Al-Si plated steel sheet (용융Al-Si도금 강재에 형성한 Cr 막의 고온 환경 중 내식특성)

  • Gang, Min-Ju;Lee, Seung-Hyo;Lee, Myeong-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.448-459
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    • 2022
  • Generally, steel is the most commonly used in the industry because of good strength, processability and cost-effectiveness. Steel can be surface-treated such as coating or used as an alloy by adding elements such as Cr, Ni, Zr, and Al to increase corrosion resistance. However, even if steel is used in same environment corrosion resistance is sharply lowered when it is exposed to a high temperature for a fixed or extended period of time due to an overload or other factors. In particular, the use of hot-dip aluminized plated steel, which is used in high-temperature atmospheres, is increasing due to the surface Al2O3 oxide film. This steel necessitates an urgent solution as issues of corrosion resistance limitations often appear. It is an important issue that not only cause analysis but also the research for the surface treatment method that can be solved. Thus, in this study, Cr in which it is expected to be effective in corrosion resistance and heat resistance attempted to deposit on hot dip aluminized plated steel with PVD sputtering. And it was possible to present the surface treatment application of various types of industrial equipment exposed to high temperature and basic design guidelines for use by confirming the corrosion resistance of hot dip Al-Si plated steel with Cr film deposited at high temperature.