• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.5
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• pp.1337-1348
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• 1990

Estimations of the thermodynamic properties are made for the selected binary non-azeotropic refrigerant mixtures including R13B1/R114, R22/R114, R12/R114, R152a/R114, R13B1/R152a and R13B1/R12 using the Peng-Robinson equation of state and mixing rules. In this study, we find that the binary interaction coefficients for the above mixtures have an effect upon the vapor-liquid equilibria and the thermodynamic properties. As the binary interaction coefficient becomes larger, the deviation from the idealized model, say, Raoult`s rule, is obvious. A correlation is proposed to relate the binary interaction coefficient to the difference between the dipole moments op each pure refrigerant. Vapor-liquid equilibrium are also accurately estimated using the binary interaction coefficient. Pressure-enthalpy and temperature-entropy relations are plotted for a certain composition ratio of each refrigerant mixture. Results show that the estimating method in this study can be applied to the investigation of the thermodynamic properties for the binary non-azeotropic refrigerant mixtures.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.836-842
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• 2013

In this paper, the 20 kW Ocean Thermal Energy Conversion(OTEC) is newly proposed in order to select the refrigerant that makes the cycle performance be optimized and the performance of 20 kW OTEC applying 15 pure refrigerants and 16 mixed refrigerants is analyzed. The efficiency of system, the mass flow of working fluids and TPP, which is new concepts, are analyzed. In view of cycle efficiency, R32/R152a (87:13) is the highest efficiency among the refrigerants. At the mass flow of working fluid to make the 20 kW electricity, R717 is shown as the lowest value. And in view of TPP in this study, R32/R134a 70:30 is the most optimized refrigerant. The analysis can confirm that the refrigerant is different along with the part of the system, so it is necessary to select the optimized refrigerant for 20 kW OTEC.

• Journal of Climate Change Research
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• v.3 no.2
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• pp.153-159
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• 2012

CFC-12 used in mobile air conditioning(MAC) system has been replaced by R-134a, a type of HFC refrigerant, from 1991 to 1994. R-134a has since been widely used as a refrigerant of a mobile air conditioner. However, it is one of the six main green house gases listed in Kyoto Protocol, which makes it imperative to regulate its emission and develop alternative refrigerants. In this study, the concentration of leaked R-134a was measured using VT(Variable Temperature) shed and Running loss test shed to analyze the level of air conditioner refrigerant leaked in a vehicle. According to the analysis of the concentration of R-134a leaked from a vehicle parked, annual leakage amount of R-134a was in the range of 6.46~13.28 g/yr. The figure was similar with the leakage from the mobile air conditioning system currently used. In a study using the same vehicle model, a vehicle equipped with dual evaporation system had a higher leakage rate of refrigerant than a vehicle with a single evaporation system. It appears that the added fittings and joints of the dual evaporator system led to higher leakage rate. Besides, the analysis of the change in R-134a concentration under various car speed found that more refrigerant leaked under high speed(100km/hr) and but the volume of the wind did not affect to the variation of refrigerant leakage.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.5
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• pp.3327-3335
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• 2014

In this study, comparison works have been performed for single-stage and multi-stage refrigeration cycle using propane as a refrigerant in order to cool down the natural gas stream. A comparative analysis has been performed for a single, two, three and four stage refrigeration cycle using propane as a refrigerant for cooling the natural gas stream. For the simulation, natural gas feedstock properties supplied by KOGAS were utilized and Peng-Robinson equation of state model was used. As the number of compression stages increase, the condenser heat duty is decreased. The refrigeration heat duty for a four-stage refrigeration cycle is decreased by 20.36% compared to that for a single-stage refrigeration cycle. Moreover, the total refrigerant circulation rate for a four-stage refrigeration system is was reduced by 14.53% compared to the single stage refrigeration cycle. The total compression power for a four-stage compression was reduced by 41.61% compared to the single stage compression.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.63-73
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• 2018

Innovative technical process for Energy Storage System (ESS), Liquid Air Energy Storage system (LAES) is mature technologies based on the gas liquefaction process. In spite of many advantages such as high energy density, no geographical constraints, low investment costs and long useful life, the system has not yet widely commercialized due to low round trip efficiency. To improve RTE and acquire high yield of liquid air, various configurations of LAES process have been considered. In this research, dual refrigerants cycle (R-600a and methanol) for air liquefaction and thermal oil circulation for power generation via liquid air gasification have been applied to improve cycle performance significantly using Aspen HYSYS simulator.

• Journal of the Korean Institute of Gas
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• v.21 no.4
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• pp.92-102
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• 2017

Fischer-Tropsch synthesis reaction converts syngas (mixture of CO and H2) to valuable hydrocarbon products. Simulation of low temperature Fischer -Tropsch Synthesis reaction and heat transfer at intensified process condition using catalyst filled single and multichannel microchannel reactor is considered. Single channel model simulation indicated potential for process intensification (higher GHSV of $30000hr^{-1}$ in presence of theoretical Cobalt based super-active catalyst) while still achieving CO conversion greater than ~65% and $C_{5+}$ selectivity greater than ~74%. Conjugate heat transfer simulation with multichannel reactor block models considering three different combinations of reactor configuration and coolant type predicted ${\Delta}T_{max}$ equal to 23 K for cross-flow configuration with wall boiling coolant, 15 K for co-current flow configuration with subcooled coolant, and 13 K for co-current flow configuration with wall boiling coolant. In the range of temperature maintained (498 - 521 K), chain growth probability calculated is desirable for low-temperature Fisher-Tropsch Synthesis.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.467-476
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• 1999

This paper analyzed the behavior of fixed-bed catalytic reactor (FBCR) which synthesizing maleic anhydride(MA) from the selective oxidation of n-butane. The behavior of FBCR describing convection-diffusion-reaction mechanism is examined by using two-dimensional pseudohomogeneous plug-flow transient model, with the kinetics of Langmuir-Hinshelwood type. Prediction model is composed by optimum parameter estimation from temperature profile, yield and conversion of single FBCR on operating condition variations of Sharma's pilot-plant experiment. A double FBCR with same yield and conversion for single FBCR generated a $8.96^{\circ}C$ lower hot spot temperature than a single FBCR. We could predict parametric sensitivity according to the variation of possible operating condition (temperature, concentration, volumetric flow of feed reactant and coolant flow rate) of single and double FBCR. Double FBCR showed the behavior of more operating range than single FBCR. Double FBCR with nonuniform activities could assure safety operation condition for the possible variation of operating condition. Also, double FBCR had slightly higher than the single FBCR in conversion and yield.

• Proceedings of the KIEE Conference
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• 2006.07d
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• pp.1923-1924
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• 2006

본 논문은 HVAC(heating, ventilating, and air conditioning) 시스템에 대하여 Multi Fuzzy 제어기 설계를 제안한다. HVAC 시스템은 Compressor(압축기), Condenser(응축기), Evaporator(증발기), Expansion Valve 로 구성되며, 각각의 기기에 대한 제어가 독립적으로 이루여져 있다. 기존의 제어가 한 제어기를 사용한 단일방식으로 이루어지다보니 HVAC 시스템의 특성인 냉매의 상태가 달라지면 시스템 전반적으로 그 영향이 파급되는 부분까지 고려를 해 주지 못하고, 제어기의 성능이 효율적이지 못했다. 본 논문에서는 비선형성이 강하고 불확실하며 복잡한 시스템을 쉽게 제어할 수 있는 Fuzzy 제어기를 구성하여 Expansion Valve 와 Compressor 에서 동시에 제어하는 Multi 제어기를 설계한다. 제안된 Multi Fuzzy 제어기는 HVAC 시스템의 효율성과 안정성에 기초하여, 과열도와 저압을 제어한다.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.25-34
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• 2013

The paper reviews the state of art in the design of liquefaction processes for the production of liquified natural gas, and addresses key design aspects to be considered in the design and how these design issues are systematically reflected in industrial applications. Various design options to improve energy efficiency of refrigeration cycles are discussed, including cascaded or multi-level pure refrigeration cycles which are used for covering wide range of cooling temperature, as well as mixed refrigerant cycle which can maintain a simple structure. Heat integration technique has been used for graphically examining differences of commercial cycles discussed in this paper, while energy efficiency and economics of commercial liquefaction processes has been summarized. Discussion also has been made about how to select the most appropriate set of drivers for compressors used in the liquefaction plant.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1200-1209
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• 1999

Prediction model was composed by optimal parameter estimation from best fitting on reactant temperature profile, inlet and outlet temperature of coolant and yield of dual fixed-bed catalytic reactor(FBCR) which was measured in the industrial field. In order to design the FBCR which could obtain maximum conversion and yield, we investigated the effect of catalyst bed length and reactor radius changes. An uniform activity FBCR showed the best performance at z = 2.8 m of total catalysst bed length in case of reactor radius r = 0.01241 m and z =2.80 m(upper layer: 1.88 m, lower layer: 0.92 m) under reactor radius r = 0.01254 m for a dual activities FCBR. In case of reactor radius changes, the axial temperature profile and maximum radial temperature was rapidly risen for radius increase. The reactor radius decrease showed the opposite result.