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THE CRYSTAL AND MOLECULAR STRUCTURE OF 3-N-(2,2-DIETHOXY-ETHYL)-2-BENZIMIDAZOLINONE (3-N-(2,2디에토오키시에칠) -2벤즈 이미다즈오리논의 결정 및 분자구조)

  • 안중태;이숙자
    • Korean Journal of Crystallography
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    • v.2 no.2
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    • pp.7-12
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    • 1991
  • C13H1SN203, Mr=250.29, is monoclinic, space group P21/a with a=8.765(4), b=17.679(3), c= 9.238(4) A, b=105.6(3)A, Z=4, V=1378.53 A3, A (Mo Ka)=0.71069 A, F(000)=536, T=299, R=0.080 for 1783 unique observed reflections with I > 1.0 σ(I). The structure was solved by direct methods and relined by cascade diagona! least-squares refinement. The C-H bond lengths and methyl groups were fixed and refined as their ideal geometry. One of two ethoxy groups is more twisted by 1 was compared with another. There is one hydrogen bond in the crystal lattice, N H‥‥0= 2.789A, forming a molecular pair packing along the b-axis.

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Phase Stability and isothermal Phase Transformation of the Yttria-Stabilized Zirconia Powder Prepared from Alkoxide Hydrolysis (알코옥시드 가수분해법으로 합성한 이트리아 안정화 지르코니아 분말의 상안정성 및 등온상전이 특성)

  • Lee, Jong-Kook;Kim, Young-Jeong;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.33 no.6
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    • pp.637-644
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    • 1996
  • Phase stability and isothermal phase transformation during gaging at 25$0^{\circ}C$ were investigated in yttria stabilized zirconia powders prepared from hydrolysis of zirconium isopropoxide. The stability of tetragonal phase at room temperature in zirconia powder was decreased with calcination temperature but increased with the addition of yttria content. During aging at 25$0^{\circ}C$ in humid atmosphere isothermal phase transformation occurred in tetragonal zirconia powder stabilized by constraint effect not by alloying effect and grain size effect. Many twins and microcrackings were found in transformed monomlinic zirconia particles.

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TCP Protocol Performance Evaluation of GMAHN (GMAHN 환경에서의 TCP 프로토콜 성능 분석)

  • Oh, Se-Duk;Kim, Jae-Ho;Bae, Jin-Seung;Jung, Chan-Hyuk;Lee, Chi-Moon;Ha, Jae-Seung;You, Choong-Yeul;Lee, Kwang-Bae;Kim, Hyun-Wook
    • Journal of IKEEE
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    • v.12 no.1
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    • pp.8-17
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    • 2008
  • Recently, GMAHN that provides interface between MANET and Wired Network has been focused in mobile communication. It is necessary that the technology provide reliable data transmission technology between mobile node and wired network in MANET environment that is varied by the node movement. In this paper, using the TCP protocol(Tahoe, Reno, Vegas, SACK)that increases reliability between source and destination, we applied the TCP protocol mechanism to various environment, and proposed the most efficient TCP mechanism by comparing each mechanism.

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The Basalts and Volcanic Process in the Seondol Cinder Cone, Seobjikoji Area, Jeju Island (제주도 섭지코지 선돌 분석구의 화산작용과 현무암)

  • Koh, Jeong-Seon;Yun, Sung-Hyo;Kim, Suck-Youn
    • Journal of the Korean earth science society
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    • v.28 no.4
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    • pp.462-477
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    • 2007
  • The purpose of this study is to determine the petrology of basalt and the volcanic process in the Seondol cinder cone, Seobjikoji area, eastern Jeju Island. The Seondol cinder cone is mainly composed of spatters in the lower part, pyroclastic deposits including reddish brown blocks, ashes with volcanic bombs in the middle part, and dark black scoria deposits in the upper part. The volcanic sequences suggest volcanic processes that progress through Strombolian eruption and end with Hawaiian lava effusion which breached the cinder cone northwestward and extended over northwestward as lava delta and basalt emplaced as a volcanic neck in the central part of crater in the cinder cone. The age of basalt lava flows is about $95\;{\pm}\;3\;ka$. The basalts belong to transitional basalt and show products of fractional crystallization of clinopyroxene and olivine from a parental basalt magma on the basis of variation diagram of major, trace and rare earth elements. Basalts in the region of this study are plotted at the region of within plate basalt.

Co-Registration of Aerial Photos, ALS Data and Digital Maps Using Linear Features (선형기하보정 요소를 이용한 항공레이저측량 자료, 항공사진, 대축척 수치지도의 기하보정에 관한 연구)

  • Lee, Jae-Bin;Yu, Ki-Yun
    • Journal of Korean Society for Geospatial Information Science
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    • v.14 no.4 s.38
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    • pp.37-44
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    • 2006
  • To use surveying data obtained from different sensors and different techniques, it is a pre-requite step that register them in a common coordinate system. For this purpose, we developed methodologies to register airborne photos, ALS (Airborne Laser Scanning) data and digital maps. To achieve this, conjugate features from these data should be extracted in advance. In this study, linear features are chosen as conjugate features. Based on such a selection strategy, a simple and robust algorithm is proposed for extracting such features from ALS data. Then, to register them, observation equations are established from similarity measurements of the extracted features and the results was evaluated statistically. The results clearly demonstrate that the proposed algorithms are appropriate to register these data.

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Development of Low-Cost Data Acquisition Method for Close-range Digital Photogrammetric System (근거리 수치사진측량시스템을 위한 저가격 자료획득방법의 개발)

  • Park, Hong-Gi
    • Journal of Korean Society for Geospatial Information Science
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    • v.7 no.2 s.14
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    • pp.143-153
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    • 1999
  • GIS have become easier to use and very popular. In recent year digital photogrammetric systems ire becoming cost-effective tools to build and update GIS databases. In close-range photogrammetry for the acquisition of geospatial data, the bundle adjustment needs both initial approximate values and control points to solve the exterior orientation parameters. This paper gives a review of applied and potential algorithms for estimating Initial approximate values before the bundle adjustment, develope new algorithms for determine the exterior orientation parameters, and gives a cost-effective methods for close-range digital photogrammetric system Modifications of existing DLT algorithm were made in this study for providing an efficient, economic, and more accurate photogrammetric data reduction technique. These modifications include robust approaches for automatic detection and elimination of all lands of gross errors in the measurement data, and incorporation of GPS to reduce the number of control points necessary for a DLT solution. Also, this paper derives a new method for space resection from a monocular image. A major advantage of proposed method is that the solution can be uniquely and analytically determined without initial approximate values of exterior orientation parameters and without iterative computation.

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The Crystal and Molecular Structure of Thiosinamine (Thiosinamine의 결정 및 분자구조)

  • Shin, Hyun-So;Koo, Chung-Hoe;Lee, Soon-Won
    • Journal of the Korean Chemical Society
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    • v.28 no.4
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    • pp.205-209
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    • 1984
  • The crystal and molecular structure of thiosinamine, $H_2NCSNHCH_2CHCH_2$, has been determined by X-ray diffraction method. The crystals are monoclinic, space group $P2_1/a$ with four molecules in a unit cell of dimensions, a = 9.819(3), b = 8.553(3), c = 9.170(2)${\AA}$, ${\beta}$ = 127.3(1)$^{\circ}$, and z = 4. Intensity data for 814 reflections were collected with a Rigaku-Denki automatic four circle diffractometer. The structure was solved by direct and Fourier methods. Refinements were carried out by full matrix least-squares method to a final R value of 0.046. The thiourea unit is planar, and the bond lengths and angles in that unit agree well with those in the compounds which contain a thiourea moiety. The molecules are linked together by the two patterns of N-H${\cdots}$S hydrogen bonds along the b-axis.

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The Crystal and Molecular Structure of Cholesteryl Hexanoate at Room and Low Tempreature (Cholesteryl Hexanoate의 실온 및 저온에서의 분자 및 결정구조)

  • Young Ja Park;B. M. Craven
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.131-139
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    • 1981
  • Cholesteryl hexanoate $(C_{33}H_{56}O_2)$, is monoclinic, space group $P2_1$, with a = 12.162(3), b = 9.314(3), c = 13.643(5) ${\AA}$, ${\beta}$ = $93. 55{\circ}(3)$ and two molecules per unit cell. The atomic coordinates from cholesteryl octanoate were used in an initial trial structure using X-ray intensities(Mo $K{\alpha}$ radiation) measured by a diffractometer at room temperature and $-75{\circ}C$. Structure refinement by block-diagonal least squares gave R = 0.129 and 0.105 for room and low temperature experiments respectively. The molecules are arranged in monolayers with their long axes antiparallel and severely tilted. There is a close packing of cholesteryl groups within the monolayers. The crystal structures is very similar to those of cholesteryl octanoate and cholesteryl oleate.

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Magma Pathway of Alkali Volcanic Rocks in Goseong, Gangwon-do, Korea (강원도 고성지역에 분포하는 알칼리 현무암질 마그마의 상승경로)

  • Kil, Young-Woo;Shin, Hong-Ja;Ko, Bo-Kyun
    • The Journal of the Petrological Society of Korea
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    • v.16 no.4
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    • pp.196-207
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    • 2007
  • Miocene basalt plugs in Goseong contain a large variety of crustal and mantle xenoliths and xenocrysts. One of basalt plugs, Unbongsan, are derived from 160 km depth. Whole-rock geochemistry and pressure and temperature conditions of mineral phases indicate that Unbongsan volcanic rocks are alkali basalts and the source magma of the alkali basalts was generated from about $0.2{\sim}2%$ partial melting of depleted garnet peridotite. Crystallization pressures and temperatures of mineral phases within ascending magma of Unbongsan alkali basalt indicate that olivines, clinopyroxenes, and plagioclases were crystallized at $75{\sim}110km,\;40{\sim}52km,\;37{\sim}54km$ depth, respectively. The ascending magma of Unbongsan alkali basalts enclosed mantle xenoliths at about $57{\sim}67km$ depth.

A Study on Slope Stability Analysis of Sedimentary Rock using Interfaces Module of FLAC (FLAC의 Interfaces Module을 이용한 퇴적암 사면의 안정성 해석에 관한 연구)

  • 오대열;정교철
    • The Journal of Engineering Geology
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    • v.12 no.3
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    • pp.345-360
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    • 2002
  • This study was for analysing the sedimentary rock slope stability and providing the reinforcement method that can heighten stability. The study area consists of Cretaceous basalt or basaltic tuff belonging to Hak-Bong Basalt Formation in Ha-Yang Group. Nature of geological structure confirmed in this area ars bedding, joint and fault. Majority of geological structure that affect most relationship rock slope stability is bedding. It is shown that dip direction is 120~160/15~25. In other structure, joint sets are shown that dip direction of set 1 is 310~330/65~85 and set 2 is 230~250/70~85. Joint set 3 shows above 85$^{\circ}$ high angle on NE trend although do not show clear. Stability analysis about rock slope used kinematic analysis, limit equilibrium method and FLAC by numerical analysis method. FLAC is continuum model that use Fintie Defferentce Method, but could use Interfaces Module and get discrete model's analysis effect such as UDEC.